Abstract
Titanium dioxide supports, which were prepared by roasting metatitanic acid under different conditions, were used to prepare a series of Ce–W–Ti catalysts. The structure and denitration properties of the catalyst were studied. The results showed that TiO2 had different crystal types (mixed crystal phases with different proportions of anatase and rutile) under different roasting conditions, and the denitration efficiency of mixed crystal was better than that of pure phase TiO2. Ce–W/200 °C-1 hTiO2 catalyst exhibited a prominent NO conversion rate, and it can reach higher than 90% at a temperature range from 250 to 500°C. The large specific surface area, low content of rutile TiO2 in the support, high content of chemical adsorbed oxygen and high surface acidity were favorable to denitration performance of Ce–W–Ti catalyst.
References
[1] C.W. Shi, J.J. Liu, W.Y. Wu, X. Bian, P. Chen, Z.X. Yang, C.T. Lu: Catal. 9 (2019) 777. DOI:10.3390/catal909077710.3390/catal9090777Search in Google Scholar
[2] L.Y Song, H. He, J. Li, W.G. Qiu: J. Rare Earths. 35 (2017) 69–82. DOI:10.11785/1000-4343.2017010710.11785/1000-4343.20170107Search in Google Scholar
[3] T. Zhou, S.G. Liu, M.Z. Tang, C.W. Chen,Y.S. Xu, J.M. Wu: J. Chin. Ceram. Soc. 37 (2009) 317–324. DOI:10.3321/j.issn:0454-5648.2009.02.02910.3321/j.issn:0454-5648.2009.02.029Search in Google Scholar
[4] S. Djerad, M. Crocoll, S. Kureti, L. Tifouti, W. Weisweiler: Catal. Today. 113 (2006) 208–214. DOI:10.1016/j.cattod.2005.11.06710.1016/j.cattod.2005.11.067Search in Google Scholar
[5] X.B. Wang, R.B. Duan, W. Liu, D.W. Wang, B.R. Wang, Y.R. Xu, C.H. Niu, J.W. Shi: Appl. Surf. Sci. 510 (2020) 145517. DOI:10.1016/j.apsusc.2020.14551710.1016/j.apsusc.2020.145517Search in Google Scholar
[6] K.H. Chen, Y. He, C. Srinivasakannan, S.W. Li, S.H. Yin, J.H. Peng, S.H. Guo, L.B. Zhang: Chem. Eng. J. 356 (2019) 453–460. DOI:10.1016/j.cej.2018.09.03910.1016/j.cej.2018.09.039Search in Google Scholar
[7] T.K. Ma, G.R. Fang, L.B. Meng, L. Wang: J. Chin. Ceram. Soc. 35 (2016) 1733–1743. DOI:10.16552/j.cnki.issn1001-1625.2016.06.015.10.16552/j.cnki.issn1001-1625.2016.06.015Search in Google Scholar
[8] G.M. Jiang, J.K. Yan, G. Yang, Z.C. Duan, K.Y. Kang, J.H. Du, G.Y. Gan, J.H. Yi: Mater. Rep. 30 (2016) 95–100. DOI:10.11896/j.issn.1005-023X.2016.19.01410.11896/j.issn.1005-023X.2016.19.014Search in Google Scholar
[9] Y.L. Huang, Y.L. Wang, L.P. Zhang: Atmos. Environ. 42 (2008) 3740–3750. DOI:10.1016/j.atmosenv.2007.12.06310.1016/j.atmosenv.2007.12.063Search in Google Scholar
[10] J.W. Huang, Z. Li: Metallurgical industry press, Beijing (2012) 95.Search in Google Scholar
[11] J.J. Zhang, J. Hou: J. Bingtuan. Edu. 17 (2007) 34–35. DOI:10.3969/j.issn.1009-1548.2007.01.01010.3969/j.issn.1009-1548.2007.01.010Search in Google Scholar
[12] D.A. Pena, B.S. UPhade, P.G. Smirniotis: J. Catal. 221 (2004) 421–431. DOI:10.1016/j.jcat.2003.09.00310.1016/j.jcat.2003.09.003Search in Google Scholar
[13] L.H. Edelson, A.M. Glaeser: J. Am. Ceram. Soc. 71 (2005) 225– 235. DOI:10.1111/j.1151-2916.1988.tb05852.x10.1111/j.1151-2916.1988.tb05852.xSearch in Google Scholar
[14] T.F. Xu, X.D. Wu, Y.X. Gao, Q.W. Lin, J.f. Hu, D. Weng: Catal. Commun. 93 (2017) 33–36. DOI:10.1016/j.catcom.2017.01.02110.1016/j.catcom.2017.01.021Search in Google Scholar
[15] A. Katarzyna, M. Michalow, L. Ye, K. Kazimierz, G. Thomas, N. Maarten, K. Oliver, F. Davide: ACS Catal. 5 (2015) 5657–5672. DOI:10.1021/acscatal.5b0158010.1021/acscatal.5b01580Search in Google Scholar
[16] W.P. Shan, F.D. Liu, H. He, X.Y. Shi, C.B. Zhang: Appl. Catal. B-Environ. 115–116 (2012) 100–106. DOI:10.1016/j.apcatb.2011.12.01910.1016/j.apcatb.2011.12.019Search in Google Scholar
[17] P.R. Ettreddy, N. Ettreddy, S. Mamedov, P. Boolchand, G.P. Smirniotis: Appl. Catal. B-Environ. 76 (2007) 123– 134. DOI:10.1016/j.apcatb.2007.05.01010.1016/j.apcatb.2007.05.010Search in Google Scholar
[18] L. Zhang, J.F. Sun, Y. Xiong, X.Q. Zeng, C.J. Tang, L. Dong: Chin. J. Catal. 38 (2017) 1749–1758. DOI:10.1016/S1872-2067(17)62887-010.1016/S1872-2067(17)62887-0Search in Google Scholar
[19] Y. Jiang, Z.M. Xing, X.C. Wang, S.B. Huang, X.W.Wang, Q.Y. Liu: Fuel. 151 (2015) 124–129. DOI:10.1016/j.fuel.2015.01.06110.1016/j.fuel.2015.01.061Search in Google Scholar
[20] L. Chen, D. Weng, Z.C. Si, X.D. Wu: Prog. Nat. Sci. 22 (2012) 265–272. DOI:10.1016/j.pnsc.2012.07.00410.1016/j.pnsc.2012.07.004Search in Google Scholar
[21] Y. Geng, H.L. Huang, X.L. Chen, H.Y. Ding, S.J. Yang, F.D. Liu, W.P. Shan: RSC Adv. 6 (2016) 64803–64810. DOI:10.1039/c6ra06392f10.1039/c6ra06392fSearch in Google Scholar
[22] S.H. Zhan, H. Zhang, Y. Zhang, Q. Shi, Y. Li, X.J. Li: Appl. Catal. B-Environ. 203 (2017) 199–209. DOI:10.1016/j.apcatb.2016.10.01010.1016/j.apcatb.2016.10.010Search in Google Scholar
[23] X.B. Zhu, Y.L. Wang, Y. Huang, Y.X. Gai: App. Sci. 8 (2018) 2430. DOI:10.3390/app812243010.3390/app8122430Search in Google Scholar
[24] G.Y. Xie, Z.Y. Liu, Z.P. Zhu, Q.Y. Liu, J. Ge, Z.G. Huang: J. Catal. 224 (2004) 36–41. DOI:10.1016/j.jcat.2004.02.01510.1016/j.jcat.2004.02.015Search in Google Scholar
[25] M.A. Centeno, I. Carrizosa, J.A. Odriozola: Appl. Catal. B-Environ. 19 (1998) 67–73. DOI:10.1016/S0926-3373(98)00059-910.1016/S0926-3373(98)00059-9Search in Google Scholar
[26] L. Lietti, P. Forzatti, F. Bregani: Ind. Eng. Chem. Res. 35 (1996) 3884–3892. DOI:10.1021/ie960158l10.1021/ie960158lSearch in Google Scholar
[27] L. Lietti, I. Nova, P. Forzatti: Top. Catal. 11 (2000) 111–122. DOI:10.1023/A:102721761294710.1023/A:1027217612947Search in Google Scholar
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Articles in the same Issue
- Contents
- Original Contributions
- Distributions of As, Pb, Sn and Zn as minor elements between iron silicate slag and copper in equilibrium with tridymite in the Cu–Fe–O–Si system
- Short Communications
- Free vibration analysis and selection of composite for high strength and stiffness using multi-attribute decision making
- Metallurgical and wear study of MWCNT-reinforced h-AMMC fabricated through microwave hybrid sintering
- Effects of microstructure and lattice misfit on creep life of Ni-based single crystal superalloy during long-term thermal exposure
- Fracture toughness assessment at different regions in an inertial friction welded Ti-5Al-2Sn-2Zr-4Mo-4Cr alloy plate
- Microstructure and mechanical property improvement of dissimilar metal joints for TC4 Ti alloy to Nitinol NiTi alloy by laser welding
- The influence of gadolinium on Al–Ti–C master alloy and its refining effect on AZ31 magnesium alloy
- Effect of adding rare-earth cerium on the microstructure and acid rain corrosion resistance of the ADC12 alloy
- Effect of TiO2 crystal form on the denitration performance of Ce–W–Ti catalyst
- Notifications
- Deutsche Gesellschaft für Materialkunde / German Materials Science Society
Articles in the same Issue
- Contents
- Original Contributions
- Distributions of As, Pb, Sn and Zn as minor elements between iron silicate slag and copper in equilibrium with tridymite in the Cu–Fe–O–Si system
- Short Communications
- Free vibration analysis and selection of composite for high strength and stiffness using multi-attribute decision making
- Metallurgical and wear study of MWCNT-reinforced h-AMMC fabricated through microwave hybrid sintering
- Effects of microstructure and lattice misfit on creep life of Ni-based single crystal superalloy during long-term thermal exposure
- Fracture toughness assessment at different regions in an inertial friction welded Ti-5Al-2Sn-2Zr-4Mo-4Cr alloy plate
- Microstructure and mechanical property improvement of dissimilar metal joints for TC4 Ti alloy to Nitinol NiTi alloy by laser welding
- The influence of gadolinium on Al–Ti–C master alloy and its refining effect on AZ31 magnesium alloy
- Effect of adding rare-earth cerium on the microstructure and acid rain corrosion resistance of the ADC12 alloy
- Effect of TiO2 crystal form on the denitration performance of Ce–W–Ti catalyst
- Notifications
- Deutsche Gesellschaft für Materialkunde / German Materials Science Society