Startseite Comparison of thermodynamic data of the ternary Cu–Sn–Zn system, measured with the EMF and with the calorimetric method
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Comparison of thermodynamic data of the ternary Cu–Sn–Zn system, measured with the EMF and with the calorimetric method

  • Sabine Knott EMAIL logo und Adolf Mikula
Veröffentlicht/Copyright: 19. Januar 2022
Veröffentlichen auch Sie bei De Gruyter Brill
Informationen für Autor*innen
International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 97 Heft 4

Abstract

The enthalpy of mixing of the ternary Cu –Sn–Zn system was measured using a Calvet-type calorimeter. The investigations were carried out along the three cross sections Cu : Sn = 1 : 2, 1 : 1, and 2 : 1. Zn was added in the concentration range between 0 and 50 at.%.

The calorimetric results were compared with EMF data investigated in an earlier work by Peng and Mikula [1]. The results of the calorimetric measurements show very good agreement in the copper-rich region, compared with the EMF measurements, but in the Cu : Sn = 1 : 2 cross section the results do not fit perfectly. The difference between both measuring methods was at the most ΔH = 300 J/mol at the cross section Cu : Sn = 1 : 1 and ΔH = 150 J/mol at the Cu : Sn = 2 : 1 cross section.

Keywords: Cu–Sn– Zn; Calorimetry; Lead-Free
Mag. Dr. Sabine Knott Inst. für Anorganische Chemie – Materialchemie Universität Wien Währingerstr. 42, A-1090 Vienna, Austria Tel.: +43 1 4277 52913 Fax: +43 1 4277 9529

Dedicated to Prof. Dr. Ferdinand Sommer on the occasion of his 65th birthday

  1. The authors thank the Austrian Science Foundation (FWF) for financial support under the grant number: P 16491-N11.

References

[1] M. Peng, A. Mikula: J. of Alloys and Compounds 247 (1997) 185.10.1016/S0925-8388(96)02575-3Suche in Google Scholar

[2] europa.eu.int/eur-lex/pri/en/ oj/dat/2003/l_037/ l_03720030213en00190023.pdfSuche in Google Scholar

[3] D.Q. Yu, H.P. Xie, L. Wang: J. of Alloys and Compounds 385 (2004) 119.10.1016/j.jallcom.2004.04.129Suche in Google Scholar

[4] D.R. Frear, P.T. Vianco: Metall. Trans. A 25 (1995) 1509.10.1007/BF02665483Suche in Google Scholar

[5] http://elib.tu-darmstadt.de/diss/000282/Dissertation_Lambracht.pdfSuche in Google Scholar

[6] B. Trumble: IEEE Spectrum May (1998) 55.10.1109/6.669978Suche in Google Scholar

[7] D.R. Frear, P.T. Vianco: Metall. Trans. A 25 (1995) 1509.10.1007/BF02665483Suche in Google Scholar

[8] M. McCormack, S. Jin: J. Electronic Mater. 23 (1994) 715.10.1007/BF02651364Suche in Google Scholar

[9] M. Abtew, G. Selvaduray: Mater. Sci. and Eng. Σ27 5–6 (2000) 95.10.1016/S0927-796X(00)00010-3Suche in Google Scholar

[10] M. Peng, Z. Qiao, A. Mikula: CALPHAD 22(4) (1998) 549.10.1016/S0364-5916(99)00005-XSuche in Google Scholar

[11] A.T. Dinsdale: CALPHAD 15 (1991) 317.10.1016/0364-5916(91)90030-NSuche in Google Scholar

[12] S. Sugino, S. Nakamura, H. Hagiwara: J. Japan Inst. of Metals 50(5) (1986) 462.10.2320/jinstmet1952.50.5_462Suche in Google Scholar

[13] P. Nguyen-Duy, M. Rigaud: J. Chemical Thermodynamics 6(10) (1974) 999.10.1016/0021-9614(74)90222-5Suche in Google Scholar

[14] B. Predel, U. Schallner: Z. Metallkd. 63 (1972) 119.Suche in Google Scholar

[15] J. Miettinen: CALPHAD 26 (2002) 119.10.1016/S0364-5916(02)00028-7Suche in Google Scholar

[16] T. Jantzen, P.J. Spencer: CALPHAD 22(3) (1998) 417.10.1016/S0364-5916(98)00040-6Suche in Google Scholar

[17] R. Hultgren, P.S. Desaii, D.T. Hawkins, M. Gleiser, K.K. Kelley: Selected Values of the Thermodynamic Properties of binary Alloys, ASM, Metals Park, OH (1973).Suche in Google Scholar

[18] A.P. Miodownik: J. of Less-Common Metals 114 (1985) 81.10.1016/0022-5088(85)90392-3Suche in Google Scholar

[19] B. Predel, U. Schallner: Mater. Sci. Eng. 10 (1972) 249.10.1016/0025-5416(72)90096-1Suche in Google Scholar

[20] B. Predel, U. Schallner: Z. Metallkd. 63 (1972) 119.10.1515/ijmr-1972-630302Suche in Google Scholar

[21] J.-H. Shim, C.-S. Oh, B.-J. Lee, D.N. Lee: Z. Metallkd. 87 (1996) 205.10.1515/ijmr-1996-870310Suche in Google Scholar

[22] C. Luef, H. Flandorfer, H. Ipser: paper in preparationSuche in Google Scholar

[23] A. Yazawa, K. Itagaki, T. Azakami: Trans. Jpn. Inst. Met. 16(11) (1975) 687.10.2320/matertrans1960.16.687Suche in Google Scholar

[24] U. Gerling, B. Predel: Z. Metallkd. 7 (1980) 158.10.1515/ijmr-1980-710305Suche in Google Scholar

[25] G.R. Blair, D.B. Downie: Metal. Science Journal 4 (1970) 1.10.1179/030634570790444095Suche in Google Scholar

[26] K. Parameswaran, G. Healy: Met. Trans. B 9 (1978) 657.10.1007/BF03257215Suche in Google Scholar

[27] D.B. Downie, J.F. Martin: J. Chem. Thermodynamics 17 (1985) 927.10.1016/0021-9614(85)90005-9Suche in Google Scholar

[28] P.J. Spencer: CALPHAD 10 (1986) 175.10.1016/0364-5916(86)90020-9Suche in Google Scholar

[29] M. Kowalski, P.J. Spencer: J. Phase Equilibria 14 (1993) 432.10.1007/BF02671961Suche in Google Scholar

[30] O.B. Sorensen, E. Maahn: Metal. Science Nov. (1976) 385.10.1080/03063453.1976.11683561Suche in Google Scholar

[31] P. Jinturkar, Y.C. Guan, K.N. Han: Corrosion 54 (1998) 106.10.5006/1.3284833Suche in Google Scholar

[32] A. Parthasarathi, N.W. Polan: Metallurgical Transactions A 13 (1982) 2027.10.1007/BF02645948Suche in Google Scholar

[33] Z. Moser, J. Dutkiewicz, W. Gasior, J. Salawa: Bull. Alloy Phase Diagrams 6 (1985) 330.10.1007/BF02880511Suche in Google Scholar

[34] C.M. Chuang, T.S. Lui, L.H. Chen: J. Electronic Mater. 30 (2001) 1232.10.1007/s11664-001-0155-3Suche in Google Scholar

[35] K. Suganuma, K. Niihara: J. Mater. Res. 13 (1998) 2859.10.1557/JMR.1998.0391Suche in Google Scholar

Received: 2005-09-29
Accepted: 2006-01-11
Published Online: 2022-01-19

© 2006 Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Frontmatter
  2. Editorial
  3. Evolution of the mixed-mode character of solid-state phase transformations in metals involving solute partitioning
  4. Liquid–liquid interfacial tension in themonotectic alloy (Al34.5Bi65.5)95Si5 (wt.%)
  5. Influence of Sb additions on surface tension and density of Sn–Sb, Sn–Ag–Sb and Sn–Ag–Cu–Sb alloys: Experiment vs. modeling
  6. Liquid–liquid transition in elemental liquids investigated by sound velocity measurements: trends in the periodic table
  7. Bulk and surface properties of liquid Ga–Tl and Zn–Cd alloys
  8. Structure-induced order – disorder transformation in Cd – Na liquid alloys
  9. An indirect approach to measure glass transition temperature in metallic glasses
  10. Fragility, kinetic stability and phase separations in the undercooled state of bulk glass formers – a case study on metallic model systems
  11. Development of long-period ordered structures during crystallisation of amorphous Mg80Cu10Y10 and Mg83Ni9Y8
  12. Isothermal crystallization behavior of undercooled liquid Pd40Cu30Ni10P20 in terms of crystal growth, overall volume crystallization kinetics and their relation to the viscosity temperature dependence
  13. The magnesium-ytterbium system: A contribution to the thermodynamics of solid alloys
  14. Experimental investigation and thermodynamic modelling of the Mg–Al-rich region of the Mg–Al–Sr System
  15. Thermodynamic properties and phase relations of Zn-rich alloys in the system Pt–Zn
  16. Comparison of thermodynamic data of the ternary Cu–Sn–Zn system, measured with the EMF and with the calorimetric method
  17. Analysis of phase formation in Ni-rich alloys of the Ni–Ta–W system by calorimetry, DTA, SEM, and TEM
  18. Site preference, thermodynamic, and magnetic properties of the ternary Laves phase Ti(Fe1 – xAlx)2 with the crystal structure of the MgZn2-type
  19. Activity measurements on the Al-rich region of the Ni–Al system – A high temperature mass spectrometric study
  20. Metastable phases and nanocrystalline-forming ability (NFA) of melt-quenched Ni-rich (Zr, Hf)–Ni alloys
  21. Low temperature deposition with inductively coupled plasma
  22. Instructions for Authors
  23. Personal/Personelles
  24. Press/Presse
  25. Conferences/Konferenzen
  26. Frontmatter
  27. Editorial
  28. Editorial
  29. BBasic
  30. Evolution of the mixed-mode character of solid-state phase transformations in metals involving solute partitioning
  31. Liquid–liquid interfacial tension in themonotectic alloy (Al34.5Bi65.5)95Si5 (wt.%)
  32. Influence of Sb additions on surface tension and density of Sn–Sb, Sn–Ag–Sb and Sn–Ag–Cu–Sb alloys: Experiment vs. modeling
  33. Liquid–liquid transition in elemental liquids investigated by sound velocity measurements: trends in the periodic table
  34. Bulk and surface properties of liquid Ga–Tl and Zn–Cd alloys
  35. Structure-induced order – disorder transformation in Cd – Na liquid alloys
  36. An indirect approach to measure glass transition temperature in metallic glasses
  37. Fragility, kinetic stability and phase separations in the undercooled state of bulk glass formers – a case study on metallic model systems
  38. Development of long-period ordered structures during crystallisation of amorphous Mg80Cu10Y10 and Mg83Ni9Y8
  39. Isothermal crystallization behavior of undercooled liquid Pd40Cu30Ni10P20 in terms of crystal growth, overall volume crystallization kinetics and their relation to the viscosity temperature dependence
  40. The magnesium-ytterbium system: A contribution to the thermodynamics of solid alloys
  41. Experimental investigation and thermodynamic modelling of the Mg–Al-rich region of the Mg–Al–Sr System
  42. Thermodynamic properties and phase relations of Zn-rich alloys in the system Pt–Zn
  43. Comparison of thermodynamic data of the ternary Cu–Sn–Zn system, measured with the EMF and with the calorimetric method
  44. Analysis of phase formation in Ni-rich alloys of the Ni–Ta–W system by calorimetry, DTA, SEM, and TEM
  45. Site preference, thermodynamic, and magnetic properties of the ternary Laves phase Ti(Fe1 – xAlx)2 with the crystal structure of the MgZn2-type
  46. Activity measurements on the Al-rich region of the Ni–Al system – A high temperature mass spectrometric study
  47. Metastable phases and nanocrystalline-forming ability (NFA) of melt-quenched Ni-rich (Zr, Hf)–Ni alloys
  48. AApplied
  49. Low temperature deposition with inductively coupled plasma
  50. Notifications/Mitteilungen
  51. Instructions for Authors
  52. Personal/Personelles
  53. Press/Presse
  54. Conferences/Konferenzen
https://doi.org/10.1515/ijmr-2006-0072
Schlagwörter für diesen Artikel
Cu–Sn– Zn; Calorimetry; Lead-Free

Artikel in diesem Heft

  1. Frontmatter
  2. Editorial
  3. Evolution of the mixed-mode character of solid-state phase transformations in metals involving solute partitioning
  4. Liquid–liquid interfacial tension in themonotectic alloy (Al34.5Bi65.5)95Si5 (wt.%)
  5. Influence of Sb additions on surface tension and density of Sn–Sb, Sn–Ag–Sb and Sn–Ag–Cu–Sb alloys: Experiment vs. modeling
  6. Liquid–liquid transition in elemental liquids investigated by sound velocity measurements: trends in the periodic table
  7. Bulk and surface properties of liquid Ga–Tl and Zn–Cd alloys
  8. Structure-induced order – disorder transformation in Cd – Na liquid alloys
  9. An indirect approach to measure glass transition temperature in metallic glasses
  10. Fragility, kinetic stability and phase separations in the undercooled state of bulk glass formers – a case study on metallic model systems
  11. Development of long-period ordered structures during crystallisation of amorphous Mg80Cu10Y10 and Mg83Ni9Y8
  12. Isothermal crystallization behavior of undercooled liquid Pd40Cu30Ni10P20 in terms of crystal growth, overall volume crystallization kinetics and their relation to the viscosity temperature dependence
  13. The magnesium-ytterbium system: A contribution to the thermodynamics of solid alloys
  14. Experimental investigation and thermodynamic modelling of the Mg–Al-rich region of the Mg–Al–Sr System
  15. Thermodynamic properties and phase relations of Zn-rich alloys in the system Pt–Zn
  16. Comparison of thermodynamic data of the ternary Cu–Sn–Zn system, measured with the EMF and with the calorimetric method
  17. Analysis of phase formation in Ni-rich alloys of the Ni–Ta–W system by calorimetry, DTA, SEM, and TEM
  18. Site preference, thermodynamic, and magnetic properties of the ternary Laves phase Ti(Fe1 – xAlx)2 with the crystal structure of the MgZn2-type
  19. Activity measurements on the Al-rich region of the Ni–Al system – A high temperature mass spectrometric study
  20. Metastable phases and nanocrystalline-forming ability (NFA) of melt-quenched Ni-rich (Zr, Hf)–Ni alloys
  21. Low temperature deposition with inductively coupled plasma
  22. Instructions for Authors
  23. Personal/Personelles
  24. Press/Presse
  25. Conferences/Konferenzen
  26. Frontmatter
  27. Editorial
  28. Editorial
  29. BBasic
  30. Evolution of the mixed-mode character of solid-state phase transformations in metals involving solute partitioning
  31. Liquid–liquid interfacial tension in themonotectic alloy (Al34.5Bi65.5)95Si5 (wt.%)
  32. Influence of Sb additions on surface tension and density of Sn–Sb, Sn–Ag–Sb and Sn–Ag–Cu–Sb alloys: Experiment vs. modeling
  33. Liquid–liquid transition in elemental liquids investigated by sound velocity measurements: trends in the periodic table
  34. Bulk and surface properties of liquid Ga–Tl and Zn–Cd alloys
  35. Structure-induced order – disorder transformation in Cd – Na liquid alloys
  36. An indirect approach to measure glass transition temperature in metallic glasses
  37. Fragility, kinetic stability and phase separations in the undercooled state of bulk glass formers – a case study on metallic model systems
  38. Development of long-period ordered structures during crystallisation of amorphous Mg80Cu10Y10 and Mg83Ni9Y8
  39. Isothermal crystallization behavior of undercooled liquid Pd40Cu30Ni10P20 in terms of crystal growth, overall volume crystallization kinetics and their relation to the viscosity temperature dependence
  40. The magnesium-ytterbium system: A contribution to the thermodynamics of solid alloys
  41. Experimental investigation and thermodynamic modelling of the Mg–Al-rich region of the Mg–Al–Sr System
  42. Thermodynamic properties and phase relations of Zn-rich alloys in the system Pt–Zn
  43. Comparison of thermodynamic data of the ternary Cu–Sn–Zn system, measured with the EMF and with the calorimetric method
  44. Analysis of phase formation in Ni-rich alloys of the Ni–Ta–W system by calorimetry, DTA, SEM, and TEM
  45. Site preference, thermodynamic, and magnetic properties of the ternary Laves phase Ti(Fe1 – xAlx)2 with the crystal structure of the MgZn2-type
  46. Activity measurements on the Al-rich region of the Ni–Al system – A high temperature mass spectrometric study
  47. Metastable phases and nanocrystalline-forming ability (NFA) of melt-quenched Ni-rich (Zr, Hf)–Ni alloys
  48. AApplied
  49. Low temperature deposition with inductively coupled plasma
  50. Notifications/Mitteilungen
  51. Instructions for Authors
  52. Personal/Personelles
  53. Press/Presse
  54. Conferences/Konferenzen
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 20.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ijmr-2006-0072/html?lang=de
Button zum nach oben scrollen