Startseite Evolution of the mixed-mode character of solid-state phase transformations in metals involving solute partitioning
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Evolution of the mixed-mode character of solid-state phase transformations in metals involving solute partitioning

  • Jilt Sietsma EMAIL logo , M. Giuseppina Mecozzi , Stefan M. C. van Bohemen und Sybrand van der Zwaag
Veröffentlicht/Copyright: 19. Januar 2022
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International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 97 Heft 4

Abstract

Partitioning phase transformations in the solid state are principally subjected to two processes that take place: the redistribution, through long-range diffusion, of the partitioning element, and the lattice transformation taking place at the interface. Consequently, the usual approximation to consider one of these two processes as controlling the rate of the phase transformation is of limited accuracy. For a more accurate description, the so-called mixed-mode character of partitioning phase transformations is to be taken into account. In the present study, it is shown that the mixed-mode character can be quantified and that it has a significant effect on the kinetics. By means of examples involving either substitutional (Mo in Ti) or interstitial (C in Fe) partitioning elements, it is shown that a gradual change of the character of the transformation occurs during the phase transformation, shifting from initially interface-controlled (which implies the largest interface velocity) towards more diffusion-controlled.

Keywords: Solid-state phase transformation; Solute partitioning; Mixed-mode character
Dr. Ir. Jilt Sietsma Delft University of Technology Dept. of Materials Science & Enineering Rotterdamseweg 137 NL-2628 AL Delft, the Netherlands Tel.: +31 15 278 2284 Fax: +31 15 278 6730 Email:

Dedicated to Prof. Dr. Ferdinand Sommer on the occasion of his 65th birthday

  1. The authors acknowledge the valuable contributions during a long and distinguished career made by Prof. Sommer to the field of physical metallurgy. One of us (JS) also acknowledges the highly appreciated personal contacts with Prof. Sommer.

  2. We acknowledge financial support by the European Union for part of the work presented here.

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Received: 2005-11-08
Accepted: 2005-11-24
Published Online: 2022-01-19

© 2006 Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Frontmatter
  2. Editorial
  3. Evolution of the mixed-mode character of solid-state phase transformations in metals involving solute partitioning
  4. Liquid–liquid interfacial tension in themonotectic alloy (Al34.5Bi65.5)95Si5 (wt.%)
  5. Influence of Sb additions on surface tension and density of Sn–Sb, Sn–Ag–Sb and Sn–Ag–Cu–Sb alloys: Experiment vs. modeling
  6. Liquid–liquid transition in elemental liquids investigated by sound velocity measurements: trends in the periodic table
  7. Bulk and surface properties of liquid Ga–Tl and Zn–Cd alloys
  8. Structure-induced order – disorder transformation in Cd – Na liquid alloys
  9. An indirect approach to measure glass transition temperature in metallic glasses
  10. Fragility, kinetic stability and phase separations in the undercooled state of bulk glass formers – a case study on metallic model systems
  11. Development of long-period ordered structures during crystallisation of amorphous Mg80Cu10Y10 and Mg83Ni9Y8
  12. Isothermal crystallization behavior of undercooled liquid Pd40Cu30Ni10P20 in terms of crystal growth, overall volume crystallization kinetics and their relation to the viscosity temperature dependence
  13. The magnesium-ytterbium system: A contribution to the thermodynamics of solid alloys
  14. Experimental investigation and thermodynamic modelling of the Mg–Al-rich region of the Mg–Al–Sr System
  15. Thermodynamic properties and phase relations of Zn-rich alloys in the system Pt–Zn
  16. Comparison of thermodynamic data of the ternary Cu–Sn–Zn system, measured with the EMF and with the calorimetric method
  17. Analysis of phase formation in Ni-rich alloys of the Ni–Ta–W system by calorimetry, DTA, SEM, and TEM
  18. Site preference, thermodynamic, and magnetic properties of the ternary Laves phase Ti(Fe1 – xAlx)2 with the crystal structure of the MgZn2-type
  19. Activity measurements on the Al-rich region of the Ni–Al system – A high temperature mass spectrometric study
  20. Metastable phases and nanocrystalline-forming ability (NFA) of melt-quenched Ni-rich (Zr, Hf)–Ni alloys
  21. Low temperature deposition with inductively coupled plasma
  22. Instructions for Authors
  23. Personal/Personelles
  24. Press/Presse
  25. Conferences/Konferenzen
  26. Frontmatter
  27. Editorial
  28. Editorial
  29. BBasic
  30. Evolution of the mixed-mode character of solid-state phase transformations in metals involving solute partitioning
  31. Liquid–liquid interfacial tension in themonotectic alloy (Al34.5Bi65.5)95Si5 (wt.%)
  32. Influence of Sb additions on surface tension and density of Sn–Sb, Sn–Ag–Sb and Sn–Ag–Cu–Sb alloys: Experiment vs. modeling
  33. Liquid–liquid transition in elemental liquids investigated by sound velocity measurements: trends in the periodic table
  34. Bulk and surface properties of liquid Ga–Tl and Zn–Cd alloys
  35. Structure-induced order – disorder transformation in Cd – Na liquid alloys
  36. An indirect approach to measure glass transition temperature in metallic glasses
  37. Fragility, kinetic stability and phase separations in the undercooled state of bulk glass formers – a case study on metallic model systems
  38. Development of long-period ordered structures during crystallisation of amorphous Mg80Cu10Y10 and Mg83Ni9Y8
  39. Isothermal crystallization behavior of undercooled liquid Pd40Cu30Ni10P20 in terms of crystal growth, overall volume crystallization kinetics and their relation to the viscosity temperature dependence
  40. The magnesium-ytterbium system: A contribution to the thermodynamics of solid alloys
  41. Experimental investigation and thermodynamic modelling of the Mg–Al-rich region of the Mg–Al–Sr System
  42. Thermodynamic properties and phase relations of Zn-rich alloys in the system Pt–Zn
  43. Comparison of thermodynamic data of the ternary Cu–Sn–Zn system, measured with the EMF and with the calorimetric method
  44. Analysis of phase formation in Ni-rich alloys of the Ni–Ta–W system by calorimetry, DTA, SEM, and TEM
  45. Site preference, thermodynamic, and magnetic properties of the ternary Laves phase Ti(Fe1 – xAlx)2 with the crystal structure of the MgZn2-type
  46. Activity measurements on the Al-rich region of the Ni–Al system – A high temperature mass spectrometric study
  47. Metastable phases and nanocrystalline-forming ability (NFA) of melt-quenched Ni-rich (Zr, Hf)–Ni alloys
  48. AApplied
  49. Low temperature deposition with inductively coupled plasma
  50. Notifications/Mitteilungen
  51. Instructions for Authors
  52. Personal/Personelles
  53. Press/Presse
  54. Conferences/Konferenzen
https://doi.org/10.1515/ijmr-2006-0059
Schlagwörter für diesen Artikel
Solid-state phase transformation; Solute partitioning; Mixed-mode character

Artikel in diesem Heft

  1. Frontmatter
  2. Editorial
  3. Evolution of the mixed-mode character of solid-state phase transformations in metals involving solute partitioning
  4. Liquid–liquid interfacial tension in themonotectic alloy (Al34.5Bi65.5)95Si5 (wt.%)
  5. Influence of Sb additions on surface tension and density of Sn–Sb, Sn–Ag–Sb and Sn–Ag–Cu–Sb alloys: Experiment vs. modeling
  6. Liquid–liquid transition in elemental liquids investigated by sound velocity measurements: trends in the periodic table
  7. Bulk and surface properties of liquid Ga–Tl and Zn–Cd alloys
  8. Structure-induced order – disorder transformation in Cd – Na liquid alloys
  9. An indirect approach to measure glass transition temperature in metallic glasses
  10. Fragility, kinetic stability and phase separations in the undercooled state of bulk glass formers – a case study on metallic model systems
  11. Development of long-period ordered structures during crystallisation of amorphous Mg80Cu10Y10 and Mg83Ni9Y8
  12. Isothermal crystallization behavior of undercooled liquid Pd40Cu30Ni10P20 in terms of crystal growth, overall volume crystallization kinetics and their relation to the viscosity temperature dependence
  13. The magnesium-ytterbium system: A contribution to the thermodynamics of solid alloys
  14. Experimental investigation and thermodynamic modelling of the Mg–Al-rich region of the Mg–Al–Sr System
  15. Thermodynamic properties and phase relations of Zn-rich alloys in the system Pt–Zn
  16. Comparison of thermodynamic data of the ternary Cu–Sn–Zn system, measured with the EMF and with the calorimetric method
  17. Analysis of phase formation in Ni-rich alloys of the Ni–Ta–W system by calorimetry, DTA, SEM, and TEM
  18. Site preference, thermodynamic, and magnetic properties of the ternary Laves phase Ti(Fe1 – xAlx)2 with the crystal structure of the MgZn2-type
  19. Activity measurements on the Al-rich region of the Ni–Al system – A high temperature mass spectrometric study
  20. Metastable phases and nanocrystalline-forming ability (NFA) of melt-quenched Ni-rich (Zr, Hf)–Ni alloys
  21. Low temperature deposition with inductively coupled plasma
  22. Instructions for Authors
  23. Personal/Personelles
  24. Press/Presse
  25. Conferences/Konferenzen
  26. Frontmatter
  27. Editorial
  28. Editorial
  29. BBasic
  30. Evolution of the mixed-mode character of solid-state phase transformations in metals involving solute partitioning
  31. Liquid–liquid interfacial tension in themonotectic alloy (Al34.5Bi65.5)95Si5 (wt.%)
  32. Influence of Sb additions on surface tension and density of Sn–Sb, Sn–Ag–Sb and Sn–Ag–Cu–Sb alloys: Experiment vs. modeling
  33. Liquid–liquid transition in elemental liquids investigated by sound velocity measurements: trends in the periodic table
  34. Bulk and surface properties of liquid Ga–Tl and Zn–Cd alloys
  35. Structure-induced order – disorder transformation in Cd – Na liquid alloys
  36. An indirect approach to measure glass transition temperature in metallic glasses
  37. Fragility, kinetic stability and phase separations in the undercooled state of bulk glass formers – a case study on metallic model systems
  38. Development of long-period ordered structures during crystallisation of amorphous Mg80Cu10Y10 and Mg83Ni9Y8
  39. Isothermal crystallization behavior of undercooled liquid Pd40Cu30Ni10P20 in terms of crystal growth, overall volume crystallization kinetics and their relation to the viscosity temperature dependence
  40. The magnesium-ytterbium system: A contribution to the thermodynamics of solid alloys
  41. Experimental investigation and thermodynamic modelling of the Mg–Al-rich region of the Mg–Al–Sr System
  42. Thermodynamic properties and phase relations of Zn-rich alloys in the system Pt–Zn
  43. Comparison of thermodynamic data of the ternary Cu–Sn–Zn system, measured with the EMF and with the calorimetric method
  44. Analysis of phase formation in Ni-rich alloys of the Ni–Ta–W system by calorimetry, DTA, SEM, and TEM
  45. Site preference, thermodynamic, and magnetic properties of the ternary Laves phase Ti(Fe1 – xAlx)2 with the crystal structure of the MgZn2-type
  46. Activity measurements on the Al-rich region of the Ni–Al system – A high temperature mass spectrometric study
  47. Metastable phases and nanocrystalline-forming ability (NFA) of melt-quenched Ni-rich (Zr, Hf)–Ni alloys
  48. AApplied
  49. Low temperature deposition with inductively coupled plasma
  50. Notifications/Mitteilungen
  51. Instructions for Authors
  52. Personal/Personelles
  53. Press/Presse
  54. Conferences/Konferenzen
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