Abstract
The magnetic properties of hard magnetic materials are closely connected to their microstructure. The complexity of this correlation is demonstrated for the two most promising permanent magnet (pm) materials at present, namely nanocrystalline RE2Fe14B (RE = Nd,Pr) and nanostructured Sm2(Co, Cu, Fe, Zr)17. In both cases the detailed analysis of the microstructure – property interaction by means of different high-resolution electron microscopy techniques, hysteresis loop measurements and the theory of micromagnetism results in a quantitative interpretation of the occurring hardening mechanisms, enabling a quite specific tailoring of optimized magnetic properties up to elevated temperatures.
Abstract
Die magnetischen Eigenschaften von hartmagnetischen Werkstoffen sind eng mit ihrer Mikrostruktur verknüpft. Dieser Zusammenhang soll im Folgenden am Beispiel von zwei leistungsfähigen Dauermagnetwerkstoffen aufgezeigt werden – nanokristallines RE2Fe14B (RE = Nd,Pr) und nanostrukturiertes Sm2(Co, Cu, Fe, Zr)17. In beiden Fällen ist es unter Ausnutzung von verschiedenen hochauflösenden Elektronenmikroskopie-Methoden und magnetischen Hysteresemessungen sowie der Theorie des Mikromagnetismus gelungen, den jeweils zugrunde liegenden Härtungsmechanismus quantitativ zu verstehen. Dies ermöglicht bis zu hohen Temperaturen ein gezieltes Maßschneidern von optimalen magnetischen Kenngrößen.
Dedicated to Professor Dr. Helmut Kronmüller on the occasion of his 70th birthday
References
1 Strnat, K.J.; Hoffer, G.; Olsen, J.C.; Ostertag, W.; Becker, J.J.: J. Appl. Phys. 38 (1967) 1001.10.1063/1.1709459Search in Google Scholar
2 Croat, J.J.; Herbst, J.F.; Lee, R.W.; Pinkerton, F.E.: J. Appl. Phys. 55 (1984) 2078.10.1063/1.333571Search in Google Scholar
3 Sagawa, M.; Fujimura, S.; Togawa, M.; Matsuura, Y.: J. Appl. Phys. 55 (1984) 2083.10.1063/1.333572Search in Google Scholar
4 Hadjipanayis, G.C.; Hazzleton, R.C.; Lawless, K.R.: J. Appl. Phys. 55 (1984) 2073.10.1063/1.333570Search in Google Scholar
5 Buschow, K.H.J., in: K.H.J. Buschow (ed.), Handbook of Magnetic Materials, Vol. 10, Elsevier, North-Holland, Amsterdam (1997) 463.10.1016/S1567-2719(97)10008-7Search in Google Scholar
6 Chen, C.H.; Walmer, M.S.; Walmer, M.H.; Liu, S.; Kuhl, E.; Simon, G.: J. Appl. Phys. 83 (1998) 6706.10.1063/1.367937Search in Google Scholar
7 Hadjipanayis, G.C.; Tang, W.; Zhang, Y.; Chui, S.T.; Liu, J.F.; Chen, C.; Kronmüller, H.: IEEE Trans. Magn. 36 (2000) 3382.10.1109/20.908808Search in Google Scholar
8 Kronmüller, H., in: G.J. Long, F. Grandjean (eds.), Supermagnets, Hard Magnetic Materials, Kluwer Academic Publishers, Dordrecht (1991) 461.10.1007/978-94-011-3324-1_19Search in Google Scholar
9 Kronmüller, H.: Phys. Stat. Sol. (b) 144 (1987) 358.10.1002/pssb.2221440134Search in Google Scholar
10 Sagawa, M.; Hirosawa, S.: J. Phys. (Paris) Coll. 49 (1987) 617.10.1051/jphyscol:19888282Search in Google Scholar
11 Brown, Jr., W.F.: Rev. Mod. Phys. 17 (1945) 15.10.1103/RevModPhys.17.15Search in Google Scholar
12 Manaf, A.; Buckley, R.A.; Davies, H.A.; Leonowicz, M.: J. Magn. Magn. Mater. 101 (1991) 360.10.1016/0304-8853(91)90779-ASearch in Google Scholar
13 Bauer, J.; Seeger, M.; Zern, A.; Kronmüller, H.: J. Appl. Phys. 80 (1996) 1667.10.1063/1.362965Search in Google Scholar
14 Goll, D.; Seeger, M.; Kronmüller, H.: J. Magn. Magn. Mater. 185 (1998) 49.10.1016/S0304-8853(98)00030-4Search in Google Scholar
15 Kneller, E.F.; Hawig, R.: IEEE Trans. Magn. 27 (1991) 3588.10.1109/20.102931Search in Google Scholar
16 Gong, W.; Hadjipanayis, G.C.; Krause, R.I.: J. Appl. Phys. 75 (1994) 6649.10.1063/1.356883Search in Google Scholar
17 Goll, D.; Kronmüller, H.: Naturwissenschaften 87 (2000) 423.10.1007/s001140050755Search in Google Scholar
18 Kronmüller, H.; Fischer, R.; Bachmann, M.; Leineweber, T.: J. Magn. Magn. Mater. 203 (1999) 12.10.1016/S0304-8853(99)00184-5Search in Google Scholar
19 Kronmüller, H.; Goll, D.; Kleinschroth, I.; Zern, A.: Mat. Res. Soc. Symp. Proc. 577 (1999) 303.10.1557/PROC-577-303Search in Google Scholar
20 Kronmüller, H.; Fischer, R.; Seeger, M.; Zern, A.: J. Phys. D 29 (1996) 2274.10.1088/0022-3727/29/9/008Search in Google Scholar
21 Goll, D.; Kleinschroth, I.; Kronmüller, H., in: H. Kaneko, M. Homma, M. Okada (eds.), Proc. 16th Int. Workshop on REM and Their Applications, The Japan Institute of Metals, Sendai (2000) 641.Search in Google Scholar
22 Neu, V.; Hubert, A.; Schultz, L.: J. Magn. Magn. Mater. 189 (1998) 391.10.1016/S0304-8853(98)00295-9Search in Google Scholar
23 Fischer, R.; Kronmüller, H.: J. Magn. Magn. Mater. 153 (1996) 35.10.1016/0304-8853(95)00494-7Search in Google Scholar
24 Fischer, R.; Kronmüller, H.: J. Magn. Magn. Mater. 184 (1998) 166.10.1016/S0304-8853(97)01139-6Search in Google Scholar
25 Fischer, R.; Kronmüller, H.: Phys. Stat. Sol. (a) 166 (1998) 489.10.1002/(SICI)1521-396X(199803)166:1<489::AID-PSSA489>3.0.CO;2-SSearch in Google Scholar
26 Goll, D.; Sigle,W.; Hadjipanayis, G.C.; Kronmüller, H.: Mat. Res. Soc. Symp. Proc. 674 (2001) U.2.4.10.1557/PROC-674-U2.4Search in Google Scholar
27 Strnat, K.: IEEE Trans. Magn. 8 (1972) 511.10.1109/TMAG.1972.1067368Search in Google Scholar
28 Livingston, J.D.; Martin, D.L.: J. Appl. Phys. 48 (1977) 1350.10.1063/1.323729Search in Google Scholar
29 Hadjipanayis, G.C., in: J. Fidler (ed.) Proc. 6th Int. Workshop on RE-Co Magnets and Their Applications, Technical University of Vienna (1982) 609.Search in Google Scholar
30 Fidler, J.: J. Magn. Magn. Mater. 30 (1982) 58.10.1016/0304-8853(82)90010-5Search in Google Scholar
31 Kronmüller, H.; Durst, K.-D.; Ervens, W.; Fernengel, F.: IEEE Trans. Magn. 20 (1984) 1569.10.1109/TMAG.1984.1063213Search in Google Scholar
32 Goll, D.; Kleinschroth, I.; Sigle, W.; Kronmüller, H.: Appl. Phys. Lett. 76 (2000) 1054.10.1063/1.125936Search in Google Scholar
33 Goll, D.; Sigle, W., Hadjipanayis, G.C.; Kronmüller, H., in: As Ref. [21], p. 61.Search in Google Scholar
34 Katter, M.; Weber, J.; Assmus, W.; Schrey, P.; Rodewald, W.: IEEE Trans. Magn. 32 (1996) 4815.10.1109/20.539161Search in Google Scholar
35 Delannay, F.; Derkaoui, S.; Allibert, C.: J. Less-Comm. Met. 134 (1987) 249.10.1016/0022-5088(87)90565-0Search in Google Scholar
36 Kronmüller, H.; Durst, K.-D.; Sagawa, M.: J. Magn. Magn. Mater. 74 (1988) 291.10.1016/0304-8853(88)90202-8Search in Google Scholar
37 Lectard, E.; Allibert, C.H.; Ballou, R.: J. Appl. Phys. 75 (1994) 6277.10.1063/1.355423Search in Google Scholar
38 Kronmüller, H.; Goll, D.: Physica B 319 (2002) 122.10.1016/S0921-4526(02)01113-4Search in Google Scholar
39 Tellez-Blanco, J.C.; Kou, X.C.; Grössinger, R.; Estevez-Rams, E.; Fidler, J.; Ma, B.M., in: F.P. Missell et al. (eds.), Proc. 14th Int. Workshop on RE-Magnets and Their Applications, World Scientific Publishing, Singapore, New Jersey, London, Hong Kong (1996) 707.Search in Google Scholar
© 2002 Carl Hanser Verlag, München
Articles in the same Issue
- Frontmatter
- Editorial
- Editorial
- Articles/Aufsätze
- Interplay between chemical and magnetic roughness of Pt in a Pt/Co bilayer investigated with X-ray resonant magnetic reflectometry
- Thermal stability and magnetic anisotropy dispersion in high-density hard-disk media
- Thickness dependence of magnetization structures in thin Permalloy rectangles
- Solving the selectivity problem in magnetic random access memories using configurations that form C-states
- Second-order magnetoelastic effects: From the Dirac equation to the magnetic properties of ultrathin epitaxial films for magnetic thin-film applications
- Magnetic relaxation in nanocrystalline systems: linking Monte Carlo steps with time
- Effect of domain size on the magneto-elastic damping in amorphous ferromagnetic metals
- The character and role of grain boundaries in NdFeB-type alloys and magnets
- Magnetic domain structure and spin reorientation process
- Magnetic properties of Tb(Fe, Mo)12 and Tb(Fe, Mo)12C compounds
- Microstructure, magnetic properties and magnetic hardening in 2 : 17 Sm–Co magnets
- Micromagnetism and microstructure – tailoring of high-performance permanent magnets
- Metastable alloys at moderate cooling rates
- Thermal critical phenomena and crossover between critical regimes in ferromagnets with long-range interactions
- Vacancies in thermal equilibrium and ferromagnetism near the Curie temperature
- The vortex lattice in superconductors
- Functional substrates – a novel approach to tailor transport properties and flux-line pinning in YBa2Cu3O7 – x thin films
- Superconducting permanent magnets and their application in magnetic levitation
- Magneto-optical studies of flux pinning in high-temperature superconductors
- Atomic transport in amorphous metals
- A novel technique for measuring diffusivities of short-lived radioisotopes in solids
- Hydrogen four-level tunnel systems in substitutional body-centred cubic alloys
- Magnetic relaxation phenomena in cobalt
- The Verwey transition in magnetite as studied by means of definite impurity doping
- Notifications/Mitteilungen
- Personal/Personelles
- Bücher/Books
- Conferences/Konferenzen
- DGM Training/DGM Fortbildung
Articles in the same Issue
- Frontmatter
- Editorial
- Editorial
- Articles/Aufsätze
- Interplay between chemical and magnetic roughness of Pt in a Pt/Co bilayer investigated with X-ray resonant magnetic reflectometry
- Thermal stability and magnetic anisotropy dispersion in high-density hard-disk media
- Thickness dependence of magnetization structures in thin Permalloy rectangles
- Solving the selectivity problem in magnetic random access memories using configurations that form C-states
- Second-order magnetoelastic effects: From the Dirac equation to the magnetic properties of ultrathin epitaxial films for magnetic thin-film applications
- Magnetic relaxation in nanocrystalline systems: linking Monte Carlo steps with time
- Effect of domain size on the magneto-elastic damping in amorphous ferromagnetic metals
- The character and role of grain boundaries in NdFeB-type alloys and magnets
- Magnetic domain structure and spin reorientation process
- Magnetic properties of Tb(Fe, Mo)12 and Tb(Fe, Mo)12C compounds
- Microstructure, magnetic properties and magnetic hardening in 2 : 17 Sm–Co magnets
- Micromagnetism and microstructure – tailoring of high-performance permanent magnets
- Metastable alloys at moderate cooling rates
- Thermal critical phenomena and crossover between critical regimes in ferromagnets with long-range interactions
- Vacancies in thermal equilibrium and ferromagnetism near the Curie temperature
- The vortex lattice in superconductors
- Functional substrates – a novel approach to tailor transport properties and flux-line pinning in YBa2Cu3O7 – x thin films
- Superconducting permanent magnets and their application in magnetic levitation
- Magneto-optical studies of flux pinning in high-temperature superconductors
- Atomic transport in amorphous metals
- A novel technique for measuring diffusivities of short-lived radioisotopes in solids
- Hydrogen four-level tunnel systems in substitutional body-centred cubic alloys
- Magnetic relaxation phenomena in cobalt
- The Verwey transition in magnetite as studied by means of definite impurity doping
- Notifications/Mitteilungen
- Personal/Personelles
- Bücher/Books
- Conferences/Konferenzen
- DGM Training/DGM Fortbildung