Abstract
In this study, the treatability of metal-plating waste water by modified direct contact membrane distillation (DCMD) at different temperature differences (∆T = 30°C, 40°C, 50°C, and 55°C was investigated. Two different hydrophobic membranes made of poly(tetrafluoroethylene) (PTFE) and poly(vinylidene fluoride) (PVDF) having different pore sizes (0.22 μm and 0.45 μm) were used. The results indicated that conductivity, COD, sulphate, copper, and nickel could be successfully removed by modified DCMD. The rejection efficiencies for conductivity, COD, and sulphate were 99 %, 86 %, and 99 %, respectively. Copper rejection was effective with both membranes while nickel concentration was below the limit of detection in the effluent. It was found that the pollutant rejection efficiency was affected by the raw water characteristics, membrane properties, and influent heating temperatures. In addition to the water quality parameters, the flux was measured to evaluate membrane performance. A high flux was obtained at 65°C (∆T = 55°C) with 0.45 μm pore size PTFE membrane (24.1 L m−2 h−1) and with PVDF membrane (17.1 L m−2 h−1). The flux was mainly affected by temperature and membrane properties. As a result, modified DCMD and all the membranes used in this study were effective for the treatment of metal-plating waste water.
Acknowledgements
This study was financially supported by Yildiz Technical University Scientific Research Projects Fund (Research Project no. 2013-05-02-KAP09) and the Turkish Academy of Science.
References
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© 2016 Institute of Chemistry, Slovak Academy of Sciences
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- Review
- Plant extracts as “green” corrosion inhibitors for steel in sulphuric acid
- Original Paper
- Use of 6-O-mono-substituted derivatives of β-cyclodextrin-bearing substituent with two permanent positive charges in capillary electrophoresis
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- Original Paper
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- Original Paper
- Preparation of corn stalk-based adsorbents and their specific application in metal ions adsorption
- Original Paper
- Treatment of metal-plating waste water by modified direct contact membrane distillation
- Original Paper
- Influence of pH and cationic surfactant on stability and interfacial properties of algerian bitumen emulsion
- Original Paper
- Synthesis, structural and spectroscopic properties of asymmetric schiff bases derived from 2,3-diaminopyridine
- Original Paper
- Syntheses of cardanol-based cationic surfactants and their use in emulsion polymerisation
- Original Paper
- Synthesis of urethane—acrylic multi-block copolymers via electrochemically mediated ATRP
- Original Paper
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- Leaching test for calcined kaolinite and kaolinite/TiO2 photoactive composite
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