Startseite Synthesis of urethane—acrylic multi-block copolymers via electrochemically mediated ATRP
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Synthesis of urethane—acrylic multi-block copolymers via electrochemically mediated ATRP

  • Pawel Chmielarz EMAIL logo und Andrzej Sobkowiak
Veröffentlicht/Copyright: 22. April 2016
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Chemical Papers
Aus der Zeitschrift Chemical Papers Band 70 Heft 9

Abstract

The electrochemically mediated atom transfer radical polymerisation (eATRP) of n-butyl acrylate was investigated under a variety of catalyst concentrations. Poly(n-butyl acry late)- block-polyurethane-block-poly (n-butyl acrylate) copolymers were prepared via electrochemically mediated atom transfer radical polymerisation (eATRP) using only 7 × 10–6 mole % of CuII complex. The successful chain extension and formation of penta-block copolymers confirmed the living nature of the poly(alkyl acrylates) prepared by eATRP. In this work, the tri-block and penta-block urethane-acrylate copolymers were synthesised for the first time by using tertiary bromine-terminated polyurethane macro-initiators as transitional products reacting with n-butyl acrylate, and subsequently with tert-butyl acrylate in the presence of the CuIIBr2/TPMA catalyst complex. The results of 1H NMR spectral studies support the formation of tri-block poly (n-butyl acrylate)-block-polyurethane-block-poly(n-butyl acrylate) copolymers, and penta-block poly(tert-butyl acrylate)-block-poly (n-butyl acry late)-block-polyurethane-block-poly (n-butyl acrylate)- block-poly(tert-butyl acrylate) copolymers.

Keywords: polymer synthesis; eATRP; copolymers; polyurethanes; polyacrylates

Acknowledgements

The financial support received from U-553/DS is gratefully acknowledged. The NMR spectra were recorded in the Laboratory of Spectrometry, Faculty of Chemistry, Rzeszow University of Technology and were financed from the DS budget.

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Received: 2015-12-24
Revised: 2016-2-1
Accepted: 2016-2-2
Published Online: 2016-4-22
Published in Print: 2016-9-1

© 2016 Institute of Chemistry, Slovak Academy of Sciences

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https://doi.org/10.1515/chempap-2016-0054
Schlagwörter für diesen Artikel
polymer synthesis; eATRP; copolymers; polyurethanes; polyacrylates

Artikel in diesem Heft

  1. Review
  2. Plant extracts as “green” corrosion inhibitors for steel in sulphuric acid
  3. Original Paper
  4. Use of 6-O-mono-substituted derivatives of β-cyclodextrin-bearing substituent with two permanent positive charges in capillary electrophoresis
  5. Original Paper
  6. Development of ICP-MS and ICP-OES methods for determination of gadolinium in samples related to hospital waste water treatment
  7. Original Paper
  8. Alkyl glycosides as potential anti-Candida albicans growth agents
  9. Original Paper
  10. Preparation of corn stalk-based adsorbents and their specific application in metal ions adsorption
  11. Original Paper
  12. Treatment of metal-plating waste water by modified direct contact membrane distillation
  13. Original Paper
  14. Influence of pH and cationic surfactant on stability and interfacial properties of algerian bitumen emulsion
  15. Original Paper
  16. Synthesis, structural and spectroscopic properties of asymmetric schiff bases derived from 2,3-diaminopyridine
  17. Original Paper
  18. Syntheses of cardanol-based cationic surfactants and their use in emulsion polymerisation
  19. Original Paper
  20. Synthesis of urethane—acrylic multi-block copolymers via electrochemically mediated ATRP
  21. Original Paper
  22. Diazene sulphonate as a cross-linking agent for polymers with pendant triarylamine hole-conducting units
  23. Original Paper
  24. Leaching test for calcined kaolinite and kaolinite/TiO2 photoactive composite
  25. Original Paper
  26. Chitosan sponge matrices with β-cyclodextrin for berberine loadinging
  27. Original Paper
  28. Ageing of plasticized poly(lactic acid)/poly(β-hydroxybutyrate) blend films under artificial UV irradiation and under real agricultural conditions during their application as mulches‡
  29. Original Paper
  30. Synthesis, in-vitro cytotoxicity of 4H-benzo[h]chromene derivatives and structure–activity relationships of 4-aryl group and 3-, 7-positions
  31. Original Paper
  32. Chemoselective synthesis of 1,2-disubstituted benzimidazoles in lactic acid without additive
  33. Original Paper
  34. Sorption properties of sheep wool irradiated by accelerated electron beam
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