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Reaction mechanisms of carbon dioxide methanation

  • Erlisa Baraj EMAIL logo , Stanislav Vagaský , Tomáš Hlinčik , Karel Ciahotný and Viktor Tekáč
Published/Copyright: January 22, 2016
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Chemical Papers
From the journal Chemical Papers Volume 70 Issue 4

Abstract

Constant increase of carbon dioxide emissions from anthropogenic activities leads to the search of options for its recycling and utilization. Although recycled CO2 utilization as a raw material for the production of chemicals and propellants can be challenging, it is the most sustainable way to mitigate its emissions. Among the most promising applications of CO2 is its catalytic fixation with hydrogen via the methanation reaction to methane. CO2 methanation, depending on the used catalyst and overall reaction conditions, can proceed through different mechanism or pathways. A literature review on the methanation reaction mechanism shows that CO2 can be converted to methane either by direct methanation or through the formation of a CO intermediate. This article analyses the proposed reaction mechanisms of CO2 methanation.

Keywords: carbon dioxide; methanation; hydrogenation; catalysis, methane

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Received: 2015-4-7
Revised: 2015-7-20
Accepted: 2015-9-7
Published Online: 2016-1-22
Published in Print: 2016-1-1

© 2015 Institute of Chemistry, Slovak Academy of Sciences

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https://doi.org/10.1515/chempap-2015-0216
Keywords for this article
carbon dioxide; methanation; hydrogenation; catalysis, methane

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  2. Prevention of degradation of γ-irradiated EPDM using phenolic antioxidants
  3. Original Paper
  4. Differentiation of black, green, herbal and fruit bagged teas based on multi-element analysis using inductively-coupled plasma atomic emission spectrometry
  5. Original Paper
  6. Reaction mechanisms of carbon dioxide methanation
  7. Review
  8. Power consumption and gas–liquid dispersion in turbulently agitated vessels with vertical dual-array tubular coil baffles
  9. Short Communication
  10. Tannins analysis from different medicinal plants extracts using MALDI-TOF and MEKC
  11. Original Paper
  12. Trihexyl(tetradecyl)phosphonium bromide as extractant for Rh(III), Ru(III) and Pt(IV) from chloride solutions‡
  13. Original Paper
  14. Synthesis of Fe3O4–Ag nanocomposites and their application to enzymeless hydrogen peroxide detection
  15. Original Paper
  16. Possibilities for removal of chlorinated dye Mordant Blue 9 from model waste water‡
  17. Review
  18. Preparation and properties of gelatin films incorporated with N-hydroxysuccinimide-activated end-bit binary acid
  19. Original Paper
  20. Synthesis and properties of novel reusable nano-ordered KIT-5-N-sulfamic acid as a heterogeneous catalyst for solvent-free synthesis of 2,4,5-triaryl-1 H-imidazoles
  21. Short Communication
  22. Prediction of power consumption in mechanically agitated gassed reactor in viscous batch‡
  23. Original Paper
  24. Hydrogel supported chiral imidazolidinone for organocatalytic enantioselective reduction of olefins in water
  25. Original Paper
  26. Continuous synthesis of N-ethylethylenediamine over supported Cu–Zn–La catalysts
  27. Preface
  28. Enzyme-assisted extraction of citrus essential oil
  29. Preface
  30. Experimental investigations of liquid flow in pipe with flat internal baffles
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