Startseite Copper oxalate complexes: synthesis and structural characterisation‡
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Copper oxalate complexes: synthesis and structural characterisation‡

  • Kristína Matelková EMAIL logo , Lenka Kucková , Anna Mašlejová , Ján Moncoľ , Vladimír Jorík und Jozef Kožíšek
Veröffentlicht/Copyright: 22. Januar 2016
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Chemical Papers
Aus der Zeitschrift Chemical Papers Band 70 Heft 1

Six copper(II) oxalate complexes, namely {K2[Cu(ox)2]}n (1), {(Hiz)2[Cu(ox)2]}n (2), {[Cu(ox) (N-Bzliz)2]}n (3), (HMeiz)2[Cu(ox)2] (4), {[Cu(ox)(Meiz)2]}n (5), and [Cu(Hox)2(H2O)2](N-Bzliz) (6) where ox = oxalate ion, iz = imidazole, N-Bzliz = N-benzylimidazole, Meiz = 2-methylimidazole, were synthesised and characterised by single crystal X-ray diffraction (complexes 1–5) or powder X-ray diffraction (compound 6). The three-dimensional crystal packing structures of 2, 4, and 5 are consolidated by intermolecular hydrogen bonds linking the oxygen atom of the oxalate group and the amine or imine group of the imidazole-based part into chains. The molecules of complex 6 are held together by intermolecular hydrogen bonds between the oxygen atoms of the oxalate group and coordinated water molecules.

Keywords: oxalate anion; carboxylate complexes; crystal structure; denticity; nitrogen ligands

‡Presented at the XXV. International Conference on Coordination and Bioinorganic Chemistry, Smolenice, Slovakia, 31 May–5 June 2015.

Acknowledgements

We gratefully acknowledge the financial support received from the following agencies: Slovak Research and Development Agency nos. APVV-0014-11 and APVV/0202-10 and Slovak Grant Agency nos. VEGA 1/0052/11 and 1/0388/14.

References

Akhriff, Y., Server-Carrió, J., Sancho, A., García-Lozano, J., Escrivá, E., Folgado, J. V., & Soto, L. (1999). Synthesis, crystal structure, and magnetic properties of oxalato–copper(II) complexes with 3,3-bis(2-imidazolyl)propionic acid, an imidazole–carboxylate polyfunctional ligand: From mononuclear entities to ladder-like chains. Inorganic Chemistry, 38, 1174– 1185. DOI: 10.1021/ic980982x.10.1021/ic980982xSuche in Google Scholar

Betteridge, P. W., Carruthers, J. R., Cooper, R. I., Prout, K., & Watkin, D. J. (2003). CRYSTALS version 12: software for guided crystal structure analysis. Journal of Applied Crystallography, 36, 1487. DOI: 10.1107/s0021889803021800.10.1107/s0021889803021800Suche in Google Scholar

Boultif, A., & Lour, D. (2004). Powder pattern indexing with the dichotomy method. Journal of Applied Crystallography, 37, 724–731. DOI: 10.1107/s0021889804014876.10.1107/s0021889804014876Suche in Google Scholar

Brandenburg, K., & Putz, H. (2015). Diamond: Crystal and molecular structure visualization [computer software]. Bonn, Germany: Crystal Impact GbR.Suche in Google Scholar

Bruker AXS Inc. (2001). SADABS [computer software]. Madison, WI, USA: Bruker AXS Inc.Suche in Google Scholar

Burla, M. C., Caliandro, R., Camalli, M., Carrozzini, B., Cascarano, G. L., Giacovazzo, C., Mallamo, M., Mazzone, A., Polidori, G., & Spagna, R. (2012). SIR2011: a new package for crystal structure determination and reffnement. Journal of Applied Crystallography, 45, 357–361. DOI: 10.1107/s0021889812001124.10.1107/s0021889812001124Suche in Google Scholar

Chattopadhyay, S. K., Mak, T. C. W., Luo, B. S., Thompson, L. K., Rana, A., & Ghosh, S. (1995). Synthesis, structural and magnetic studies of imidazolium bis(oxalato)cuprate(II). Polyhedron, 14, 3661–3667. DOI: 1016/0277-5387(95)00151-h.1016/0277-5387(95)00151-hSuche in Google Scholar

Chen, W., Chu, J. F., Mutikainen, I., Reedijk, J., Turpeinen, U., & Song, Y. F. (2011). Tripodal bis(imidazole)-based ligands and their chelation to copper(II). CrystEngComm, 13, 7299– 7304. DOI: 10.1039/c1ce05556a.10.1039/c1ce05556aSuche in Google Scholar

Deacon, G. B., & Phillips, R. J. (1980). Relationship between the carbon-oxygen stretching frequencies of carboxylato complexes and the type of carboxylate coordination. Coordination Chemistry Reviews, 33, 227–250. DOI: 10.1016/s00108545(00)80455-5.10.1016/s00108545(00)80455-5Suche in Google Scholar

Duan, Z. M., Zhang, Y., Zhang, B., & Zhu, D. B. (2008). Co(C2O4)(HO(CH2)3 OH): An antiferromagnetic neutral zigzag chain compound showing long-range ordering of spin canting. Inorganic Chemistry, 47, 9152–9154. DOI: 10.1021/ic801544r.10.1021/ic801544rSuche in Google Scholar PubMed

Favre-Nicolin, V., & Černý, R. (2002). FOX, ‘free objects for crystallography’: a modular approach to ab initio structure determination from powder diffraction. Journal of Applied Crystallography, 35, 734–743. DOI: 10.1107/s0021889802015236.10.1107/s0021889802015236Suche in Google Scholar

Geiser, U., Ramakrishna, B. L., Willett, R. D., Hulsbergen, F. B., & Reedijk, J. (1987). Crystal structures and magnetic behavior of pyridinium bis(oxalato)cuprate(II)-oxalic acid and bis(2-methylimidazole)copper(II) oxalate. Inorganic Chemistry, 26, 3750–3756. DOI: 10.1021/ic00269a026.10.1021/ic00269a026Suche in Google Scholar

Halcrow, M. A. (2013). Jahn–Teller distortions in transitionmetal compounds, and their importance in functional molecular and inorganic materials. Chemical Society Reviews, 42, 1784–1795. DOI: 10.1039/c2cs35253b.10.1039/c2cs35253bSuche in Google Scholar

Jin, Z. N., & Lin, H. (2011). Poly[diimidazole-μ4 -oxalatoμ2 -oxalato-dicopper(II)]. Acta Crystallographica Section E: Structure Reports Online, 67, m680, DOI: 10.1107/s1600536811015777.10.1107/s1600536811015777Suche in Google Scholar

Julve, M., Verdaguer, M., Gleizes, A., Philoche-Lavisalles, M., & Kahn, O. (1984). Design of μ-oxalato copper(II) binuclear complexes exhibiting expected magnetic properties. Inorganic Chemistry, 23, 3808–3818. DOI: 10.1021/ic00191a028.10.1021/ic00191a028Suche in Google Scholar

Kang, D. B. (2005). Inffuence of Jahn-Teller distortion on the magnetic coupling in oxalato-bridged copper(II) dimers: An orbital interpretation of the superexchange mechanism. Bulletin of the Korean Chemical Society, 26, 1965–1968. DOI: 10.5012.bkcs.2005.26.12. 1965.10.5012.bkcs.2005.26.12Suche in Google Scholar

Kaştaş, G., Paşaoffǧlu, H., & Karabulut, B. (2011). Magnetic, structural and computational studies on transition metal complexes of a neurotransmitter, histamine. Journal of Molecular Structure, 1000, 39–48. DOI: 10.1016/j.molstruc.2011.05.047.10.1016/j.molstruc.2011.05.047Suche in Google Scholar

Kuchár, J., Černák, J., Sabová, I., Kappenstein, C., Kajňaková, M., Orendáč, M., & Boča, R. (2009). Cu–Ni hetero-bimetallic compounds, Part 1: Preparation, structure and properties of [Cu0.05 Ni0.95 (bpy)2 (ox)]·4H2 O. Solid State Sciences, 11, 950–955. DOI: 10.1016/j.solidstatesciences.2008.03.032.10.1016/j.solidstatesciences.2008.03.032Suche in Google Scholar

Leong, W. L., & Vittal, J. J. (2011). Synthesis, characterization and structures of copper(II) complexes containing carboxylate and sulfonate groups. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 71, 557–566. DOI: 10.1007/s10847-011-0015-6.10.1007/s10847-011-0015-6Suche in Google Scholar

Matelková, K., Mašlejová, A., & Moncol’, J. (2013). Various modes of oxalato ligand in copper(II) complexes. In M. Melník, P. Segffa, & M. Tatarko (Eds.), Recent developments in coordination, bioinorganic and applied inorganic chemistry (pp. 288–293). Bratislava, Slovakia: Slovak University of Technology Press.Suche in Google Scholar

Meng, W. L., Liu, G. X., & Okamura, T. a., Kawaguchi, H., Zhang, Z. H., Sun, W. Y., & Ueyama, N. (2006). Syntheses, crystal structures, and magnetic properties of novel copper(II) complexes with the flexible bidentate ligand 1-bromo3,5-bis(imidazol-1-ylmethyl)benzene. Crystal Growth & Design, 6, 2092–2102. DOI: 10.1021/cg060304i.10.1021/cg060304iSuche in Google Scholar

Murphy, B., & Hathaway, B. (2003). The stereochemistry of the copper(II) ion in the solid-state—some recent perspectives linking the Jahn–Teller effect, vibronic coupling, structure correlation analysis, structural pathways and comparative Xray crystallography, Coordination Chemistry Reviews, 243, 237–262. DOI: 10.1016/s0010-8545(03)00084-5.10.1016/s0010-8545(03)00084-5Suche in Google Scholar

Oxford Diffraction Ltd. (2013). CrysAlis RED, CrysAlis CCD, Version 1.171.36.32 [computer software]. Abingdon, UK: Oxford Diffraction Ltd.Suche in Google Scholar

Petříček, V., Dušek, M., & Palatinus, L. (2014). Crystallographic computing system JANA2006: General features. Zeitschrift für Kristallographie, 229, 345–352. DOI: 10.1515/zkri-2014-1737.10.1515/zkri-2014-1737Suche in Google Scholar

Sánchez, H., Server-Carrió, J., Escriv`a, E., Soto, L., GarcíaLozano, J., Sancho, A., & Ramírez de Arellano, C. (2013). Mononuclear and binuclear copper(II) complexes with bis(2imidazolyl)(bis(methoxycarbonyl)methylmethane) (BIBM), a tripodal bis(imidazole) based ligand. Synthesis, crystal structure and magnetic characterization of [Cu(BIBM)2 ] (ClO4 )2 and [﹛Cu(BIBM)(H2 O)﹜2 (μ1,2,3,4 -C2O4 )](C4 O4) · 6H2 O. Polyhedron, 50, 383–389. DOI: 10.1016/j.poly.2012.11.024.10.1016/j.poly.2012.11.024Suche in Google Scholar

Sheldrick, G. M. (2008). A short history of SHELX. Acta Crystallographica Section A, A64, 112–122. DOI: 10.1107/s0108767307043930.10.1107/s0108767307043930Suche in Google Scholar PubMed

Sheldrick, G. M. (2015). Crystal structure reffnement with SHELXL. Acta Crystallographica Section C, C71, 3–8. DOI: 10.1107/s2053229614024218.10.1107/s2053229614024218Suche in Google Scholar

Spek, A. L. (2015). PLATON SQUEEZE: a tool for the calculation of the disordered solvent contribution to the calculated structure factors. Acta Crystallographica Section C, C71, 9– 18. DOI: 10.1107/s2053229614024929.10.1107/s2053229614024929Suche in Google Scholar PubMed

Toby, B. H. (2005). CMPR – a powder diffraction toolkit. Journal of Applied Crystallography, 38, 1040–1041. DOI: 10.1107/s0021889805030232.10.1107/s0021889805030232Suche in Google Scholar

Xu, Q. A. (2011). catena-Poly[[bis(1-ethyl-1H-imidazole-δN 3) copper(II)]-μ-oxalato-δ4 O1, O2 : O11, O21]. Acta Crystallographica Section E: Structure Reports Online, 67, m1585. DOI: 10.1107/s1600536811043121.10.1107/s1600536811043121Suche in Google Scholar PubMed PubMed Central

Zhu, Q. R., & Zhang, W. (2013). Synthesis, structural and dielectric characterization of two imidazoleand oxalatecontaining copper(II) complexes. Zeitschrift für Anorganische und Allgemeine Chemie, 639, 1274–1278. DOI: 10.1002/zaac.201300101.10.1002/zaac.201300101Suche in Google Scholar

Received: 2015-4-30
Accepted: 2015-6-26
Published Online: 2016-1-22
Published in Print: 2016-1-1

© 2015 Institute of Chemistry, Slovak Academy of Sciences

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https://doi.org/10.1515/chempap-2015-0174
Schlagwörter für diesen Artikel
oxalate anion; carboxylate complexes; crystal structure; denticity; nitrogen ligands

Artikel in diesem Heft

  1. Original Paper
  2. Mononuclear and heterodinuclear phenanthrolinedione complexes of d- and f-block elements‡
  3. Original Paper
  4. New heteroscorpionate lanthanide complexes for ring-opening polymerisation of ɛ-caprolactone and rac-lactide‡
  5. Original Paper
  6. EPR on bis(1,2-dithiosquarato)cuprate(II) in the bis(1,2-dithiosquarato)nickelate(II) host lattice – structure and spectroscopy‡
  7. Review
  8. Electric fields in zeolites: fundamental features and environmental implications‡
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  12. Nickel(II) complex with 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane‡
  13. Original Paper
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  17. Review
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  19. Original Paper
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