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Formation of coordination compounds with aniline in the interlayer space of Ca2+-, Cu2+- and Fe3+-exchanged montmorillonite‡

  • Veronika Janíková EMAIL logo , Eugen Jóna , Róbert Janík , Viliam Pavlík , Darina Ondrušová and Michaela Ďurčeková
Published/Copyright: January 22, 2016
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Chemical Papers
From the journal Chemical Papers Volume 70 Issue 1

The influence of Ca2+-, Cu2+- and Fe3+-exchanged montmorillonite (MMT) on the type of interaction with aniline in the interlayer space of MMT has been studied by means of X-ray powder diffraction and infrared spectra. Results of X-ray diffraction showed that aniline was successfully intercalated into the interlayer space of MMT. Based on IR spectra evaluation, aniline was indirectly coordinated through a water-bridge in Ca2+- and Fe3+-MMT and it was indirectly coordinated through a water-bridge as well as protonated in Cu2+-MMT (the spectrum of protonated aniline showed deformation and changes in the NH3+ absorption at approximately 1521 cm−1). It is important to point out that Cu2+-MMT indirect coordination and protonation occur simultaneously.

Keywords: montmorillonite; aniline; XRD powder diffraction; IR spectroscopy

‡Presented at the XXV. International Conference on Coordination and Bioinorganic Chemistry, Smolenice, Slovakia, 31 May–5 June 2015.

Acknowledgements.

This work was supported by KEGA No. 006 TnUAD – 4/2014

References

Cloos, P., Moreale, A., Broers, C., & Badot, C. (1979). Adsorption and oxidation of aniline and p-chloroaniline by montmorillonite. Clay Minerals, 14, 307–321. DOI: 10.1180/claymin.1979.014.4.07.10.1180/claymin.1979.014.4.07Search in Google Scholar

Gupta, B., Rakesh, A., Melvin, A. A., Pandey, A. C., & Prakash, R. (2014). In-situ synthesis of polyaniline coated montmorillonite (Mt) clay using Fe3+ intercalated Mt as oxidizing agent. Applied Clay Science, 95, 50–54. DOI: 10.1016/j.clay.2014.02.009.10.1016/j.clay.2014.02.009Search in Google Scholar

Ilic, M., Koglin, E., Pohlmeier, A., Narres, H. D., & Schwuger, M. J. (2000). Adsorption and polymerization of aniline on Cu(II)-montmorillonite: Vibrational spectroscopy and ab initio calculation. Langmuir, 16, 8946–8951. DOI: 10.1021/la000534d.10.1021/la000534dSearch in Google Scholar

Janík, R., Jóna, E., Pajtášová, M., Ondrušová, D., Lizák, P., Pavlík, V., Durný, R., & Mojumdar, S. C. (2012). Thermal, spectral, and diffraction properties of Co-exchanged montmorillonite with 2-, 3-, and 4-hydroxyphenol. Journal of Thermal Analysis and Calorimetry, 108, 915–919. DOI: 10.1007/s10973-012-2364-9.10.1007/s10973-012-2364-9Search in Google Scholar

Kowalska, M., Güller, H., & Cocke, D. L. (1994). Interaction of clay minerals with organic pollutants. Science of the Total Environment, 141, 223–240. DOI: 10.1016/00489697(94)90030-2.10.1016/00489697(94)90030-2Search in Google Scholar

Liu, R., Frost, R. L., Martens, W. N., & Yuan, Y. (2008). Synthesis, characterization of mono-, diand tri alkyl surfactant intercalated Wyoming montmorillonite for the removal of phenol from aqueous systems. Journal of Colloid and Interface Science, 327, 287–294. DOI: 10.1016/j.jcis.2008.08.049.10.1016/j.jcis.2008.08.049Search in Google Scholar PubMed

Queslati, W., Ben Rhaiem, H., & Ben Haj Amara, A. (2011). XRD investigation of hydrated homoionic montmorillonite saturated by several heavy metal cations. Desalination, 271, 139–149. DOI: 10.1016/j.desal.2010.12.018.10.1016/j.desal.2010.12.018Search in Google Scholar

Soma, Y., & Soma, M. (1988). Adsorption of benzidines and anilines on Cuand Fe-montmorillonites studied by resonance Raman spectroscopy. Clay Minerals, 23, 1–12. DOI: 10.1180/claymin.1988.023.1.01.10.1180/claymin.1988.023.1.01Search in Google Scholar

Yariv, S. (1996). Thermo-IR-spectroscopy analysis of the interactions between organic pollutants and clay minerals. Termochimica Acta, 274, 1–35. DOI: 10.1016/00406031(95)02708-4.10.1016/00406031(95)02708-4Search in Google Scholar

Yavuz, Ö., Altunkaynak, Y., & Güzel, F. (2003). Removal of copper, nickel, cobalt and mangane from aqueous solution by kaolinite. Water Research, 37, 948–953. DOI: 10.1016/s00431354(02)00409-8.10.1016/s00431354(02)00409-8Search in Google Scholar

Received: 2015-3-31
Revised: 2015-7-22
Accepted: 2015-8-2
Published Online: 2016-1-22
Published in Print: 2016-1-1

© 2015 Institute of Chemistry, Slovak Academy of Sciences

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https://doi.org/10.1515/chempap-2015-0196
Keywords for this article
montmorillonite; aniline; XRD powder diffraction; IR spectroscopy

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  3. Original Paper
  4. New heteroscorpionate lanthanide complexes for ring-opening polymerisation of ɛ-caprolactone and rac-lactide‡
  5. Original Paper
  6. EPR on bis(1,2-dithiosquarato)cuprate(II) in the bis(1,2-dithiosquarato)nickelate(II) host lattice – structure and spectroscopy‡
  7. Review
  8. Electric fields in zeolites: fundamental features and environmental implications‡
  9. Short Communication
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  11. Original Paper
  12. Nickel(II) complex with 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane‡
  13. Original Paper
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