Home Nickel(II) complex with 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane‡
Article
Licensed
Unlicensed Requires Authentication

Nickel(II) complex with 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane‡

  • Masahiro Mikuriya EMAIL logo , Mayu Hamagawa , Natsuki Tomioka , Rika Fujimori , Daisuke Yoshioka , Shoichi Hori , Taro Kuriyama , Hiroshi Sakiyama , Makoto Handa and Ryoji Mitsuhashi
Published/Copyright: January 22, 2016
Become an author with De Gruyter Brill
Author Information
Chemical Papers
From the journal Chemical Papers Volume 70 Issue 1

A nickel(II) complex, [Ni(taetacn)](ClO4)2 · H2O, where taetacn = 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane was synthesized. The crystal structure was determined by the single-crystal X-ray diffraction method at 293 K. The complex crystallizes in the orthorhombic space groupPna21 with a = 16.004(2) Å, b = 10.186(1) Å, c = 13.937(2) Å, V = 2271.9(5) Å3, Dx = 1.56 g cm−3, Dm = 1.59 g cm−3 (floatation method), and Z = 4. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0636 and 0.1672, respectively, for all 4845 independent reflections. The compound is composed of octahedral nickel(II) cation with three 2-aminoethyl pendant groups of taetacn, tetrahedral ClO4− anion, and a water molecule of crystallization. Electronic spectra are consistent with the octahedral geometry. Temperature dependence of the magnetic susceptibility (4.5–300 K) can be interpreted considering the zero-field splitting of the nickel(II) ion (g = 2.14, D = 3.72 cm−1, and Nα = 300 × 10−6 cm3 mol−1). Cyclic voltammetry in DMF showed quasi-reversible and irreversible oxidation waves (Epa = 0.54 V, Epc = 0.45 V; Epa = 1.16 V, Epc = 0.71 V vs. Ag/Ag+).

Keywords: nickel(II) complex; triazacyclononane ligand; crystal structure; magnetic property; electronic spectra

‡ Presented at the XXV. International Conference on Coordination and Bioinorganic Chemistry, Smolenice, Slovakia, 31 May–5 June 2015

Acknowledgements.

The present work was partially supported by Grants-in-Aid for Scientific Research Nos. 26410080 from the Ministry of Education, Culture, Sports, Science and Technology and the MEXT-Supported Program for the Strategic Research Foundation at Private Universities, 2010-2014.

Supplementary data

Crystallographic data for complex I reported in this paper have been deposited with the Cambridge Crystallographic Data Centre, CCDC no. 1035536. Copies of the information may be obtained free of charge from: The Director, CCDC, 12 Union Road, Cambridge, CB2 1EZ, UK (fax: +441223-336033; e-mail: or via http://www.ccdc.cam.ac.uk/datarequest/cif).

References

Chaudhuri, P., Wieghardt, K., Tsai, Y. H., & Krüger, C. (1984). Reaction of LM(CO)3 complexes (M = Cr, Mo, W; L = 1,4,7triazacyclononane) with bromine, iodine, and nitric acid. Syntheses of air-stable hydridocarbonyl and hydridonitrosyl complexes. Crystal structure of [LMo(CO)3 Br](ClO4)·H2 O. Inorganic Chemistry, 23, 427-432. DOI: 10.1021/ic00172a010.10.1021/ic00172a010Search in Google Scholar

Ginsberg, A. P., Martin, R. L., Brookes, R. W., & Sherwood, R.C. (1972). Magnetic exchange in transition metal complexes. IX. Dimeric nickel(II)-ethylenediamine complexes. Inorganic Chemistry, 11, 2884-2889. DOI: 10.1021/ic50118a006.10.1021/ic50118a006Search in Google Scholar

Hammershøi, A., & Sargeson, A. M. (1983). Macrocyclic hexaamine cage complexes of cobalt(III): Synthesis, characterization, and properties. Inorganic Chemistry, 22, 3554-3561. DOI: 10.1021/ic00166a014.10.1021/ic00166a014Search in Google Scholar

Kida, S., Murase, I., Harada, C., Daizeng, L., & Mikuriya, M. (1986). Syntheses and properties of copper(II) triperchlorates with N,N 1,N 11,N 111 -tetrakis(2-aminoethyl)-1,4,8,11-tetraazacyclotetradecane and an anion. Bulletin of the Chemical Society of Japan, 59, 2595-2597. DOI: 10.1246/bcsj.59.2595.10.1246/bcsj.59.2595Search in Google Scholar

Mikuriya, M., Kida, S., & Murase, I. (1987a). Crystal and molecular structure of a novel mixed-spin binuclear nickel(II) complex with N,N 1,N 11,N 111-tetrakis(2-aminoethyl)-1,4,8,11tetraazacyclotetradecane. Journal of the Chemical Society, Dalton Transactions, 1987, 1261-1262. DOI: 10.1039/dt9870001261.10.1039/dt9870001261Search in Google Scholar

Mikuriya, M., Kida, S., & Murase, I. (1987b). Preparation and crystal structures of binuclear copper(II) complexes of N,N 1,N 11,N 111-tetrakis(2-aminoethyl)-1,4,8,11-tetraazacyclotetradecane containing azide, cyanate, or thiocyanate ion. Bulletin of the Chemical Society of Japan, 60, 1355-1359. DOI: 10.1246/bcsj.60.1355.10.1246/bcsj.60.1355Search in Google Scholar

Mikuriya, M., Kida, S., & Murase, I. (1987c). Crystal and molecular structures of [Cu2(taec)X](ClO4 )3 ·nH2O (taec = N,N 1,N 11,N 111-tetrakis(2-aminoethyl)-1,4,8,11-tetraazacyclotetradecane; X = I, F, NO2, and CH3COO; n = 0, 1, or 2). Effect of incorporation of an anion X on the structure of the complex cation. Bulletin of the Chemical Society of Japan, 60, 1681-1689. DOI: 10.1246/bcsj.60.1681.10.1246/bcsj.60.1681Search in Google Scholar

Mikuriya, M., Kida, S., Kohzuma, T., & Murase, I. (1988). Xray crystal structure and electrochemical property of a novel monohydroxo-bridged binuclear cobalt(II) complex with N,N 1,N 11,N 111 -tetrakis(2-aminoethyl)-1,4,8,11-tetraazacyclotetradecane. Bulletin of the Chemical Society of Japan, 61, 2666-2668. DOI: 10.1246/bcsj.61.2666.10.1246/bcsj.61.2666Search in Google Scholar

Mikuriya, M., Murase, I., Asato, E., & Kida, S. (1989). A novel μ-carbonato-bridged binuclear nickel(II) complex with N,N 1,N 11,N 111 -tetrakis(2-aminoethyl)-1,4,8,11-tetraazacyclotetradecane. Chemistry Letters, 18, 497-500. DOI: 10.1246/cl.1989.497.10.1246/cl.1989.497Search in Google Scholar

Mikuriya, M., Nakadera, K., & Kotera, T. (1996). Synthesis and characterization of dinuclear and tetranuclear mixed-spin nickel(II) complexes with 2,6-bis(salicylidenaminomethyl)-4methylphenol. Bulletin of the Chemical Society of Japan, 69, 399-405. DOI: 10.1246/bcsj.69.399.10.1246/bcsj.69.399Search in Google Scholar

Mikuriya, M., Schumacher, M., Kawano, C., Akihara, T., Ono, K., Yoshioka, D., Sakiyama, H., & Handa, M. (2014). Dinuclear nickel(II) pivalate with -aqua and di-pivalato bridges showing a ferromagnetic interaction. Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry, 9, 62-66.10.19261/cjm.2014.09(2).09Search in Google Scholar

Murakami, Y., & Sakata, S. (1976). Electronic spectra. In K. Ueno (Ed.), Kireto kagaku (Vol. 1, Chapter 2, pp. 191-196). Tokyo, Japan: Nankodo.Search in Google Scholar

Murase, I., Mikuriya, M., Sonoda, H., Fukuda, Y., & Kida, S. (1986). Synthesis and X-ray structural characterization of novel binuclear complexes of copper(II), nickel(II), and cobalt(II) with an octadentate ligand, N,N 1,N 11,N 111 tetrakis(2-aminoethyl)-1,4,8,11-tetraazacyclotetradecane. Journal of the Chemical Society, Dalton Transactions, 1986, 953-959. DOI: 10.1039/dt9860000953.10.1039/dt9860000953Search in Google Scholar

Sakiyama, H., Suzuki, T., Ono, K., Ito, R., Watanabe, Y., Yamasaki, M., & Mikuriya, M. (2005). Synthesis, structure, and magnetic properties of dinuclear nickel(II) complexes with a phenol-based dinucleating ligand with four methoxyethyl chelating arms. Inorganica Chimica Acta, 358, 1897-1903. DOI: 10.1016/j.ica.2004.12.012.10.1016/j.ica.2004.12.012Search in Google Scholar

Sakiyama, H., Tone, K., Yamasaki, M., & Mikuriya, M. (2011). Electronic spectrum and magnetic properties of a dinuclear nickel(II) complex with two nickel(II) ions of C2-twisted octahedral geometry. Inorganica Chimica Acta, 365, 183-189. DOI: 10.1016/j.ica.2010.09.005.10.1016/j.ica.2010.09.005Search in Google Scholar

Sheldrick, G. M. (1997). SHELXS-97 and SHELXL-97. Program for crystal structure resolution and analysis. Göttingen, Germany: University of Göttingen.Search in Google Scholar

Sheldrick, G. M. (2015). Crystal structure reffnement with SHELXL. Acta Crystallographica Section C: Structural Chemistry, C71, 3-8. DOI: 10.1107/s2053229614024218.10.1107/s2053229614024218Search in Google Scholar

Taylor, S. G., Snow, M. R., & Hambley, T. W. (1983). The structures and energy minimization analyses of the macrotricyclic cage complex [Co(nosartacn)]3+ and its precursor [Co(taetacn)]3+ . Australian Journal of Chemistry, 36, 23592368. DOI: 10.1071/ch9832359.10.1071/ch9832359Search in Google Scholar

Wada, S., Kotera, T., & Mikuriya, M. (2008). Synthesis and structural characterization of a dinuclear palladium(II) complex with N,N 1,N 11,N 111 -tetrakis(2-p-toluenesulfonamidoethyl)cyclam. Bulletin of the Chemical Society of Japan, 81, 1454-1460. DOI: 10.1246/bcsj.81.1454.10.1246/bcsj.81.1454Search in Google Scholar

Wainwright, K. P. (1997). Synthetic and structural aspects of the chemistry of saturated polyaza macrocyclic ligands bearing pendant coordinating groups attached to nitrogen. Coordination Chemistry Reviews, 166, 35-90. DOI: 10.1016/s0010-8545(97)00003-9.10.1016/s0010-8545(97)00003-9Search in Google Scholar

Wieghardt, K., Schöffmann, E., Nuber, B., & Weiss, J. (1986). Syntheses, properties, and electrochemistry of transitionmetal complexes of the macrocycle 1,4,7-tris(2-pyridylmethyl)-1,4,7-triazacyclononane (L). Crystal structures of [NiL](ClO4)2, [MnL](ClO4)2, and [PdL](PF6)2 containing a distorted-square-base-pyramidal PdIIN5 core. Inorganic Chemistry, 25, 4877-4883. DOI: 10.1021/ic00247a020.10.1021/ic00247a020Search in Google Scholar

Zompa, L. J., & Margulis, T. N. (1978). Trigonal distortion in a nickel(II) complex. Structure of [Ni([9]aneN3)2](NO3)Cl.H2O. Inorganica Chimica Acta, 28, L157-L159. DOI: 10.1016/s0020-1693(00)87389-2.10.1016/s0020-1693(00)87389-2Search in Google Scholar

Received: 2015-3-15
Revised: 2015-5-29
Accepted: 2015-6-10
Published Online: 2016-1-22
Published in Print: 2016-1-1

© 2015 Institute of Chemistry, Slovak Academy of Sciences

Articles in the same Issue

  1. Original Paper
  2. Mononuclear and heterodinuclear phenanthrolinedione complexes of d- and f-block elements‡
  3. Original Paper
  4. New heteroscorpionate lanthanide complexes for ring-opening polymerisation of ɛ-caprolactone and rac-lactide‡
  5. Original Paper
  6. EPR on bis(1,2-dithiosquarato)cuprate(II) in the bis(1,2-dithiosquarato)nickelate(II) host lattice – structure and spectroscopy‡
  7. Review
  8. Electric fields in zeolites: fundamental features and environmental implications‡
  9. Short Communication
  10. Mononuclear cobalt(III) complexes with N-salicylidene-2-hydroxy-5-bromobenzylamine and N-salicylidene-2-hydroxy-5-chlorobenzylamine‡
  11. Original Paper
  12. Nickel(II) complex with 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane‡
  13. Original Paper
  14. SOD mimetic activity of salicylatocopper complexes‡
  15. Original Paper
  16. Copper oxalate complexes: synthesis and structural characterisation‡
  17. Review
  18. Towards the development of highly active copper catalysts for atom transfer radical addition (ATRA) and polymerization (ATRP)‡
  19. Original Paper
  20. Synthesis, DFT calculations and characterisation of new mixed Pt(II) complexes with 3-thiolanespiro-5′ 1-hydantoin and 4-thio-1H-tetrahydropyranspiro-5′-hydantoin‡
  21. Short Communication
  22. Formation of coordination compounds with aniline in the interlayer space of Ca2+-, Cu2+- and Fe3+-exchanged montmorillonite‡
  23. Original Paper
  24. Self-assembly hydrogen-bonded supramolecular arrays from copper(II) halogenobenzoates with nicotinamide:Structure and EPR spectra‡
  25. Original Paper
  26. Different structural types of copper(II) furan- and thiophencarboxylates: X-ray structural, EPR, spectral and magnetic analyses‡
  27. Preface
  28. XXV. International Conference on Coordination & Bioinorganic Chemistry (25th ICCBiC), June 2015, Slovakia
https://doi.org/10.1515/chempap-2015-0165
Keywords for this article
nickel(II) complex; triazacyclononane ligand; crystal structure; magnetic property; electronic spectra

Articles in the same Issue

  1. Original Paper
  2. Mononuclear and heterodinuclear phenanthrolinedione complexes of d- and f-block elements‡
  3. Original Paper
  4. New heteroscorpionate lanthanide complexes for ring-opening polymerisation of ɛ-caprolactone and rac-lactide‡
  5. Original Paper
  6. EPR on bis(1,2-dithiosquarato)cuprate(II) in the bis(1,2-dithiosquarato)nickelate(II) host lattice – structure and spectroscopy‡
  7. Review
  8. Electric fields in zeolites: fundamental features and environmental implications‡
  9. Short Communication
  10. Mononuclear cobalt(III) complexes with N-salicylidene-2-hydroxy-5-bromobenzylamine and N-salicylidene-2-hydroxy-5-chlorobenzylamine‡
  11. Original Paper
  12. Nickel(II) complex with 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane‡
  13. Original Paper
  14. SOD mimetic activity of salicylatocopper complexes‡
  15. Original Paper
  16. Copper oxalate complexes: synthesis and structural characterisation‡
  17. Review
  18. Towards the development of highly active copper catalysts for atom transfer radical addition (ATRA) and polymerization (ATRP)‡
  19. Original Paper
  20. Synthesis, DFT calculations and characterisation of new mixed Pt(II) complexes with 3-thiolanespiro-5′ 1-hydantoin and 4-thio-1H-tetrahydropyranspiro-5′-hydantoin‡
  21. Short Communication
  22. Formation of coordination compounds with aniline in the interlayer space of Ca2+-, Cu2+- and Fe3+-exchanged montmorillonite‡
  23. Original Paper
  24. Self-assembly hydrogen-bonded supramolecular arrays from copper(II) halogenobenzoates with nicotinamide:Structure and EPR spectra‡
  25. Original Paper
  26. Different structural types of copper(II) furan- and thiophencarboxylates: X-ray structural, EPR, spectral and magnetic analyses‡
  27. Preface
  28. XXV. International Conference on Coordination & Bioinorganic Chemistry (25th ICCBiC), June 2015, Slovakia
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 24.9.2025 from https://www.degruyterbrill.com/document/doi/10.1515/chempap-2015-0165/html
Scroll to top button