Startseite Towards the development of highly active copper catalysts for atom transfer radical addition (ATRA) and polymerization (ATRP)‡
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Towards the development of highly active copper catalysts for atom transfer radical addition (ATRA) and polymerization (ATRP)

  • Tomislav Pintauer EMAIL logo
Veröffentlicht/Copyright: 22. Januar 2016
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Fundamentals of copper catalyzed atom transfer radical addition (ATRA) and mechanistically similar polymerization (ATRP) were discussed. Special emphasis was placed on structural characterization and electrochemical properties of copper complexes. Recent advances in the development of highly active copper complexes for both processes were also reviewed. It was found that electron-donating groups (methoxy and methyl in the 4 and 3,5 positions, respectively) of the pyridine rings in tris(2-pyridylmethyl)amine (TPMA) ligand, significantly increase the catalytic activity in copper mediated ATRA/ATRP.


Presented at the XXV. International Conference on Coordination and Bioinorganic Chemistry, Smolenice, Slovakia, 31 May–5 June 2015.


Acknowledgements.

Financial support from the National Science Foundation (CHE-0844131 and CHE-1360886) is greatly acknowledged.

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Received: 2015-3-9
Revised: 2015-7-2
Accepted: 2015-7-13
Published Online: 2016-1-22
Published in Print: 2016-1-1

© 2015 Institute of Chemistry, Slovak Academy of Sciences

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  26. Different structural types of copper(II) furan- and thiophencarboxylates: X-ray structural, EPR, spectral and magnetic analyses
  27. Preface
  28. XXV. International Conference on Coordination & Bioinorganic Chemistry (25th ICCBiC), June 2015, Slovakia
Heruntergeladen am 24.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/chempap-2015-0183/html
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