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Structural and thermal characterization of copper(II) complexes with phenyl-2-pyridylketoxime and deposition of thin films by spin coating

  • Robert Szczęsny EMAIL logo , Tadeusz M. Muzioƚ , Duncan H. Gregory and Edward Szƚyk
Published/Copyright: March 3, 2015
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Chemical Papers
From the journal Chemical Papers Volume 69 Issue 4

Abstract

Four copper(II) oxime complexes, [Cu(HPPK)(PPK)X] (HPPK = phenyl-2-pyridylketoxime and X = CI− (I ), CF3COO− (II ), C3F7COO− (III ), and [Cu(PPK)2]2 (IV )), were synthesized and characterized by elemental analysis, infrared spectroscopy (IR), and single-crystal X-ray diffraction (XRD). XRD analysis revealed that I -III contain copper(II) coordinated by four nitrogen atoms from two oxime molecules in the basal plane and one monodentate anion X in the apical position of a distorted square pyramid. Complex IV is dimeric and it is formed by two Cu(PPK)2 units. Bridges between these units are formed by the two oxygen atoms of the deprotonated oxime groups. Thermal stability of I -IV was investigated by thermogravimetric analysis (TGA) in air and in nitrogen atmosphere, respectively. Evolved gaseous decomposition products were characterized by IR. I -IV decompose via multistep processes. Fluorocarbons and CO2 were observed to be the most abundant gaseous species evolved. Preliminary ammonolysis experiments were performed to examine the possibility of using II and IV as precursors for the synthesis of copper nitride. Moreover, solutions of IV were spin-coated onto silicon substrates. Surface structure and morphology of the resulting films were studied by scanning electron microscopy (SEM) and atomic force microscopy (AFM) and layers with island-like distribution of material were observed

Keywords: copper(II) complexes; phenyl-2-pyridylketoxime; spin coating; thermal properties; ammonolysis

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Received: 2014-7-15
Revised: 2014-8-21
Accepted: 2014-8-22
Published Online: 2015-3-3
Published in Print: 2015-4-1

© 2015 Institute of Chemistry, Slovak Academy of Sciences

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https://doi.org/10.1515/chempap-2015-0065
Keywords for this article
copper(II) complexes; phenyl-2-pyridylketoxime; spin coating; thermal properties; ammonolysis

Articles in the same Issue

  1. Liquid–liquid extraction and cloud point extraction for spectrophotometric determination of vanadium using 4-(2-pyridylazo)resorcinol
  2. Sensitive and selective determination of peptides, PG and PGP, using a novel fluorogenic reagent 4-chlorobenzene-1,2-diol
  3. Spectroscopy studies of sandwich-type complex of silver(I) co-ordinated to nuclear fast red and adenine and its analytical applications
  4. Differentiation of selected blue writing inks by surface-enhanced Raman spectroscopy
  5. A simple pyridine-based colorimetric chemosensor for highly sensitive and selective mercury(II) detection with the naked eye
  6. Phospho sulfonic acid as efficient heterogeneous Brønsted acidic catalyst for one-pot synthesis of 14H-dibenzo[a,j ]xanthenes and 1,8-dioxo-octahydro-xanthenes
  7. Microfiltration of post-fermentation broth with backflushing membrane cleaning
  8. Mass transfer examination in electrodialysis using limiting current measurements
  9. Determination of diffusivity from mass transfer measurements in a batch dialyzer: numerical analysis of pseudo-steady state approximation
  10. Structural and thermal characterization of copper(II) complexes with phenyl-2-pyridylketoxime and deposition of thin films by spin coating
  11. Oxidation of 4-nitro-o-xylene with nitric acid using N-hydroxyphthalimide under phase transfer conditions
  12. Synthesis of pyranopyrazoles, benzopyrans, amino-2-chromenes and dihydropyrano[c]chromenes using ionic liquid with dual Brønsted acidic and Lewis basic sites
  13. Eco-friendly conjugate hydrocyanation of α-cyanoacrylates using potassium hexacyanoferrate(II) as cyanating reagent
  14. Morphological orders of spherulitic crystal textures in Belousov–Zhabotinsky-type oscillatory reaction system
  15. Zwitterionic structures of selenocysteine-containing dipeptides and their interactions with Cu(II) ions
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