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Liquid–liquid extraction and cloud point extraction for spectrophotometric determination of vanadium using 4-(2-pyridylazo)resorcinol

  • Teodora S. Stefanova , Kiril K. Simitchiev and Kiril B. Gavazov EMAIL logo
Published/Copyright: March 3, 2015
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Chemical Papers
From the journal Chemical Papers Volume 69 Issue 4

Abstract

Liquid-liquid extraction (LLE) and cloud point extraction (CPE) of vanadium(V) ternary complexes with 4-(2-pyridylazo)resorcinol (PAR) and 2,3,5-triphenyl-2H-tetrazolum chloride (TTC) were investigated. The optimal conditions for vanadium extraction and spectrophotometric determination were identified. The composition (V : PAR : TTC) of the extracted species was 1 : 2 : 3 (optimal conditions; LLE), 2 : 2 : 2 (low reagents concentrations; LLE), 1 : 1 : 1 (short heating time; CPE), and 1 : 1 : 1 + 1 : 1 : 0 (optimal extraction conditions; CPE). LLE, performed in the presence of 1,2-diaminocyclohexane-N,N,N’,N’-tetraacetic acid and NH4F as masking agents, afforded the sensitive, selective, precise, and inexpensive spectrophotometric determination of vanadium. The absorption maximum, molar absorptivity, limit of detection, and linear working range were 559 nm, 1.95 × 105 dm3 mol−1 cm−1, 0.7 ng cm−3, and 2.2-510 ng cm−3, respectively. The procedure thus developed was applied to the analysis of drinking waters and steels. The relative standard deviations for V(V) determination were below 9.4 % (4-6 × 10−7 mass %; water samples) and 2.12 % (1-3 mass %; steel samples).

Keywords: vanadium(V); ternary complex; 2,3,5-triphenyl-2H-tetrazolium chloride; spectrophotometric analysis; liquid-liquid extraction; cloud point extraction

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Received: 2014-6-19
Revised: 2014-8-16
Accepted: 2014-8-16
Published Online: 2015-3-3
Published in Print: 2015-4-1

© 2015 Institute of Chemistry, Slovak Academy of Sciences

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https://doi.org/10.1515/chempap-2015-0048
Keywords for this article
vanadium(V); ternary complex; 2,3,5-triphenyl-2H-tetrazolium chloride; spectrophotometric analysis; liquid-liquid extraction; cloud point extraction

Articles in the same Issue

  1. Liquid–liquid extraction and cloud point extraction for spectrophotometric determination of vanadium using 4-(2-pyridylazo)resorcinol
  2. Sensitive and selective determination of peptides, PG and PGP, using a novel fluorogenic reagent 4-chlorobenzene-1,2-diol
  3. Spectroscopy studies of sandwich-type complex of silver(I) co-ordinated to nuclear fast red and adenine and its analytical applications
  4. Differentiation of selected blue writing inks by surface-enhanced Raman spectroscopy
  5. A simple pyridine-based colorimetric chemosensor for highly sensitive and selective mercury(II) detection with the naked eye
  6. Phospho sulfonic acid as efficient heterogeneous Brønsted acidic catalyst for one-pot synthesis of 14H-dibenzo[a,j ]xanthenes and 1,8-dioxo-octahydro-xanthenes
  7. Microfiltration of post-fermentation broth with backflushing membrane cleaning
  8. Mass transfer examination in electrodialysis using limiting current measurements
  9. Determination of diffusivity from mass transfer measurements in a batch dialyzer: numerical analysis of pseudo-steady state approximation
  10. Structural and thermal characterization of copper(II) complexes with phenyl-2-pyridylketoxime and deposition of thin films by spin coating
  11. Oxidation of 4-nitro-o-xylene with nitric acid using N-hydroxyphthalimide under phase transfer conditions
  12. Synthesis of pyranopyrazoles, benzopyrans, amino-2-chromenes and dihydropyrano[c]chromenes using ionic liquid with dual Brønsted acidic and Lewis basic sites
  13. Eco-friendly conjugate hydrocyanation of α-cyanoacrylates using potassium hexacyanoferrate(II) as cyanating reagent
  14. Morphological orders of spherulitic crystal textures in Belousov–Zhabotinsky-type oscillatory reaction system
  15. Zwitterionic structures of selenocysteine-containing dipeptides and their interactions with Cu(II) ions
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