Startseite Lebenswissenschaften Microwave-assisted solvent-free synthesis and luminescence properties of 2-substituted-4,5-di(2-furyl)-1H-imidazoles
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Microwave-assisted solvent-free synthesis and luminescence properties of 2-substituted-4,5-di(2-furyl)-1H-imidazoles

  • Jian Zhang , Tian-Qi Zhao , Yao Chen , Xiao-Dong Chen , Hai-Kun Chang , Yu-Min Zhang EMAIL logo und Shu-Cheng Hua
Veröffentlicht/Copyright: 12. Dezember 2014
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Chemical Papers
Aus der Zeitschrift Chemical Papers Band 69 Heft 2

Abstract

A solvent-free microwave-assisted method for the synthesis of 2-substituted-4,5-di(2-furyl)-1H-imidazoles was developed. Imidazoles with moderate to good yields were produced by condensation of furil with aldehydes over acidic alumina impregnated with ammonium acetate, and they were characterized by FT-IR, HRMS, 1H NMR and 13C NMR spectroscopy. Crystal structure of 2,4,5- tri-2-furyl-1H-imidazole (I ) in the orthorhombic space group Pbca was reported, which showed more coplanarity than the reported crystal structure of I in the monoclinic space group Cc. Moreover, their luminescent properties were investigated. It was found that the organic small molecule compounds synthesized possess higher fluorescence quantum efficiency (up to 0.508) in a 0.1 M H2SO4 aqueous solution dissolved in 0.5 mL of CH3OH; along with higher stability; also the emission of some compounds synthesized in the solution was sensitive to the polarity of the solvents.

Keywords: crystal structure; furil; luminescence property; microwave-assisted; 2-substituted-4,5- di(2-furyl)-1H-imidazole

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Received: 2014-5-4
Revised: 2014-6-19
Accepted: 2014-6-21
Published Online: 2014-12-12
Published in Print: 2015-2-1

© 2015 Institute of Chemistry, Slovak Academy of Sciences

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https://doi.org/10.1515/chempap-2015-0014
Schlagwörter für diesen Artikel
crystal structure; furil; luminescence property; microwave-assisted; 2-substituted-4,5- di(2-furyl)-1H-imidazole

Artikel in diesem Heft

  1. Selection and design of ionic liquids as solvents in extractive distillation and extraction processes
  2. Analytical procedure for steroid profiling valid for Athlete Biological Passport
  3. Fabrication of paper-based analytical device by silanisation of filter cellulose using alkyltrimethoxysilane coupled with UV radiation
  4. Synthesis, characterisation and photocatalytic activity of Ag+- and Sn2+-substituted KSbTeO6
  5. Dysprosium pertraction through facilitated supported liquid membrane using D2EHPA as carrier
  6. Volatile compounds composition and antioxidant activity of bee pollen collected in Lithuania
  7. Self-penetrating and interpenetrating 3D metal–organic frameworks constructed from 4-(4-carboxyphenoxy)-phthalic acid and N-donor auxiliary ligands
  8. Preparation of ceramic γ-Al2O3–TiO2 nanofiltration membranes for desalination
  9. Promoting effect of group VI metals on Ni/MgO for catalytic growth of carbon nanotubes by ethylene chemical vapour deposition
  10. Microwave-assisted solvent-free synthesis and luminescence properties of 2-substituted-4,5-di(2-furyl)-1H-imidazoles
  11. Synthesis of potential inhibitors of glycosyltransferases representing UDP-GlcNAc
  12. Development of transition state analogue inhibitors for N-acetylglycosyltransferases bearing D-psicoor D-tagatofuranose scaffolds
  13. Efavirenz–eudragit E-100 nanoparticle-loaded aerosol foam for sustained release: in-vitro and ex-vivo evaluation
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