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Thermochemical Study of High Temperature Corrosion of Iron in a Diluted HCl + SO2 Environment

  • Guy Reumont EMAIL logo , Pierre Perrot , Nathalie Giuliana and Jacques Foct
Published/Copyright: January 6, 2022
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 92 Issue 4

Abstract

Depending on the chemical make-up of the waste stream and operational parameters, a variety of high temperature corrosive environments are generated in the incinerator. As corrosion of industrial equipments is essentially due to high content of sulfur and chlorine in the combustion gas, this study is focused on the interpretation of degradations of pure iron in experimental air environment containing 1000 ppm of HCl and 100 ppm of SO2. Thermochemical calculations were used to estimate the role of these corrosive elements considering chemical potential diagrams and stability paths in pseudo-binary diagrams involving iron and the corrosive atmosphere. The influence of chlorine has been described by the “active corrosion” mechanism proposed by Grabke and confirmed by our calculations. The role of sulfur has been pointed by its “cycle” leading to the formation of eutectic metallic tri-sulfates, promoting a liquid phase corrosion type in the range of the industrial temperatures.

Keywords: High temperature corrosion of Fe; Thermochemical calculations
G. Reumont Laboratoire de Métallurgie Physique et Génie des Matériaux UMR CNRS 8517, Université de Lille I F-59655 Villeneuve d’Ascq Cedex, France Fax:+33 3 20434040

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Received: 2000-10-18
Published Online: 2022-01-06

© 2001 Carl Hanser Verlag, München

Articles in the same Issue

  1. Frontmatter
  2. Aufsätze/Articles
  3. On Properties of Interstitials and Vacancies in Stainless Steels: A Review
  4. Thermodynamic Assessment of the Ru–Si System
  5. The Phase Diagram of the In–Sb–Sn System
  6. The Excess Enthalpies of Liquid Ag-Ge-Te and Ag-Sn-Te Alloys
  7. A Model for the Calculation of the Bainitic Phase Transformation Kinetics from Dilatometric Data
  8. Untersuchung zum Vergleich der σ-Phasenausscheidung in einem rostfreien Superferrit und einem Duplex-Stahl
  9. Effect of Different Rolling Schedules on the Mechanical Properties and Microstructure of X60 Type HSLA Steel
  10. Thermochemical Study of High Temperature Corrosion of Iron in a Diluted HCl + SO2 Environment
  11. Calculation of the Debye Temperature and Study of the Lattice Dynamics of Fe80–xNixCr20 by 57Fe Mössbauer Spectroscopy
  12. Surface Self-Cleaning Effect of Zn-22Al Alloy during Superplastic Deformation
  13. Acoustic Emission and Strain Localization in FCC Single Crystals Compressed in Channel-Die at Low Temperature
  14. Wetting of Alumina, Iron and Stainless Steel Substrates by Molten Magnesium
  15. Split-Induced Lüders Bands in Non-Sag Tungsten Wires during Torsion
  16. The Structure and Crystallization of Amorphous Ni–Fe–P–B Alloys Prepared by Electrons Plating
  17. The Formation of Aluminum Phosphide in Aluminum Melt Treated with an Al–Fe–P Inoculant Addition
  18. Vapor Pressure and Critical Data for Uranium
  19. Mitteilungen/Notifications
  20. Personen
  21. Mitteilungen/News
  22. Bücher/Books
  23. Tagungen/Conferences
https://doi.org/10.3139/ijmr-2001-0070
Keywords for this article
High temperature corrosion of Fe; Thermochemical calculations

Articles in the same Issue

  1. Frontmatter
  2. Aufsätze/Articles
  3. On Properties of Interstitials and Vacancies in Stainless Steels: A Review
  4. Thermodynamic Assessment of the Ru–Si System
  5. The Phase Diagram of the In–Sb–Sn System
  6. The Excess Enthalpies of Liquid Ag-Ge-Te and Ag-Sn-Te Alloys
  7. A Model for the Calculation of the Bainitic Phase Transformation Kinetics from Dilatometric Data
  8. Untersuchung zum Vergleich der σ-Phasenausscheidung in einem rostfreien Superferrit und einem Duplex-Stahl
  9. Effect of Different Rolling Schedules on the Mechanical Properties and Microstructure of X60 Type HSLA Steel
  10. Thermochemical Study of High Temperature Corrosion of Iron in a Diluted HCl + SO2 Environment
  11. Calculation of the Debye Temperature and Study of the Lattice Dynamics of Fe80–xNixCr20 by 57Fe Mössbauer Spectroscopy
  12. Surface Self-Cleaning Effect of Zn-22Al Alloy during Superplastic Deformation
  13. Acoustic Emission and Strain Localization in FCC Single Crystals Compressed in Channel-Die at Low Temperature
  14. Wetting of Alumina, Iron and Stainless Steel Substrates by Molten Magnesium
  15. Split-Induced Lüders Bands in Non-Sag Tungsten Wires during Torsion
  16. The Structure and Crystallization of Amorphous Ni–Fe–P–B Alloys Prepared by Electrons Plating
  17. The Formation of Aluminum Phosphide in Aluminum Melt Treated with an Al–Fe–P Inoculant Addition
  18. Vapor Pressure and Critical Data for Uranium
  19. Mitteilungen/Notifications
  20. Personen
  21. Mitteilungen/News
  22. Bücher/Books
  23. Tagungen/Conferences
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