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Phase transformations in non-isothermally annealed as-cast and cold-rolled AlMnScZr alloys

  • Martin Vlach , Ivana Stulíková , Bohumil Smola , Hana Císarová , Jaroslava Piešová , Stanislav Daniš , Ryota Gemma , Jaroslav Málek , Dhritti Tanprayoon and Volkmar Neubert
Published/Copyright: June 11, 2013
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Abstract

The effect of Mn addition on the microstructure, thermal and mechanical properties in as-cast and cold-rolled Al–Sc–Zr alloys was studied. Electrical resistometry, differential scanning calorimetry and microhardness measurements were used. Transmission electron microscopy, electron backscatter diffraction and X-ray diffraction of specimens quenched from temperatures of pronounced changes in resistivity helped to identify the microstructural processes responsible for resistivity changes. The distinct microhardness increase observed after annealing above ∼320°C is caused by precipitation of the Al3Sc particles. The cold-rolling prior to a heat treatment has no substantial effect on temperature position of the Al3Sc-phase precipitation. The formation of Al6Mn and/or Al6(Mn,Fe) particles is responsible for the intensive resistivity decrease of the cold-rolled materials compared to the as-cast materials. Precipitation of these particles has an insignificant effect on microhardness. The apparent activation energy for the precipitation of the Al3Sc particles was determined.


* Correspondence address Dr. Martin Vlach Charles University in PragueFaculty of Mathematics and Physics Ke Karlovu 3, Prague, Czech Republic Tel.: +420221911458 Fax: +420221911618 E-mail:

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Received: 2011-6-7
Accepted: 2012-1-4
Published Online: 2013-06-11
Published in Print: 2012-07-01

© 2012, Carl Hanser Verlag, München

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