Synthesis, structure, and luminescent properties of two novel polynuclear complexes of 1,3-di(pyridin-2-yl)propane-1,3-dione
Abstract
Two complexes, {[Cd6(o-dppd)2(µ2-Cl)6(µ3-Cl)2(DMF)2(H2O)2Cl2]·DMF·CH3OH}n (I) (DMF = N,N-dimethylformamide; o-dppdH = 1,3-di(pyridin-2-yl)propane-1,3-dione) and [Cu4(o-dppd)2(OAc)4(OH)2]·4H2O (II), were synthesised and characterised by single-crystal X-ray diffraction, elemental analysis, IR, solid fluorescence and TGA. The results showed that complex I had a rodshaped polynuclear chain with hexacoordinating Cd atoms bridged by oxygen, µ2-Cl and µ3-Cl; complex II was a tetranuclear oligomer. In general, supramolecular architectures are constructed through hydrogen-bonding and π-π stacking interactions. I shows luminescence.
[1] Bassett, A. P., Magennis, S. W., Glover, P. B., Lewis, D. J., Spencer, N., Parsons, S., Williams, R. M., De Cola, L., & Pikramenou, Z. (2004). Highly luminescent, tripleand quadruple-stranded, dinuclear Eu, Nd, and Sm(III) lanthanide complexes based on bis-diketonate ligands. Journal of the American Chemical Society, 126, 9413–9424. DOI: 10.1021/ja048022z. http://dx.doi.org/10.1021/ja048022z10.1021/ja048022zSearch in Google Scholar
[2] Batten, S. R., & Robson, R. (1998). Interpenetrating nets: Ordered, periodic entanglement. Angewandte Chemie International Edition, 37, 1460–1494. DOI: 10.1002/(SICI)1521-3773(19980619)37:11〈1460::AID-ANIE1460〉3.0.CO;2-Z. http://dx.doi.org/10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO;2-Z10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO;2-ZSearch in Google Scholar
[3] Braga, D., Grepioni, F., Biradha, K., Pedireddi, V. R., & Desiraju, G. R. (1995). Hydrogen bonding in organometallic crystals. 2. C-H…O hydrogen bonds in bridged and terminal first-row metal carbonyls. Journal of the American Chemical Society, 117, 3156–316 DOI: 10.1021/ja00116a020. http://dx.doi.org/10.1021/ja00116a02010.1021/ja00116a020Search in Google Scholar
[4] Brück, S., Hilder, M., Junk, P. C., & Kynast, U. H. (2000). Synthesis, structure and optical characteristics of pyridyl substituted diketonates of lanthanoids. Inorganic Chemistry Communications, 3, 666–670. DOI: 10.1016/S1387-7003(00)00164-7. http://dx.doi.org/10.1016/S1387-7003(00)00164-710.1016/S1387-7003(00)00164-7Search in Google Scholar
[5] Bruker AXS (1997). SHELXTL, Version 5.1. An integrated system for solving and refining crystal structures from diffraction data. Madison, WI, USA: Bruker AXS Ltd. Search in Google Scholar
[6] Dede, B., Karipcin, F., Arabalı, F., & Cengiz, M. (2010). Synthesis, structure, and solvent-extraction properties of tridentate oxime ligands and their cobalt(II), nickel(II), copper( II), zinc(II) complexes. Chemical Papers, 64, 25–33. DOI: 10.2478/s11696-009-0095-6. http://dx.doi.org/10.2478/s11696-009-0095-610.2478/s11696-009-0095-6Search in Google Scholar
[7] Fang, H. C., Zhu, J. Q., Zhou, L. J., Jia, H. Y., Li, S. S., Gong, X., Li, S. B., Cai, Y. P., Thallapally, P. K., Liu, J., & Exarhos, G. J. (2010). pH-Dependent assembly and conversions of six cadmium(II)-based coordination complexes. Crystal Growth & Design, 10, 3277–3284. DOI: 10.1021/cg1004598. http://dx.doi.org/10.1021/cg100459810.1021/cg1004598Search in Google Scholar
[8] Kowalik-Jankowska, T., Jezierska, J., & Kuczer, M. (2010). Mono- and polynuclear copper(II) complexes with fragment of alloferons 1 and 2; combined potentiometric and spectroscopic studies. Dalton Transactions, 39, 4117–4125. DOI: 10.1039/B923491H. http://dx.doi.org/10.1039/b923491h10.1039/b923491hSearch in Google Scholar
[9] Kozoni, C., Manolopoulou, E., Siczek, M., Lis, T., Brechin, E. K., & Milios, C. J. (2010). Polynuclear manganese amino acid complexes. Dalton Transactions, 39, 7943–7950. DOI: 10.1039/C0DT00192A. http://dx.doi.org/10.1039/c0dt00192a10.1039/c0dt00192aSearch in Google Scholar
[10] Leininger, S., Olenyuk, B., & Stang, P. J. (2000). Selfassembly of discrete cyclic nanostructures mediated by transition metals. Chemical Reviews, 100, 853–908. DOI: 10.1021/cr9601324. http://dx.doi.org/10.1021/cr960132410.1021/cr9601324Search in Google Scholar
[11] Lin, S., Yang, M. X., & Liu, S. X. (2007). Three novel trinuclear zinc(II)/nickel(II) complexes with pentadentate ligands Nnitrobenzoylsalicylhydrazidate. Polyhedron, 26, 4793–4798. DOI: 10.1016/j.poly.2007.01.028. http://dx.doi.org/10.1016/j.poly.2007.01.02810.1016/j.poly.2007.01.028Search in Google Scholar
[12] Luo, W., Meng, X. G., Cheng, G. Z., & Ji, Z. P. (2009b). Synthesis, characterization and bioactivity of two novel trinuclear Cu(II)/Ni(II) complexes with pentadentate ligand N-2-methyl-acryloyl-salicylhydrazide. Inorganica Chimica Acta, 362, 551–555. DOI: 10.1016/j.ica.2008.05.007. http://dx.doi.org/10.1016/j.ica.2008.05.00710.1016/j.ica.2008.05.007Search in Google Scholar
[13] Luo, W., Wang, X. T., Meng, X. G., Cheng, G. Z., & Ji, Z. P. (2008b). Synthesis, crystal structure, and magnetic properties of two bent trinuclear Cu(II)/Ni(II) complexes of ligands derived from N-acyl-salicylhydrazides. Inorganic Chemistry Communications, 11, 1044–1047. DOI: 10.1016/j.inoche.2008.05.024. http://dx.doi.org/10.1016/j.inoche.2008.05.02410.1016/j.inoche.2008.05.024Search in Google Scholar
[14] Luo, W., Wang, X. T., Meng, X. G., Cheng, G. Z., & Ji, Z. P. (2009a). Metal coordination architectures of N-acylsalicylhydrazides: The effect of metal ions and steric repulsion of ligands to their structures of polynuclear metal complexes. Polyhedron, 28, 300–306. DOI: 10.1016/j.poly.2008.10.055. http://dx.doi.org/10.1016/j.poly.2008.10.05510.1016/j.poly.2008.10.055Search in Google Scholar
[15] Luo, Y. M., Chen, Z., Tang, R. R., Xiao, L. X., & Peng, H. J. (2008a). Investigations into the synthesis and fluorescence properties of Eu(III), Tb(III), Sm(III) and Gd(III) complexes of a novel bis-β-diketone-type ligand. Spectrochimica Acta Part A, 69, 513–516. DOI: 10.1016/j.saa.2007.04.029. http://dx.doi.org/10.1016/j.saa.2007.04.02910.1016/j.saa.2007.04.029Search in Google Scholar PubMed
[16] Mezei, G., Zaleski, C. M., & Pecoraro, V. L. (2007). Structural and functional evolution of metallacrowns. Chemical Reviews, 107, 4933–5003. DOI: 10.1021/cr078200h. http://dx.doi.org/10.1021/cr078200h10.1021/cr078200hSearch in Google Scholar PubMed
[17] Miao, Y. L., Liu, J. L., Lin, Z. J., Ou, Y. C., Leng, J. D., & Tong, M. L. (2010). Synthesis, structures, adsorption behaviour and magnetic properties of a new family of polynuclear iron clusters. Dalton Transactions, 39, 4893–4902. DOI: 10.1039/C000126K. http://dx.doi.org/10.1039/c000126k10.1039/c000126kSearch in Google Scholar PubMed
[18] Ondrejovič, G., Koman, M., & Kotočová, A. (2008). Structural and electronic effects involving pyridine rings in 4-methylpyridine Cu4OX6L4 complexes. I. Vibrational spectra of Cu4OBrnCl(6−n)(4-Mepy)4 complexes. Chemical Papers, 62, 480–486. DOI: 10.2478/s11696-008-0055-6. http://dx.doi.org/10.2478/s11696-008-0055-610.2478/s11696-008-0055-6Search in Google Scholar
[19] Ondrejovič, G., Kotočová, A., Koman, M., & Segła, P. (2010a). Synthesis, spectral and electrochemical study of coordination molecules Cu4OX6L4: 4-cyanopyridine Cu4OBrnCl(6−n)(4-CNpy)4 complexes. Chemical Papers, 64, 329–338. DOI: 10.2478/s11696-010-0015-9. http://dx.doi.org/10.2478/s11696-010-0015-910.2478/s11696-010-0015-9Search in Google Scholar
[20] Ondrejovič, G., Kotočová, A., Koman, M., & Segła, P. (2010b). Synthesis, spectral and electrochemical study of coordination molecules Cu4OX6L4: 3-cyanopyridine Cu4OBrnCl(6−n)(3-CNpy)4 complexes. Chemical Papers, 64, 339–345. DOI: 10.2478/s11696-010-0016-8. http://dx.doi.org/10.2478/s11696-010-0016-810.2478/s11696-010-0016-8Search in Google Scholar
[21] Peng, R., Wu, T., & Li, D. (2005). A chiral coordination polymer containing copper(I) iodide layer composed of intersecting [CuI]n helices. CrystEngComm, 7, 595–598. DOI: 10.1039/B511708A. http://dx.doi.org/10.1039/b511708a10.1039/b511708aSearch in Google Scholar
[22] Perry IV, J. J., Perman, J. A., & Zaworotko, M. J. (2009). Design and synthesis of metal-organic frameworks using metal-organic polyhedra as supermolecular building blocks. Chemical Society Reviews, 38, 1400–1417. DOI: 10.1039/B807086P. http://dx.doi.org/10.1039/b807086p10.1039/b807086pSearch in Google Scholar
[23] Sheldrick, G. M. (2003). SADABS, Version 2.10. Göttingen, Germany: University of Göttingen. Search in Google Scholar
[24] Siemens AXS (1998). SMART and SAINT, Version 5.0. Area detector control and integration software. Madison, WI, USA: Siemens AXS Inc. Search in Google Scholar
[25] Teixidor, F., Garcia, R., Pons, J., & Casabó, J. (1988). Metal derivatives of 1,3-bis(2-pyridyl)-1,3-propanedione and N,N′-dimethyl-1,3-bis(2-pyridyl)-1,3-propanedione. Polyhedron, 7, 43–47. DOI: 10.1016/S0277-5387(00)81180-8. http://dx.doi.org/10.1016/S0277-5387(00)81180-810.1016/S0277-5387(00)81180-8Search in Google Scholar
[26] Vaidhyanathan, R., Natarajan, S., & Rao, C. N. R. (2003). Solvothermal synthesis of a layered open-framework chlorocadmium oxalate, Cd2(C2O4)0.5Cl3NaCl·4H2O. European Journal of Inorganic Chemistry, 2003, 1675–1680. DOI: 10.1002/ejic.200200612. http://dx.doi.org/10.1002/ejic.20020061210.1002/ejic.200200612Search in Google Scholar
[27] Xia, C. K., Lu, C. Z., Zhang, Q. Z., He, X., Zhang, J. J., & Wu, D. M. (2005). Syntheses, structures, and photoluminescent properties of three silver(I) coordination polymers with 2-(4-pyridyl)benzimidazole. Crystal Growth & Design, 5, 1569–1574. DOI: 10.1021/cg050040k. http://dx.doi.org/10.1021/cg050040k10.1021/cg050040kSearch in Google Scholar
[28] Yaghi, O. M., O’Keeffe, M., Ockwig, N. W., Chae, H. K., Eddaoudi, M., & Kim, J. (2003). Reticular synthesis and the design of new materials. Nature, 423, 705–714. DOI: 10.1038/nature01650. http://dx.doi.org/10.1038/nature0165010.1038/nature01650Search in Google Scholar PubMed
[29] Yu, F. S., Zhang, L. L., Tan, J. T., Li, X., Wang, L. J., Liu, F., & Yang, X. W. (2011). Synthesis, crystal structure, and thermal analysis of a copper(II) complex with imidazo[4,5-f]1,10-phenantroline. Chemical Papers, 65, 23–28. DOI: 10.2478/s11696-010-0087-6. http://dx.doi.org/10.2478/s11696-010-0087-610.2478/s11696-010-0087-6Search in Google Scholar
[30] Zerkowski, J. A., & Whitesides, G. M. (1994). Steric control of secondary, solid-state architecture in 1:1 complexes of melamines and barbiturates that crystallize as crinkled tapes. Journal of the American Chemical Society, 116, 4298–4304. DOI: 10.1021/ja00089a019. http://dx.doi.org/10.1021/ja00089a01910.1021/ja00089a019Search in Google Scholar
© 2011 Institute of Chemistry, Slovak Academy of Sciences
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Articles in the same Issue
- Layered double hydroxides — multifunctional nanomaterials
- A novel reagent for spectroscopic determination of Mo(VI)
- Influence of chemical composition of nanocrystalline iron’s surface on the rates of two parallel reactions: nitriding and catalytic decomposition of ammonia
- Application of 2-(octylsulphanyl)benzoic acid as Pb2+ selective ionophore in hybrid membrane system
- Additive-assisted Rupe rearrangement of 1-ethynylcyclohexan-1-ol in near-critical water
- Treatment of acidic palm oil for fatty acid methyl esters production
- Synthesis, structure, and luminescent properties of two novel polynuclear complexes of 1,3-di(pyridin-2-yl)propane-1,3-dione
- Mixed-ligand complexes of boric acid with organic biomolecules
- Ultrasound-assisted rapid synthesis of β-aminoketones with direct-type catalytic Mannich reaction using bismuth(III) triflate in aqueous media at room temperature
- Design, synthesis, preliminary pharmacological evaluation, and docking studies of pyrazoline derivatives
- One-pot synthesis and luminescent spectra of 3-allyl substituted quinazoline-2,4-dione derivatives as allyl capping agents