Startseite Naturwissenschaften Application of Aqueous-Based Covalent Crosslinking Strategies to the Formation of Metal Chalcogenide Gels and Aerogels
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Application of Aqueous-Based Covalent Crosslinking Strategies to the Formation of Metal Chalcogenide Gels and Aerogels

  • Indika K. Hewavitharana und Stephanie L. Brock EMAIL logo
Veröffentlicht/Copyright: 25. April 2018
Zeitschrift für Physikalische Chemie
Aus der Zeitschrift Zeitschrift für Physikalische Chemie Band 232 Heft 9-11

Abstract

An aqueous-based metal ion crosslinking approach for assembly of metal chalcogenide nanoparticles (NPs) into robust gels is reported. Short chalcogenide ligands (S2−) undergo crosslinking with metal salts (Sn4+) to form a gel [NP/S2−/Sn4+]n (NP=PbTe, PbS, CdS, CdSe). The corresponding aerogel networks retain the crystallinity and quantum confinement effects of the native building blocks while achieving excellent porosity [Brunauer–Emmett–Teller (BET) surface areas of 160–238 m2/g]. Treatment of sulfide-capped PbTe nanoparticles with an excess of Sn4+ leads to ion exchange and formation of an amorphous “SnTe” gel.

Keywords: aqueous medium; ion-exchange; metal ion crosslinking; porosity; quantum dots; surface area

Dedicated to Alexander Eychmüller on the occasion of his 60th birthday.

Acknowledgments

We thank the U.S. National Science Foundation (NSF) for support of this work via CHE-1709776. This work made use of the following instrumentation supported by NSF awards: JEOL 2010 TEM (NSF-0216084), PXRD facility (NSF-1427926).

References

1. C. R. Kagan, E. Lifshitz, E. H. Sargent, D. V. Talapin, Science 353 (2016) 885.10.1126/science.aac5523Suche in Google Scholar PubMed

2. G. H. Carey, A. L. Abdelhady, Z. J. Ning, S. M. Thon, O. M. Bakr, E. H. Sargent, Chem. Rev. 115 (2015) 12732.10.1021/acs.chemrev.5b00063Suche in Google Scholar PubMed

3. V. Sayevich, B. Cai, A. Benad, D. Haubold, L. Sonntag, N. Gaponik, V. Lesnyak, A. Eychmüller, Angew. Chem. Int. Ed. 55 (2016) 6334.10.1002/anie.201600094Suche in Google Scholar PubMed

4. J. Y. Kim, N. A. Kotov, Chem. Mater. 26 (2014) 134.10.1021/cm402675kSuche in Google Scholar

5. M. Kuno, J. K. Lee, B. O. Dabbousi, F. V. Mikulec, M. G. Bawendi, J. Chem. Phys. 106 (1997) 9869.10.1063/1.473875Suche in Google Scholar

6. M. Soreni-Harari, D. Mocatta, M. Zimin, Y. Gannot, U. Banin, N. Tessler, Adv. Funct. Mater. 20 (2010) 1005.10.1002/adfm.200902149Suche in Google Scholar

7. M. V. Kovalenko, B. Spokoyny, J. S. Lee, M. Scheele, A. Weber, S. Perera, D. Landry, D. V. Talapin, J. Am. Chem. Soc. 132 (2010) 6686.10.1021/ja909591xSuche in Google Scholar PubMed

8. M. V. Kovalenko, M. I. Bodnarchuk, J. Zaumseil, J. S. Lee, D. V. Talapin, J. Am. Chem. Soc. 132 (2010) 10085.10.1021/ja1024832Suche in Google Scholar PubMed

9. M. V. Kovalenko, M. I. Bodnarchuk, D. V. Talapin, J. Am. Chem. Soc. 132 (2010) 15124.10.1021/ja106841fSuche in Google Scholar PubMed

10. J. L. Mohanan, I. U. Arachchige, S. L. Brock, Science 307 (2005) 397.10.1126/science.1104226Suche in Google Scholar

11. L. Korala, L. Li, S. L. Brock, Chem. Commun. 48 (2012) 8523.10.1039/c2cc34188cSuche in Google Scholar PubMed PubMed Central

12. L. Korala, Z. J. Wang, Y. Liu, S. Maldonado, S. L. Brock, ACS Nano 7 (2013) 1215.10.1021/nn304563jSuche in Google Scholar PubMed PubMed Central

13. I. U. Arachchige, S. L. Brock, J. Am. Chem. Soc. 129 (2007) 1840.10.1021/ja066749cSuche in Google Scholar PubMed

14. H. Dollefeld, K. Hoppe, J. Kolny, K. Schilling, H. Weller, A. Eychmüller, PCCP 4 (2002) 4747.10.1039/B202101CSuche in Google Scholar

15. N. Gaponik, A. Wolf, R. Marx, V. Lesnyak, K. Schilling, A. Eychmüller, Adv. Mater. 20 (2008) 4257.10.1002/adma.200702986Suche in Google Scholar

16. H. Dollefeld, H. Weller, A. Eychmüller, Nano Lett. 1 (2001) 267.10.1021/nl015524rSuche in Google Scholar

17. N. Gaponik, A.-K. Herrmann, A. Eychmüller, J. Phys. Chem. Lett. 3 (2011) 8.10.1021/jz201357rSuche in Google Scholar

18. I. R. Pala, I. U. Arachchige, D. G. Georgiev, S. L. Brock, Angew. Chem. Int. Ed. Engl. 49 (2010) 3661.10.1002/anie.201000034Suche in Google Scholar PubMed

19. A. Singh, B. A. Lindquist, G. K. Ong, R. B. Jadrich, A. Singh, H. Ha, C. J. Ellison, T. M. Truskett, D. J. Milliron, Angew. Chem. Int. Ed. Engl. 54 (2015) 14840.10.1002/anie.201508641Suche in Google Scholar PubMed

20. A. Wolf, V. Lesnyak, N. Gaponik, A. Eychmüller, J. Phys. Chem. Lett. 3 (2012) 2188.10.1021/jz300726nSuche in Google Scholar PubMed

21. S. Ganguly, S. L. Brock, J. Mater. Chem. 21 (2011) 8800.10.1039/c1jm11015bSuche in Google Scholar

22. J. Hühn, C. Carrillo-Carrion, M. G. Soliman, C. Pfeiffer, D. Valdeperez, A. Masood, I. Chakraborty, L. Zhu, M. Gallego, Z. Yue, M. Carril, N. Feliu, A. Escudero, A. M. Alkilany, B. Pelaz, P. D. Pino, W. J. Parak, Chem. Mater. 29 (2017) 399.10.1021/acs.chemmater.6b04738Suche in Google Scholar

23. C. W. Zhang, Y. Xia, Z. M. Zhang, Z. Huang, L. Y. Lian, X. S. Miao, D. L. Zhang, M. C. Beard, J. B. Zhang, Chem. Mater. 29 (2017) 3615.10.1021/acs.chemmater.7b00411Suche in Google Scholar

24. B. D. Chernomordik, A. R. Marshall, G. F. Pach, J. M. Luther, M. C. Beard, Chem. Mater. 29 (2017) 189.10.1021/acs.chemmater.6b02939Suche in Google Scholar

25. I. K. Hewavitharana, S. L. Brock, ACS Nano 11 (2017) 11217.10.1021/acsnano.7b05534Suche in Google Scholar PubMed

26. S. Bag, M. G. Kanatzidis, J. Am. Chem. Soc. 132 (2010) 14951.10.1021/ja1059284Suche in Google Scholar PubMed

27. G. N. Liu, G. C. Guo, F. Chen, S. P. Guo, X. M. Jiang, C. Yang, M. S. Wang, M. F. Wu, J. S. Huang, CrystEngComm 12 (2010) 4035.10.1039/c0ce00292eSuche in Google Scholar

28. K. K. Rangan, P. N. Trikalitis, C. Canlas, T. Bakas, D. P. Weliky, M. G. Kanatzidis, Nano Lett. 2 (2002) 513.10.1021/nl025502kSuche in Google Scholar

29. L. Protesescu, M. Nachtegaal, O. Voznyy, O. Borovinskaya, A. J. Rossini, L. Emsley, C. Coperet, D. Gunther, E. H. Sargent, M. V. Kovalenko, J. Am. Chem. Soc. 137 (2015) 1862.10.1021/ja510862cSuche in Google Scholar PubMed PubMed Central

30. Y. Oh, S. Bag, C. D. Malliakas, M. G. Kanatzidis, Chem. Mater. 23 (2011) 2447.10.1021/cm2003462Suche in Google Scholar

31. A. Nag, D. S. Chung, D. S. Dolzhnikov, N. M. Dimitrijevic, S. Chattopadhyay, T. Shibata, D. V. Talapin, J. Am. Chem. Soc. 134 (2012) 13604.10.1021/ja301285xSuche in Google Scholar PubMed

32. K. K. Kalebaila, S. L. Brock, Z. Anorg. Allg. Chem. 638 (2012) 2598.10.1002/zaac.201200354Suche in Google Scholar

33. H. Yu, S. L. Brock, ACS Nano 2 (2008) 1563.10.1021/nn8002295Suche in Google Scholar PubMed

Received: 2018-03-01
Accepted: 2018-03-10
Published Online: 2018-04-25
Published in Print: 2018-08-28

©2018 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Preface
  3. Congratulations to Alexander Eychmüller
  4. Halogens in the Synthesis of Colloidal Semiconductor Nanocrystals
  5. Controlled Aqueous Synthesis of CdSe Quantum Dots using Double-Hydrophilic Block Copolymers as Stabilizers
  6. Fabrication of Ag2S/CdS Heterostructured Nanosheets via Self-Limited Cation Exchange
  7. Ion-Selective Ligands: How Colloidal Nano- and Micro-Particles Can Introduce New Functionalities
  8. TEM, FTIR and Electrochemistry Study: Desorption of PVP from Pt Nanocubes
  9. Incorporation of CdTe Nanocrystals into Metal Oxide Matrices Towards Inorganic Nanocomposite Materials
  10. Diatoms – A “Green” Way to Biosynthesize Gold-Silica Nanocomposites?
  11. Evidence for Photo-Switchable Carrier Mobilities in Blends of PbS Nanocrystals and Photochromic Dithienylcyclopentene Derivatives
  12. Gelation-Assisted Layer-by-Layer Deposition of High Performance Nanocomposites
  13. Enhancement of the Fluorescence Quantum Yield of Thiol-Stabilized CdTe Quantum Dots Through Surface Passivation with Sodium Chloride and Bicarbonate
  14. Fluorescence Quenching of CdTe Quantum Dots with Co (III) Complexes via Electrostatic Assembly Formation
  15. Colloidal Photoluminescent Refractive Index Nanosensor Using Plasmonic Effects
  16. Towards Low-Toxic Colloidal Quantum Dots
  17. Color-Enrichment Semiconductor Nanocrystals for Biorhythm-Friendly Backlighting
  18. Transient Absorption Studies on Nanostructured Materials and Composites: Towards the Development of New Photocatalytic Systems
  19. Transient Spectroscopy of Glass-Embedded Perovskite Quantum Dots: Novel Structures in an Old Wrapping
  20. Energy Transfer Between Single Semiconductor Quantum Dots and Organic Dye Molecules
  21. Chemical Routes to Surface Enhanced Infrared Absorption (SEIRA) Substrates
  22. Plasmonic Cu/CuCl/Cu2S/Ag and Cu/CuCl/Cu2S/Au Supports with Peroxidase-Like Activity: Insights from Surface Enhanced Raman Spectroscopy
  23. n-Type Cu2O/α-Fe2O3 Heterojunctions by Electrochemical Deposition: Tuning of Cu2O Thickness for Maximum Photoelectrochemical Performance
  24. The Photoelectrochemistry of Assemblies of Semiconductor Nanoparticles at Interfaces
  25. Surface-Charge Dependent Orientation of Water at the Interface of a Gold Electrode: A Cluster Study
  26. Single Particle Spectroscopy of Radiative Processes in Colloid-to-Film-Coupled Nanoantennas
  27. Coupled Plasmon Resonances and Gap Modes in Laterally Assembled Gold Nanorod Arrays
  28. Anisotropy of Structure and Optical Properties of Self-Assembled and Oriented Colloidal CdSe Nanoplatelets
  29. Simple Electroless Synthesis of Cobalt Nanoparticle Chains, Oriented by Externally Applied Magnetic Fields
  30. Functionalization of Graphene Aerogels and their Applications in Energy Storage and Conversion
  31. Macroscopic Aerogels with Retained Nanoscopic Plasmonic Properties
  32. Application of Aqueous-Based Covalent Crosslinking Strategies to the Formation of Metal Chalcogenide Gels and Aerogels
  33. Cellulose-Based Hydrogels with Controllable Electrical and Mechanical Properties
  34. Naphthalenetetracarboxylic Diimide Derivatives: Molecular Structure, Thin Film Properties and Solar Cell Applications
  35. Metal-Phenolic Encapsulated Mesoporous Silica Nanoparticles for pH-Responsive Drug Delivery and Magnetic Resonance Imaging
  36. Extraction of K2CO3 from Low Concentration [K+] Solutions with the Aid of CO2: A Study on the Metastable Phase Equilibrium of K2CO3-Na2CO3-H2O Ternary System
https://doi.org/10.1515/zpch-2018-1171
Schlagwörter für diesen Artikel
aqueous medium; ion-exchange; metal ion crosslinking; porosity; quantum dots; surface area

Artikel in diesem Heft

  1. Frontmatter
  2. Preface
  3. Congratulations to Alexander Eychmüller
  4. Halogens in the Synthesis of Colloidal Semiconductor Nanocrystals
  5. Controlled Aqueous Synthesis of CdSe Quantum Dots using Double-Hydrophilic Block Copolymers as Stabilizers
  6. Fabrication of Ag2S/CdS Heterostructured Nanosheets via Self-Limited Cation Exchange
  7. Ion-Selective Ligands: How Colloidal Nano- and Micro-Particles Can Introduce New Functionalities
  8. TEM, FTIR and Electrochemistry Study: Desorption of PVP from Pt Nanocubes
  9. Incorporation of CdTe Nanocrystals into Metal Oxide Matrices Towards Inorganic Nanocomposite Materials
  10. Diatoms – A “Green” Way to Biosynthesize Gold-Silica Nanocomposites?
  11. Evidence for Photo-Switchable Carrier Mobilities in Blends of PbS Nanocrystals and Photochromic Dithienylcyclopentene Derivatives
  12. Gelation-Assisted Layer-by-Layer Deposition of High Performance Nanocomposites
  13. Enhancement of the Fluorescence Quantum Yield of Thiol-Stabilized CdTe Quantum Dots Through Surface Passivation with Sodium Chloride and Bicarbonate
  14. Fluorescence Quenching of CdTe Quantum Dots with Co (III) Complexes via Electrostatic Assembly Formation
  15. Colloidal Photoluminescent Refractive Index Nanosensor Using Plasmonic Effects
  16. Towards Low-Toxic Colloidal Quantum Dots
  17. Color-Enrichment Semiconductor Nanocrystals for Biorhythm-Friendly Backlighting
  18. Transient Absorption Studies on Nanostructured Materials and Composites: Towards the Development of New Photocatalytic Systems
  19. Transient Spectroscopy of Glass-Embedded Perovskite Quantum Dots: Novel Structures in an Old Wrapping
  20. Energy Transfer Between Single Semiconductor Quantum Dots and Organic Dye Molecules
  21. Chemical Routes to Surface Enhanced Infrared Absorption (SEIRA) Substrates
  22. Plasmonic Cu/CuCl/Cu2S/Ag and Cu/CuCl/Cu2S/Au Supports with Peroxidase-Like Activity: Insights from Surface Enhanced Raman Spectroscopy
  23. n-Type Cu2O/α-Fe2O3 Heterojunctions by Electrochemical Deposition: Tuning of Cu2O Thickness for Maximum Photoelectrochemical Performance
  24. The Photoelectrochemistry of Assemblies of Semiconductor Nanoparticles at Interfaces
  25. Surface-Charge Dependent Orientation of Water at the Interface of a Gold Electrode: A Cluster Study
  26. Single Particle Spectroscopy of Radiative Processes in Colloid-to-Film-Coupled Nanoantennas
  27. Coupled Plasmon Resonances and Gap Modes in Laterally Assembled Gold Nanorod Arrays
  28. Anisotropy of Structure and Optical Properties of Self-Assembled and Oriented Colloidal CdSe Nanoplatelets
  29. Simple Electroless Synthesis of Cobalt Nanoparticle Chains, Oriented by Externally Applied Magnetic Fields
  30. Functionalization of Graphene Aerogels and their Applications in Energy Storage and Conversion
  31. Macroscopic Aerogels with Retained Nanoscopic Plasmonic Properties
  32. Application of Aqueous-Based Covalent Crosslinking Strategies to the Formation of Metal Chalcogenide Gels and Aerogels
  33. Cellulose-Based Hydrogels with Controllable Electrical and Mechanical Properties
  34. Naphthalenetetracarboxylic Diimide Derivatives: Molecular Structure, Thin Film Properties and Solar Cell Applications
  35. Metal-Phenolic Encapsulated Mesoporous Silica Nanoparticles for pH-Responsive Drug Delivery and Magnetic Resonance Imaging
  36. Extraction of K2CO3 from Low Concentration [K+] Solutions with the Aid of CO2: A Study on the Metastable Phase Equilibrium of K2CO3-Na2CO3-H2O Ternary System
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