Abstract
In this review, we highlight the role of halogenated compounds in the colloidal synthesis of nanostructured semiconductors. Halogen-containing metallic salts used as precursors and halogenated hydrocarbons used as ligands allow stabilizing different shapes and crystal phases, and enable the formation of colloidal systems with different dimensionality. We summarize recent reports on the tremendous influence of these compounds on the physical properties of nanocrystals, like field-effect mobility and solar cell performance and outline main analytical methods for the nanocrystal surface control.
Dedicated to: Alexander Eychmüller on the occasion of his 60th birthday.
Acknowledgements
The authors thank Beatriz H. Juarez for critically reading the manuscript and helpful suggestions. The authors gratefully acknowledge financial support of the European Research Council via the ERC Starting Grant “2D-SYNETRA” (Seventh Framework Program FP7, Project: 304980) and thank the German Research Foundation DFG for financial support in the frame of the Cluster of Excellence “Center of ultrafast imaging CUI”. C.K. thanks the German Research Foundation DFG for financial support in the frame the Heisenberg scholarship KL 1453/9-2. MMRM thanks PIER Helmholtz Graduate School for the financial support.
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©2018 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Preface
- Congratulations to Alexander Eychmüller
- Halogens in the Synthesis of Colloidal Semiconductor Nanocrystals
- Controlled Aqueous Synthesis of CdSe Quantum Dots using Double-Hydrophilic Block Copolymers as Stabilizers
- Fabrication of Ag2S/CdS Heterostructured Nanosheets via Self-Limited Cation Exchange
- Ion-Selective Ligands: How Colloidal Nano- and Micro-Particles Can Introduce New Functionalities
- TEM, FTIR and Electrochemistry Study: Desorption of PVP from Pt Nanocubes
- Incorporation of CdTe Nanocrystals into Metal Oxide Matrices Towards Inorganic Nanocomposite Materials
- Diatoms – A “Green” Way to Biosynthesize Gold-Silica Nanocomposites?
- Evidence for Photo-Switchable Carrier Mobilities in Blends of PbS Nanocrystals and Photochromic Dithienylcyclopentene Derivatives
- Gelation-Assisted Layer-by-Layer Deposition of High Performance Nanocomposites
- Enhancement of the Fluorescence Quantum Yield of Thiol-Stabilized CdTe Quantum Dots Through Surface Passivation with Sodium Chloride and Bicarbonate
- Fluorescence Quenching of CdTe Quantum Dots with Co (III) Complexes via Electrostatic Assembly Formation
- Colloidal Photoluminescent Refractive Index Nanosensor Using Plasmonic Effects
- Towards Low-Toxic Colloidal Quantum Dots
- Color-Enrichment Semiconductor Nanocrystals for Biorhythm-Friendly Backlighting
- Transient Absorption Studies on Nanostructured Materials and Composites: Towards the Development of New Photocatalytic Systems
- Transient Spectroscopy of Glass-Embedded Perovskite Quantum Dots: Novel Structures in an Old Wrapping
- Energy Transfer Between Single Semiconductor Quantum Dots and Organic Dye Molecules
- Chemical Routes to Surface Enhanced Infrared Absorption (SEIRA) Substrates
- Plasmonic Cu/CuCl/Cu2S/Ag and Cu/CuCl/Cu2S/Au Supports with Peroxidase-Like Activity: Insights from Surface Enhanced Raman Spectroscopy
- n-Type Cu2O/α-Fe2O3 Heterojunctions by Electrochemical Deposition: Tuning of Cu2O Thickness for Maximum Photoelectrochemical Performance
- The Photoelectrochemistry of Assemblies of Semiconductor Nanoparticles at Interfaces
- Surface-Charge Dependent Orientation of Water at the Interface of a Gold Electrode: A Cluster Study
- Single Particle Spectroscopy of Radiative Processes in Colloid-to-Film-Coupled Nanoantennas
- Coupled Plasmon Resonances and Gap Modes in Laterally Assembled Gold Nanorod Arrays
- Anisotropy of Structure and Optical Properties of Self-Assembled and Oriented Colloidal CdSe Nanoplatelets
- Simple Electroless Synthesis of Cobalt Nanoparticle Chains, Oriented by Externally Applied Magnetic Fields
- Functionalization of Graphene Aerogels and their Applications in Energy Storage and Conversion
- Macroscopic Aerogels with Retained Nanoscopic Plasmonic Properties
- Application of Aqueous-Based Covalent Crosslinking Strategies to the Formation of Metal Chalcogenide Gels and Aerogels
- Cellulose-Based Hydrogels with Controllable Electrical and Mechanical Properties
- Naphthalenetetracarboxylic Diimide Derivatives: Molecular Structure, Thin Film Properties and Solar Cell Applications
- Metal-Phenolic Encapsulated Mesoporous Silica Nanoparticles for pH-Responsive Drug Delivery and Magnetic Resonance Imaging
- Extraction of K2CO3 from Low Concentration [K+] Solutions with the Aid of CO2: A Study on the Metastable Phase Equilibrium of K2CO3-Na2CO3-H2O Ternary System
Artikel in diesem Heft
- Frontmatter
- Preface
- Congratulations to Alexander Eychmüller
- Halogens in the Synthesis of Colloidal Semiconductor Nanocrystals
- Controlled Aqueous Synthesis of CdSe Quantum Dots using Double-Hydrophilic Block Copolymers as Stabilizers
- Fabrication of Ag2S/CdS Heterostructured Nanosheets via Self-Limited Cation Exchange
- Ion-Selective Ligands: How Colloidal Nano- and Micro-Particles Can Introduce New Functionalities
- TEM, FTIR and Electrochemistry Study: Desorption of PVP from Pt Nanocubes
- Incorporation of CdTe Nanocrystals into Metal Oxide Matrices Towards Inorganic Nanocomposite Materials
- Diatoms – A “Green” Way to Biosynthesize Gold-Silica Nanocomposites?
- Evidence for Photo-Switchable Carrier Mobilities in Blends of PbS Nanocrystals and Photochromic Dithienylcyclopentene Derivatives
- Gelation-Assisted Layer-by-Layer Deposition of High Performance Nanocomposites
- Enhancement of the Fluorescence Quantum Yield of Thiol-Stabilized CdTe Quantum Dots Through Surface Passivation with Sodium Chloride and Bicarbonate
- Fluorescence Quenching of CdTe Quantum Dots with Co (III) Complexes via Electrostatic Assembly Formation
- Colloidal Photoluminescent Refractive Index Nanosensor Using Plasmonic Effects
- Towards Low-Toxic Colloidal Quantum Dots
- Color-Enrichment Semiconductor Nanocrystals for Biorhythm-Friendly Backlighting
- Transient Absorption Studies on Nanostructured Materials and Composites: Towards the Development of New Photocatalytic Systems
- Transient Spectroscopy of Glass-Embedded Perovskite Quantum Dots: Novel Structures in an Old Wrapping
- Energy Transfer Between Single Semiconductor Quantum Dots and Organic Dye Molecules
- Chemical Routes to Surface Enhanced Infrared Absorption (SEIRA) Substrates
- Plasmonic Cu/CuCl/Cu2S/Ag and Cu/CuCl/Cu2S/Au Supports with Peroxidase-Like Activity: Insights from Surface Enhanced Raman Spectroscopy
- n-Type Cu2O/α-Fe2O3 Heterojunctions by Electrochemical Deposition: Tuning of Cu2O Thickness for Maximum Photoelectrochemical Performance
- The Photoelectrochemistry of Assemblies of Semiconductor Nanoparticles at Interfaces
- Surface-Charge Dependent Orientation of Water at the Interface of a Gold Electrode: A Cluster Study
- Single Particle Spectroscopy of Radiative Processes in Colloid-to-Film-Coupled Nanoantennas
- Coupled Plasmon Resonances and Gap Modes in Laterally Assembled Gold Nanorod Arrays
- Anisotropy of Structure and Optical Properties of Self-Assembled and Oriented Colloidal CdSe Nanoplatelets
- Simple Electroless Synthesis of Cobalt Nanoparticle Chains, Oriented by Externally Applied Magnetic Fields
- Functionalization of Graphene Aerogels and their Applications in Energy Storage and Conversion
- Macroscopic Aerogels with Retained Nanoscopic Plasmonic Properties
- Application of Aqueous-Based Covalent Crosslinking Strategies to the Formation of Metal Chalcogenide Gels and Aerogels
- Cellulose-Based Hydrogels with Controllable Electrical and Mechanical Properties
- Naphthalenetetracarboxylic Diimide Derivatives: Molecular Structure, Thin Film Properties and Solar Cell Applications
- Metal-Phenolic Encapsulated Mesoporous Silica Nanoparticles for pH-Responsive Drug Delivery and Magnetic Resonance Imaging
- Extraction of K2CO3 from Low Concentration [K+] Solutions with the Aid of CO2: A Study on the Metastable Phase Equilibrium of K2CO3-Na2CO3-H2O Ternary System