Carbon dioxide adsorption onto modified polyvinyl chloride with ionic liquid
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Narmin Noorani
,
Abbas Mehrdad
,
Iraj Ahadzadeh
Abstract
To modify polyvinylchloride membranes for carbon dioxide gas separation, six polyvinyl chloride-g-polyionic liquid ionomers such as polyvinylchloride-g-poly1-vinyl-3-hexylimidazolium bromide (PVC-g-P[VHIm][Br]), polyvinylchloride-g-poly1-vinyl-3-hexylimidazolium thiocyanate (PVC-g-P[VHIm][SCN]), polyvinylchloride-g-poly1-vinyl-3-hexylimidazolium tetrafluoroborate (PVC-g-P[VHIm][ BF4]), polyvinylchloride-g-poly1-vinyl-3-octylimidazolium bromide (PVC-g-P[VOIm][Br]), polyvinylchloride-g-poly1-vinyl-3-octylimidazolium thiocyanate (PVC-g-P[VOIm][SCN]) and polyvinylchloride-g-poly1-vinyl-3-octylimidazolium tetrafluoroborate (PVC-g-P[VOIm][ BF4]) were synthesized. The polyvinyl chloride-g-polyionic liquid ionomers were characterized using elemental analyzer (CHN) and Fourier transform infrared spectroscopy (FTIR) techniques. CO2 adsorption onto these ionomers was measured by quartz crystal microbalance (QCM) and the experimental data were correlated by the sorption model. The parameters obtained imply that CO2 adsorption has an exothermic and physisorption nature. Also, the investigations point to that the PVC-g-P[VHIm][SCN] has better performance for CO2 separation.
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Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: None declared.
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Conflict of interest statement: The authors declare that they have no known competing financial and non financial interest so personal relationships that could have appeared to influence the work reported in this paper.
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Supplementary Material
The online version of this article offers supplementary material (https://doi.org/10.1515/polyeng-2021-0332).
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Artikel in diesem Heft
- Frontmatter
- Material Properties
- Development and characterization of eco-friendly biopolymer gellan gum based electrolyte for electrochemical application
- Structural transitions and rheological properties of poly-d-lysine hydrobromide: effect of pH, salt, temperature, and shear rate
- Carbon dioxide adsorption onto modified polyvinyl chloride with ionic liquid
- Synergistic effect of organic-Zn(H2PO2)2 and lithium containing polyhedral oligomeric phenyl silse-squioxane on flame-retardant, thermal and mechanical properties of poly(ethylene terephthalate)
- Preparation and Assembly
- Network structural hardening of polypropylene matrix using hybrid of 0D, 1D and 2D carbon-ceramic nanoparticles with enhanced mechanical and thermomechanical properties
- An environment friendly hemp fiber modified with phytic acid for enhancing fire safety of automobile parts
- Flexible silicone rubber/carbon fiber/nano-diamond composites with enhanced thermal conductivity via reducing the interface thermal resistance
- In situ synthesis of Ag NPs in the galactomannan based biodegradable composite for the development of active packaging films
- Engineering and Processing
- Multi-objective optimization of injection molded parts with insert based on IFOA-GRNN-NSGA-II
