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Flexible silicone rubber/carbon fiber/nano-diamond composites with enhanced thermal conductivity via reducing the interface thermal resistance

  • Chaoyu Wang , Junqi Shen , Zhi Hao EMAIL logo , Zhu Luo , Zong Shen , Xiaolong Li , Le Yang and Qin Zhou
Published/Copyright: March 30, 2022
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Abstract

Insulating materials with heat dissipation are urgently required for modern electronic devices and systems. In this study, 4,4-methylene diphenyl diisocyanate was used as the coupling agent, and nano-diamond (ND) particles were grafted onto the surface of carbon fibers (CFs) to prepare CF-ND/silicone rubber (SR) composites. The ND acted as a “bridge” among CFs, which can reduce the interface thermal resistance between CFs because the dot-like ND can increase the interfacial area of CFs, making it easier to form heat-conducting networks between SR. When the content of CF-ND (1:6) was 20%, the thermal conductivity of the SR composite was 0.305 W/(m·K), 69% higher than that of pure SR. The ND between CFs can improve the dynamic mechanical properties by acting as a crack pinhole. In addition, the CF-ND/SR composites also exhibited excellent thermal stability. This work has enormous potential for advanced electronic devices.


Corresponding author: Zhi Hao, College of Materials and Metallurgy, Guizhou University, Guiyang 550025, China, E-mail:
Chaoyu Wang and Junqi Shen contributed equally to this work.

Funding source: Scientific Research Project of Introducing Talents of Guizhou University

Award Identifier / Grant number: [2020] 53

Funding source: the Science and Technology Department of Guizhou Province

Award Identifier / Grant number: Grant No. Platform &Talents [2019] 2030

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was supported by Scientific Research Project of Introducing Talents of Guizhou University ([2020] 53) and financially supported by the Science and Technology Department of Guizhou Province (grant no. Platform & Talents [2019] 2030).

  3. Conflict of interest statement: The authors declare that they have no conflicts of interest regarding this article.

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Received: 2021-11-06
Accepted: 2022-02-16
Published Online: 2022-03-30
Published in Print: 2022-07-26

© 2022 Walter de Gruyter GmbH, Berlin/Boston

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