Flexible silicone rubber/carbon fiber/nano-diamond composites with enhanced thermal conductivity via reducing the interface thermal resistance
Abstract
Insulating materials with heat dissipation are urgently required for modern electronic devices and systems. In this study, 4,4-methylene diphenyl diisocyanate was used as the coupling agent, and nano-diamond (ND) particles were grafted onto the surface of carbon fibers (CFs) to prepare CF-ND/silicone rubber (SR) composites. The ND acted as a “bridge” among CFs, which can reduce the interface thermal resistance between CFs because the dot-like ND can increase the interfacial area of CFs, making it easier to form heat-conducting networks between SR. When the content of CF-ND (1:6) was 20%, the thermal conductivity of the SR composite was 0.305 W/(m·K), 69% higher than that of pure SR. The ND between CFs can improve the dynamic mechanical properties by acting as a crack pinhole. In addition, the CF-ND/SR composites also exhibited excellent thermal stability. This work has enormous potential for advanced electronic devices.
Funding source: Scientific Research Project of Introducing Talents of Guizhou University
Award Identifier / Grant number: [2020] 53
Funding source: the Science and Technology Department of Guizhou Province
Award Identifier / Grant number: Grant No. Platform &Talents [2019] 2030
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: This work was supported by Scientific Research Project of Introducing Talents of Guizhou University ([2020] 53) and financially supported by the Science and Technology Department of Guizhou Province (grant no. Platform & Talents [2019] 2030).
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Conflict of interest statement: The authors declare that they have no conflicts of interest regarding this article.
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Articles in the same Issue
- Frontmatter
- Material Properties
- Development and characterization of eco-friendly biopolymer gellan gum based electrolyte for electrochemical application
- Structural transitions and rheological properties of poly-d-lysine hydrobromide: effect of pH, salt, temperature, and shear rate
- Carbon dioxide adsorption onto modified polyvinyl chloride with ionic liquid
- Synergistic effect of organic-Zn(H2PO2)2 and lithium containing polyhedral oligomeric phenyl silse-squioxane on flame-retardant, thermal and mechanical properties of poly(ethylene terephthalate)
- Preparation and Assembly
- Network structural hardening of polypropylene matrix using hybrid of 0D, 1D and 2D carbon-ceramic nanoparticles with enhanced mechanical and thermomechanical properties
- An environment friendly hemp fiber modified with phytic acid for enhancing fire safety of automobile parts
- Flexible silicone rubber/carbon fiber/nano-diamond composites with enhanced thermal conductivity via reducing the interface thermal resistance
- In situ synthesis of Ag NPs in the galactomannan based biodegradable composite for the development of active packaging films
- Engineering and Processing
- Multi-objective optimization of injection molded parts with insert based on IFOA-GRNN-NSGA-II