Startseite Photocatalytic paraquat degradation over TiO2 modified by hydrothermal technique in alkaline solution
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Photocatalytic paraquat degradation over TiO2 modified by hydrothermal technique in alkaline solution

  • Pallavi Nagaraju , Rattabal Khunphonoi , Shivaraju Harikaranahalli Puttaiah , Totsaporn Suwannaruang , Chatkamol Kaewbuddee und Kitirote Wantala EMAIL logo
Veröffentlicht/Copyright: 3. Juni 2017
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Journal of Advanced Oxidation Technologies
Aus der Zeitschrift Journal of Advanced Oxidation Technologies Band 20 Heft 2

Abstract

In the present research, titanium nanotubes were synthesized via the soft hydrothermal method. A study on the effect of the synthesizing parameters such as aging temperature and time of the hydrothermal process on the photocatalytic paraquat degradation was explored. Central Composite Design (CCD) was used to determine the influence of the preparation parameter on the optimal condition, main and interaction effects on crystalline size, percent paraquat removal by adsorption and photocatalytic degradation as responses. The XRD pattern of the synthesized nanomaterial reported the anatase phase of titania nanotubes. SEM image of the prepared nanomaterial clearly indicated the agglomerated with tubular structure. Band gap energy of the nanotubes was found lower than that of the pure anatase TiO2. Paraquat removal by adsorption is more effective than by photocatalytic degradation. The error of the model remains insignificant for all the three responses.

Keywords: advanced oxidation process; herbicide; surface response methodology; aging temperature; aging time

Acknowledgment

This research was partially supported by JSS University Mysore. This research work was carried out in the Chemical Kinetics and Applied Catalysis Laboratory (CKCL), Faculty of Engineering, Khon Kaen University (KKU), Thailand. We thank our colleagues from KKU Thailand who provided insight and expertise that greatly assisted the research.

References

[1] Gawarammana IB, Buckley NA. Br Clin J Pharmacol. 2011;72:745–757.10.1111/j.1365-2125.2011.04026.xSuche in Google Scholar

[2] Tanturatna P, Wirojanagud W, Neramittagapong S, Wantala K, Grisdanurak N. Indian J Chem Techn. 2011;18:363–371.Suche in Google Scholar

[3] Garcia-Segura S, Dosta S, Guilemany JM, Brillas E. Appl Catal B Environ. 2013;132–133:142–150.10.1016/j.apcatb.2012.11.037Suche in Google Scholar

[4] Oliveira C, Gruskevica K, Juhna T, Tihomirova K, Alves A, Madeira LM. Drink Water Eng Sci. 2014;7:11–21.10.5194/dwes-7-11-2014Suche in Google Scholar

[5] Khunphonoi R, Grisdanurak N. Chem Eng J. 2016;296:420–427.10.1016/j.cej.2016.03.117Suche in Google Scholar

[6] Shivaraju HP, Byrappa K, Vijay Kumar TMS, Ranganathaiah C. Bull Catal Soc India. 2010;9:37–50.Suche in Google Scholar

[7] Hashimoto K, Irie H, Fujishima A. J Appl Phys. 2005;44:8269–8285.10.1143/JJAP.44.8269Suche in Google Scholar

[8] Byrappa K, Subramani AK, Ananda S, Lokanatha Rai KM, Ranganathaiah C, Yoshimura M. B Mater Sci. 2007;30:37–41.10.1007/s12034-007-0007-8Suche in Google Scholar

[9] Pan H, Wang XD, Xiao SS, Yu LG, Zhang ZJ. Indian J Eng Mater Sci. 2013;20:561–567.Suche in Google Scholar

[10] Kong H, Song J, Jang J. Environ Sci Technol. 2010;44:5672–5676.10.1021/es1010779Suche in Google Scholar

[11] Pavasupree S, Jitputti J, Ngamsinlapasathian S, Yoshikawa S. Mater Res Bull. 2008;43:149–157.10.1016/j.materresbull.2007.02.028Suche in Google Scholar

[12] Muggli DS, Ding L. Appl Catal B–Environ. 2001;32:181–194.10.1016/S0926-3373(01)00137-0Suche in Google Scholar

[13] Suwannnaruang T, Rivera KKP, Neramittagapong A, Wantala K. Surf Coat Tech. 2015;271:192–200.10.1016/j.surfcoat.2014.12.041Suche in Google Scholar

[14] Malekshahi Byranvanda M, NematiKharat A, Fatholahi L, Malekshahi Beiranvand Z. J Nanostruct. 2013;3:1–9.Suche in Google Scholar

[15] Chen X, Mao SS. Chem Rev. 2007;107:2891–2959.10.1021/cr0500535Suche in Google Scholar PubMed

[16] Eustis S, El–Sayed MA. Chem Soc Rev. 2006;35:209–217.10.1039/B514191ESuche in Google Scholar

[17] Bazargan MH, Malekshahi Byranvand M, NematiKharat K. Int J Mater Res. 2012;103:347–351.10.3139/146.110644Suche in Google Scholar

[18] Wahi RK, Liu Y, Falkner JC, Colvin VL. J Colloid Int Sci. 2006;302:530–536.10.1016/j.jcis.2006.07.003Suche in Google Scholar PubMed

[19] Andersson M, Oesterlund L, Ljungstroem S, Palmqvist A. J Phys Chem B. 2002;106:10674–10681.10.1021/jp025715ySuche in Google Scholar

[20] Ryu WH, Park CJ, Kwon HS. J Nanosci Nanotecho. 2008;8:1–4.10.1166/jnn.2008.N03Suche in Google Scholar PubMed

[21] Shinde PS, Bhosale CH. J Anal Appl Pyrol. 2008;82:83–88.10.1016/j.jaap.2008.01.004Suche in Google Scholar

[22] Tan W, Chen J, Zhou X, Zhang J, Lin Y, Li X, et al. J Solid State Electr. 2009;13:651–656.10.1007/s10008-008-0605-4Suche in Google Scholar

[23] Arami H, Mazloumi M, Khalifehzadeh R, Sadrnezhaad SK. Mater Lett. 2007;61:4559–4561.10.1016/j.matlet.2007.02.051Suche in Google Scholar

[24] Corradi AB, Bondioli F, Focher B. J Am Ceram Soc. 2005;88:2639–2641.10.1111/j.1551-2916.2005.00474.xSuche in Google Scholar

[25] Yuan ZY, Su BL. Colloid Surface A. 2004;241:173–183.10.1016/j.colsurfa.2004.04.030Suche in Google Scholar

[26] Zhou Y, Huang Y, Li D, He W. Mater Res Bull. 2013;48:2420–2425.10.1016/j.materresbull.2013.02.051Suche in Google Scholar

[27] Wanga D, Yu B, Zhou F, Wang C, Liua W. Mater Chem Phys. 2009;113:602–606.10.1016/j.matchemphys.2008.08.011Suche in Google Scholar

[28] Rivera KKP, De Luna MDG, Suwannaruang T, Wantala K. Desalin Water Treat. 2016;57:22017–22028.10.1080/19443994.2015.1125797Suche in Google Scholar

[29] Suwannaruang T, Wantala K. Appl Surf Sci. 2016;380:257–267.10.1016/j.apsusc.2016.01.117Suche in Google Scholar

[30] Li W, Fu T, Xie F, Yu SF, He S. Mater Lett. 2007;61:730–735.10.1016/j.matlet.2006.05.053Suche in Google Scholar

[31] Wong CL, Tan YN, Mohamed AR. J Environ Manage. 2011;92:1669–1680.10.1016/j.jenvman.2011.03.006Suche in Google Scholar PubMed

[32] Ou HH, Lo SL. Sep Purif Tech. 2007;58:179–191.10.1016/j.seppur.2007.07.017Suche in Google Scholar

[33] Fen LB, Han TK, Nee NM, Ang BC, Johan MR. Appl Surf Sci. 2011;258:431–435.10.1016/j.apsusc.2011.08.115Suche in Google Scholar

[34] Zahedi F, Behpour M, Ghoreishi SM, Khalilian H. Sol Energy. 2015;120:287–295.10.1016/j.solener.2015.07.010Suche in Google Scholar

[35] Wantala K, Laokiat L, Khemthong P, Grisdanurak N, Fukaya K. J Taiwan Inst Chem E. 2010;41:612–616.10.1016/j.jtice.2010.01.008Suche in Google Scholar

[36] Inagaki M, Kondo N, Nonaka R, Ito E, Toyoda M, Sogabe K, et al. J Hazard Mater. 2009;161:1514–1521.10.1016/j.jhazmat.2008.05.003Suche in Google Scholar PubMed

[37] Wang LS, Xiao MW, Huang XJ, Wu YD. J Hazard Mater. 2009;161:49–54.10.1016/j.jhazmat.2008.03.080Suche in Google Scholar PubMed

[38] Chen HW, Ku Y, Kuo YL. Water Res. 2007;41:2069–2078.10.1016/j.watres.2007.02.021Suche in Google Scholar PubMed

[39] Vetrivel V, Rajendran K, Kalaiselvi V. Int J Chem Tech Res. 2015;7:1090–1097.Suche in Google Scholar

[40] Peng T, Zhao D, Dhai K, Shi W, Hirao K. J Phys Chem B. 2005;109:4947–4952.10.1021/jp044771rSuche in Google Scholar PubMed

[41] Lee JC, Kim MS, Kim CK, Chung CH, Cho SM, Han GY, et al. Korean J Chem Eng. 2003;20:862–868.10.1007/BF02697289Suche in Google Scholar

[42] Md. Razali H, Ruslimie CA, Khairul WM. J Sustain Sci Manage. 2013;8:244–253.Suche in Google Scholar

[43] Ali R, Hassan SH. Malaysian J Anal Sci. 2008;12:77–87.Suche in Google Scholar

[44] De Luna MDG, Lin JC-T, Gotostos MJN, Lu M-C. Sustain Environ Res. 2016;26:161–167.10.1016/j.serj.2016.02.001Suche in Google Scholar

[45] Dosta S, Robotti M, Garcia-Segura S, Brillas E, Cano IG, Guilemany JM. Appl Catal B Environ. 2016;189:151–159.10.1016/j.apcatb.2016.02.048Suche in Google Scholar

Published Online: 2017-6-3

© 2017 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

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  4. Excitation Kinetics of Oxygen O(1D) State in Low-Pressure Oxygen Plasma and the Effect of Electron Energy Distribution Function
  6. Using amino-functionalized Fe3O4-WO3 nanoparticles for diazinon removal from synthetic and real water samples in presence of UV irradiation
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  10. Electrochemical Advanced Oxidation Processes (EAOP) to degrade per- and polyfluoroalkyl substances (PFASs)
  12. Effect of feedstock impurities on activity and selectivity of V-Mo-Nb-Te-Ox catalyst in ethane oxidative dehydrogenation
  14. Photocatalytic Degradation of Azo Dyes Over Semiconductors Supported on Polyethylene Terephthalate and Polystyrene Substrates
  16. Effects of calcination temperature on sol-gel synthesis of porous La2Ti2O7 photocatalyst on degradation of Reactive Brilliant Red X3B
  18. ClO2-oxidation-based demulsification of oil-water transition layer in oilfields: An experimental study
  20. Semi-permanent hair dyes degradation at W/WO3 photoanode under controlled current density assisted by visible light
  22. Degradation of PVA (polyvinyl alcohol) in wastewater by advanced oxidation processes
  24. Degradation of imidacloprid insecticide in a binary mixture with propylene glycol by conventional fenton process
  26. Gemini surfactant-assisted synthesis of BiOBr with superior visible light-induced photocatalytic activity towards RhB degradation
  28. Photocatalytic paraquat degradation over TiO2 modified by hydrothermal technique in alkaline solution
  30. Enhancement of Profenofos Remediation Using Stimulated Bioaugmentation Technique
  32. Mechanistic insight on the sonolytic degradation of phenol at interface and bulk using additives
  34. Biosolubilization of low-grade rock phosphate by mixed thermophilic iron-oxidizing bacteria
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https://doi.org/10.1515/jaots-2017-0004
Schlagwörter für diesen Artikel
advanced oxidation process; herbicide; surface response methodology; aging temperature; aging time

Artikel in diesem Heft

  2. Editorial
  4. Excitation Kinetics of Oxygen O(1D) State in Low-Pressure Oxygen Plasma and the Effect of Electron Energy Distribution Function
  6. Using amino-functionalized Fe3O4-WO3 nanoparticles for diazinon removal from synthetic and real water samples in presence of UV irradiation
  8. Treatment of high salinity wastewater using CWPO process for reuse
  10. Electrochemical Advanced Oxidation Processes (EAOP) to degrade per- and polyfluoroalkyl substances (PFASs)
  12. Effect of feedstock impurities on activity and selectivity of V-Mo-Nb-Te-Ox catalyst in ethane oxidative dehydrogenation
  14. Photocatalytic Degradation of Azo Dyes Over Semiconductors Supported on Polyethylene Terephthalate and Polystyrene Substrates
  16. Effects of calcination temperature on sol-gel synthesis of porous La2Ti2O7 photocatalyst on degradation of Reactive Brilliant Red X3B
  18. ClO2-oxidation-based demulsification of oil-water transition layer in oilfields: An experimental study
  20. Semi-permanent hair dyes degradation at W/WO3 photoanode under controlled current density assisted by visible light
  22. Degradation of PVA (polyvinyl alcohol) in wastewater by advanced oxidation processes
  24. Degradation of imidacloprid insecticide in a binary mixture with propylene glycol by conventional fenton process
  26. Gemini surfactant-assisted synthesis of BiOBr with superior visible light-induced photocatalytic activity towards RhB degradation
  28. Photocatalytic paraquat degradation over TiO2 modified by hydrothermal technique in alkaline solution
  30. Enhancement of Profenofos Remediation Using Stimulated Bioaugmentation Technique
  32. Mechanistic insight on the sonolytic degradation of phenol at interface and bulk using additives
  34. Biosolubilization of low-grade rock phosphate by mixed thermophilic iron-oxidizing bacteria
  36. Degradation of methyl orange using dielectric barrier discharge water falling film reactor
  38. Rapid prediction of hydrogen peroxide concentration eletrogenerated with boron doped diamond electrodes
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