Band 236, Heft 3

To date, the noble metal-based nanoparticles have been used in every field of life. The Au and Ag nanoparticles (NPs) have been fabricated employing different techniques to tune the properties. In this study, the methodologies developed and adopted for the fabrication of Au and Ag have been discussed, which include physical, chemical and biological routes. The Au and Ag characteristics (morphology, size, shape) along with advantages and disadvantages are discussed. The Au and Ag NPs catalytic and biomedical applications are discussed. For the Ag and Au NPs characterization, SEM (scanning electron microscope), TEM (transmission electron microscope), FTIR (Fourier transform infra-red spectroscopy), XRD (X-rays diffraction) and DLS (dynamic light scattering) techniques are employed. The properties of Au and Ag NPs found dependent to synthesis approach, i.e., the size, shape and morphologies, which showed a promising Catalytic, drug delivery and antimicrobial agent applications. The review is a comprehensive study for the comparison of Au and Ag NPs synthesis, properties and applications in different fields.

Electroplated protective thin film is highly promising materials for advanced applications such as high corrosion resistance and energy conversion and storage. This work is to investigate the effect of Co content and TiO 2 on the corrosion resistance of Ni–xCo–yTiO 2 nanocomposites in alkaline media. The nanocrystalline Ni–xCo–yTiO 2 composites were electroplated using the sulfate-gluconate bath containing the suspended TiO 2 nanograins under ultrasound waves and mechanical stirring. The microstructure and corrosion behavior of the electroplated Ni–xCo–yTiO 2 nanocomposites have been investigated via X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The XRD pattern of the electroplated Ni–Co matrices with 1–75% of cobalt arranged in face-centered cubic (FCC) system, while the electroplated Ni–Co matrices of further Co% more than 76% converted to hexagonal closed-package (HCP) crystal system. The surface of the Ni–xCo–yTiO 2 nanocomposites after immersion in 1.0 M KOH electrolytes was investigated via SEM, atomic force microscopy and EDX. The results displayed that the rate of corrosion of the different composites decreased by combining Ni, Co and the inclusion of TiO 2 . The improved corrosion resistance of Ni–47Co–3.77TiO 2 composites is due to the formation of Ni/Co oxy/hydroxide layer and rebelling effect of OH − by TiO 2 sites, which reduces the attacking effect of OH − , O 2 , and H 2 O, and notably retards the overall corrosion processes.

In the present study, the conductometric and dye-solubilization techniques have been utilized to investigate the interaction between an anionic dye (acid yellow 23 [AY]) and a cationic surfactant (cetyltrimethylammonium bromide [CTAB]) in presence of organic (ethanol)/inorganic (NaCl) additives. From the conductometric method, two critical micelle concentrations ( cmc ) were found for AY + CTAB mixture in an aqueous system and the cmc values were found to undergo a change with the variation of AY concentrations. The cmc values of AY + CTAB systems were observed higher in the alcoholic medium, while the same was found to be lower in the NaCl solutions. The change in cmc of AY + CTAB systems shows an U-like curve with an increase of temperature. The negative free energy of micellization ( Δ G m o ${\Delta}{G}_{m}^{o}$ ) for the AY + CTAB systems has indicated a spontaneous micelle formation in all of the cases studied. The enthalpy ( Δ H m o ${\Delta}{H}_{m}^{o}$ ), as well as the entropy of micellization ( Δ S m o ${\Delta}{S}_{m}^{o}$ ) for the AY + CTAB systems, were assessed and discussed with proper reasoning. Additionally, the enthalpy-entropy compensation parameters were also investigated and illustrated. The solubility of AY and C D was observed to rise linearly with an increase in the concentration of CTAB/NaCl solution. The solubilization capacity ( χ ) of AY, the molar partition coefficient ( K M ) amongst the micellar and the aqueous phase, and free energy of solubilization ( Δ G S o ${\Delta}{G}_{S}^{o}$ ) were evaluated and discussed in detail. The former parameters undergo an increase with an increase of NaCl concentrations.

In the present work, halloysite nano-clay (HNTs) based hydrogel was fabricated and their efficiency for the removal of methylene blue dye was studied. The hydrogel films were prepared with varying amount of halloysite nano-clay via facile solution casting method. Effect of halloysite clay on adsorption performance of composite was investigated. The hydrophobic thermoplastic synthetic polymer, polylactic acid (PLA) was blended with hydrophilic polymer polyvinyl alcohol (PVA) and HNTs to synthesize hydrogels. Swelling behavior and antimicrobial efficiency was also evaluated. The halloysite incorporating films showed excellent antibacterial activity. Swelling capacity of hydrogel with increased halloysite content was reduced due to increased crosslinking among polymer chains. Halloysite incorporated hydrogel exhibited higher adsorption ability as compared to film comprising of only PVA and PLA and dye removal followed pseudo first order kinetics. Film with 0.03 g HNTs rapidly attained adsorption-desorption equilibria and removed the dye completely within 30 min. Results confirmed that synthesized film could be potentially used for the removal of cationic dye and fabricated hydrogel film have promising potential for wastewater treatment since a higher adsorption capacity was observed for halloysite nano-clay incorporated hydrogel.

Densities, ultrasonic velocity, conductance and viscosity of some alkaline earth metal chlorides such as magnesium chloride (MgCl 2 ) and calcium chloride (CaCl 2 ) were calculated in the concentration range (0.01–0.12 mol kg −1 ) in 0.01 mol kg −1 aqueous solution of citric acid (CA + H 2 O) at four varying temperatures T 1  = 303.15 K, T 2  = 308.15 K, T 3  = 313.15 K and T 4  = 318.15 K. The parameters like apparent molar volume ( ϕ v ), limiting apparent molar volume ( ϕ v o ${\phi }_{v}^{o}$ ) and transfer volume (Δ tr ϕ v o ${\phi }_{v}^{o}$ ) were calculated from density data. Viscosity data have been employed to calculate Falkenhagen coefficient (A), Jone–Dole’s coefficient (B), relative viscosity ( η r ), and relaxation time ( τ ) whereas limiting molar conductance ( Λ m o ${{\Lambda}}_{m}^{o}$ ) has been evaluated from conductance studies. Using these parameters, various type of interactions occurred in the molecules have been discussed. Values of Hepler’s constant ( d 2 ϕ v o ${\phi }_{v}^{o}$ / dT 2 ) p , ( dB / dT ) and d ( Λ m o ${{\Lambda}}_{m}^{o}$ η o )/ dT suggests that both MgCl 2 and CaCl 2 behave as structure breaker in (CA + H 2 O) system. The positive value of transfer volume exclusively tells about solute–solvent interactions which further indicate that both metal chlorides distort the structure of water and act as structure breaker. These studies are helpful in understanding the nature of interactions occurs in biological systems as CA and metal salts are essential for normal functioning of body.

Herein, the aggregation manner of the mixture of polyvinyl alcohol (PVA) and tetradecyltrimethylammonium bromide (TTAB) was performed in polyols (glucose, maltose and galactose) media over 300.55–320.55 K temperatures range with 5 K interval through conductivity measurement method. The micelle formation of TTAB + PVA mixture was identified by the assessment of critical micelle concentration ( CMC ) from the plots of specific conductivity ( κ ) versus TTAB concentration. The degree of micelle ionization ( α ), the extent of bound counter ions ( β ) as well as thermodynamic properties ( Δ G m 0 ${\Delta}{G}_{m}^{0}$ , Δ H m 0 ${\Delta}{H}_{m}^{0}$ and Δ S m 0 ${\Delta}{S}_{m}^{0}$ ) of TTAB + PVA systems have been estimated. The CMC values reveal that the micelle formation of TTAB + PVA mixture experience an enhancement in the manifestation of polyols. The values of free energy of micellization ( Δ G m 0 ${\Delta}{G}_{m}^{0}$ ) are negative for the TTAB + PVA system in aqueous polyols media, suggesting a spontaneous aggregation phenomenon. The Δ H m 0 ${\Delta}{H}_{m}^{0}$ and Δ S m 0 ${\Delta}{S}_{m}^{0}$ values of TTAB + PVA systems direct that the PVA molecule interacts with TTAB through the exothermic, ion-dipole, and hydrophobic interactions. The thermodynamic properties of transfer were also determined for the move of TTAB + PVA mixture from H 2 O to water + polyols mixed solvents. The values of compensation temperature ( T c ) and intrinsic enthalpy gain ( Δ H m 0 , ∗ ${\Delta}{H}_{m}^{0,\ast }$ ) were evaluated and discussed for the studied system.

To understand the expected mode of action, the physicochemical study on the solution properties of medicinal compounds and their interaction with deoxyribonucleic acid (DNA), under varying experimental conditions, is of prime importance. The present research work illustrates the physicochemical study and interaction of certain medicinal compounds such as; Levofloxacin, Ciprofloxacin, and Ibuprofen with DNA. Density, viscosity and surface tension measurements have been performed in order to determine, in a systematic manner, the physicochemical, volumetric and thermodynamic properties of these compounds; and most of these parameters have shown different behavior with varying concentration of solution, temperature of the medium and chemical nature/structure of the compound. In addition, these drugs showed a spontaneous surface-active and association behavior in aqueous solutions. The flow behavior, surface properties, volumetric behavior and solute–solvent interaction of these drugs were prominently influenced by experimental variables and addition of DNA to their solutions. UV–Visible spectroscopy was also used to examine the interaction of these drugs with DNA in aqueous media in detail. Calculated values of binding constants (K b ) for all complexes of drug-DNA are positive, indicating a fruitful binding process. It is seen that a smaller K b value reflects weaker binding of the drug with DNA and vise versa. Due to the difference in the chemical structure of drugs the values of binding constant are different for various drug-DNA complexes and follow the order K b (Levofloxacin-DNA) > K b (Ciprofloxacin-DNA) > K b (Ibuprofen-DNA). On the basis of spectral changes and K b it can be said that the binding of all these drugs with DNA may be of physicochemical nature and the dominating binding force be of hydrogen bonding between oxygen of drugs and hydrogen of DNA units and the drug having more oxygen atoms showed stronger binding ability. The data further suggest a limited possibility of chemical type attachment of these drugs with DNA.