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Molecular interaction investigation of some alkaline earth metal salts in aqueous citric acid at various temperatures by physiochemical studies

  • Manish Kumar ORCID logo EMAIL logo , Shashi Kant and Deepika Kaushal
Published/Copyright: September 30, 2021
Zeitschrift für Physikalische Chemie
From the journal Zeitschrift für Physikalische Chemie Volume 236 Issue 3

Abstract

Densities, ultrasonic velocity, conductance and viscosity of some alkaline earth metal chlorides such as magnesium chloride (MgCl2) and calcium chloride (CaCl2) were calculated in the concentration range (0.01–0.12 mol kg−1) in 0.01 mol kg−1 aqueous solution of citric acid (CA + H2O) at four varying temperatures T 1 = 303.15 K, T 2 = 308.15 K, T 3 = 313.15 K and T 4 = 318.15 K. The parameters like apparent molar volume (ϕ v ), limiting apparent molar volume ( ϕ v o ) and transfer volume (Δtr ϕ v o ) were calculated from density data. Viscosity data have been employed to calculate Falkenhagen coefficient (A), Jone–Dole’s coefficient (B), relative viscosity (η r ), and relaxation time (τ) whereas limiting molar conductance ( Λ m o ) has been evaluated from conductance studies. Using these parameters, various type of interactions occurred in the molecules have been discussed. Values of Hepler’s constant (d 2 ϕ v o /dT 2) p , (dB/dT) and d( Λ m o η o )/dT suggests that both MgCl2 and CaCl2 behave as structure breaker in (CA + H2O) system. The positive value of transfer volume exclusively tells about solute–solvent interactions which further indicate that both metal chlorides distort the structure of water and act as structure breaker. These studies are helpful in understanding the nature of interactions occurs in biological systems as CA and metal salts are essential for normal functioning of body.

Keywords: apparent molar volume; citric acid; molecular interactions; transfer volume
Corresponding author: Manish Kumar, Department of Chemistry & Chemical Sciences, Central University of Himachal Pradesh, Shahpur, Kangra, HP-176206, India; and Department of Chemistry, Himachal Pradesh University, Shimla-171005, India, E-mail:

Funding source: CSIR

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: M.K is thankful to the funding agency (CSIR, New Delhi) for financial assistance.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2020-10-14
Accepted: 2021-09-09
Published Online: 2021-09-30
Published in Print: 2022-03-28

© 2021 Walter de Gruyter GmbH, Berlin/Boston

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https://doi.org/10.1515/zpch-2020-1766
Keywords for this article
apparent molar volume; citric acid; molecular interactions; transfer volume

Articles in the same Issue

  1. Frontmatter
  2. Review Article
  3. State-of-art of silver and gold nanoparticles synthesis routes, characterization and applications: a review
  4. Original Papers
  5. Microstructural characterization and corrosion behaviour of ultrasound-assisted synthesis of Ni–xCo–yTiO2 nanocomposites in alkaline environments
  6. Interaction of cationic surfactant with acid yellow dye in absence/presence of organic and inorganic additives: conductivity and dye solubilization methods
  7. Kinetics of methylene blue dye adsorptive removal using halloysite nanocomposite hydrogels
  8. Molecular interaction investigation of some alkaline earth metal salts in aqueous citric acid at various temperatures by physiochemical studies
  9. Impacts of polyols and temperature on the micellization, interaction and thermodynamics behavior of the mixture of tetradecyltrimethylammonium bromide and polyvinyl alcohol
  10. The physicochemical and DNA binding studies of some medicinal compounds in solutions
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