Startseite Naturwissenschaften Microstructural characterization and corrosion behaviour of ultrasound-assisted synthesis of Ni–xCo–yTiO2 nanocomposites in alkaline environments
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Microstructural characterization and corrosion behaviour of ultrasound-assisted synthesis of Ni–xCo–yTiO2 nanocomposites in alkaline environments

  • Nady ElSayed , Mohamed M. El-Rabiei und Mosaad Negem EMAIL logo
Veröffentlicht/Copyright: 27. Mai 2021
Zeitschrift für Physikalische Chemie
Aus der Zeitschrift Zeitschrift für Physikalische Chemie Band 236 Heft 3

Abstract

Electroplated protective thin film is highly promising materials for advanced applications such as high corrosion resistance and energy conversion and storage. This work is to investigate the effect of Co content and TiO2 on the corrosion resistance of Ni–xCo–yTiO2 nanocomposites in alkaline media. The nanocrystalline Ni–xCo–yTiO2 composites were electroplated using the sulfate-gluconate bath containing the suspended TiO2 nanograins under ultrasound waves and mechanical stirring. The microstructure and corrosion behavior of the electroplated Ni–xCo–yTiO2 nanocomposites have been investigated via X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The XRD pattern of the electroplated Ni–Co matrices with 1–75% of cobalt arranged in face-centered cubic (FCC) system, while the electroplated Ni–Co matrices of further Co% more than 76% converted to hexagonal closed-package (HCP) crystal system. The surface of the Ni–xCo–yTiO2 nanocomposites after immersion in 1.0 M KOH electrolytes was investigated via SEM, atomic force microscopy and EDX. The results displayed that the rate of corrosion of the different composites decreased by combining Ni, Co and the inclusion of TiO2. The improved corrosion resistance of Ni–47Co–3.77TiO2 composites is due to the formation of Ni/Co oxy/hydroxide layer and rebelling effect of OH− by TiO2 sites, which reduces the attacking effect of OH−, O2, and H2O, and notably retards the overall corrosion processes.

Keywords: co content; electrochemical technique; microstructure; nanocomposite; Ni–Co–TiO2 coating
Corresponding author: Mosaad Negem, Chemistry Department, Faculty of Science, Fayoum University, Faiyum, Egypt, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2020-08-10
Accepted: 2021-10-22
Published Online: 2021-05-27
Published in Print: 2022-03-28

© 2021 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Review Article
  3. State-of-art of silver and gold nanoparticles synthesis routes, characterization and applications: a review
  4. Original Papers
  5. Microstructural characterization and corrosion behaviour of ultrasound-assisted synthesis of Ni–xCo–yTiO2 nanocomposites in alkaline environments
  6. Interaction of cationic surfactant with acid yellow dye in absence/presence of organic and inorganic additives: conductivity and dye solubilization methods
  7. Kinetics of methylene blue dye adsorptive removal using halloysite nanocomposite hydrogels
  8. Molecular interaction investigation of some alkaline earth metal salts in aqueous citric acid at various temperatures by physiochemical studies
  9. Impacts of polyols and temperature on the micellization, interaction and thermodynamics behavior of the mixture of tetradecyltrimethylammonium bromide and polyvinyl alcohol
  10. The physicochemical and DNA binding studies of some medicinal compounds in solutions
https://doi.org/10.1515/zpch-2020-1733
Schlagwörter für diesen Artikel
co content; electrochemical technique; microstructure; nanocomposite; Ni–Co–TiO2 coating

Artikel in diesem Heft

  1. Frontmatter
  2. Review Article
  3. State-of-art of silver and gold nanoparticles synthesis routes, characterization and applications: a review
  4. Original Papers
  5. Microstructural characterization and corrosion behaviour of ultrasound-assisted synthesis of Ni–xCo–yTiO2 nanocomposites in alkaline environments
  6. Interaction of cationic surfactant with acid yellow dye in absence/presence of organic and inorganic additives: conductivity and dye solubilization methods
  7. Kinetics of methylene blue dye adsorptive removal using halloysite nanocomposite hydrogels
  8. Molecular interaction investigation of some alkaline earth metal salts in aqueous citric acid at various temperatures by physiochemical studies
  9. Impacts of polyols and temperature on the micellization, interaction and thermodynamics behavior of the mixture of tetradecyltrimethylammonium bromide and polyvinyl alcohol
  10. The physicochemical and DNA binding studies of some medicinal compounds in solutions
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