Band 41, Heft 4

In the prevailing apocalyptic times of coronavirus disease (COVID-19), the whole scientific community is busy in designing anticovid drug or vaccine. Under such a fascination, Schiff bases or azomethine compounds are continuously interrogated for antimicrobial properties. These compounds represent interesting molecular scaffolds of huge medicinal and industrial relevance. In order to update the current literature support of such facts this article introduces the synthetic chemistry, mechanism of formation of a Schiff base, followed by biological efficacy and finally a suitable discussion on the mechanism of respective bioactivity. In most of the studies revealing the biological evaluation of azomethine functionalized frameworks, fascinated results have been recorded in case of azomethine-metal complexes as compared with the free ligands. Also, the CH=N or C=N form of organic ligands have indicated marvellous results. Therefore, in connection with the biological relevance and microbicidal implications of such metallic compounds, this works reviews the current update of microorganism fighting efficacy of azomethine metal complexes along with the introduction of some metallodrugs as excellent candidates having COVID-19 defending potentiality.

Heterogeneous photocatalysts was a promising material for removing organic pollutants. Titanium dioxide (TiO 2 ) was a suitable photocatalyst for its cost efficiency and high stability to reduce various pollutants. Enhancing TiO 2 photocatalyst performance by doping with changed metals or non-metal ions and organic compounds have been reviewed. These methods could enhance photoelectrochemical activity via: (i) by a donor of electrons via electron-donor agents that would produce particular defects in TiO 2 structure and capture transporters of charge; (ii) by reducing recombination rate of the charge transporters and increasing degradation of pollutants. This study investigates the modification approaches of TiO 2 that comprise methods for overcoming the essential TiO 2 restrictions and enhancing the photocatalytic degradation of organic pollutants. Consequently, it emphasized on the current progress of modified-TiO 2 used for different pollutants in ambient conditions. Amendment techniques, such as inorganic and organic parts as doping, are studied. The reported experimental results obtained with the photocatalytic oxidation process for degrading organic pollutants were also collected and assessed.

The current advancements in nanotechnology suggest a sustainable development in the green synthesis of bimetallic nanoparticles (BMNPs) through green approaches. Though challenging, nano phyto technology has versatile methods to achieve desired unique properties like optic, electronic, magnetic, therapeutic, and catalytic efficiencies. Bio-inspired, facile synthesis of bifunctional BMNPs is possible using abundant, readily available natural plant sources, bio-mass wastes and microorganisms. Synergistic effects of two different metals on mixing, bring new insight for the vast applications, which is not achievable in using monometallic NPs. By adopting bio-inspired greener approaches for synthesizing NPs, the risk of environmental toxicity caused by conventional physicochemical methods become negligible. This article hopes to provide the significance of cost-effective, one-step, eco-friendly and facile synthesis of noble/transition bimetallic NPs. This review article endows an overview of the bio-mediated synthesis of bimetallic NPs, classifications of BMNPs, current characterization techniques, possible mechanistic aspects for reducing metal ions, and the stability of formed NPs and bio-medical/industrial applications of fabricated NPs. The review also highlights the prospective future direction to improve reliability, reproducibility of biosynthesis methods, its actual mechanism in research works and extensive application of biogenic bimetallic NPs.