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Environmental pollution produced due to direct and untreated release of toxic organic pollutants such as dyes from the textile industries is not only effect the human life but also contaminates the ecosystem through different transferal modes. Green nanomaterials synthesized by using biological reducing agents offer sustainable, economically viable, facile, rapid and eco-friendly approach with photocatalytic degradation efficiencies >90% for organic dyes over the other traditional technologies. Current review has for the first time comprehensively abridged the suitability of green nanoparticles over chemogenic nanoparticles, the remediative role of these biogenic nanoparticles with major emphasis on the recent progressions in the photocatalysis of different toxic dyes and pollutants. Unlike physicochemically processed nanoparticles, biogenic nanoparticles has profound contribution to the sustainable development goals due to their cleaner and economical synthesis in addition to their detoxifying role. Meticulous review of the publications are strongly suggestive of the adoptability of biogenic nanoparticles at an implementation scale for their auspicious remediative role in addition to facile fabrication, natural reducing agents based synthetic mode, toxicity free and sustainable nature. However, the studies are also indicative of the need for utilization of biogenic synthesis at practical scale to derive maximum sustainability and ecological benefits.

Technetium radionuclide ( 99m Tc) has excellent extent of disintegration properties and occupies a special place in the field of nuclear medicinal chemistry and other health disciplines. Current review describes recent approaches of synthesis in detailed ways for radio-pharmaceuticals of technetium which have been developed to treat and diagnose the biotic disorders. These technetium labeled radio-pharmaceuticals have been established to apply in the field of diagnostic nuclear medicine especially for imaging of different body parts such as brain, heart, kidney, bones and so on, through single photon emission computed tomography (SPECT) that is thought to be difficult to image such organs by using common X-ray and MRI (Magnetic Resonance Imaging) techniques. This review highlights and accounts an inclusive study on the various synthetic routes of technetium labeled radio-pharmaceuticals using ligands with various donor atoms such as carbon, nitrogen, sulphur, phosphorus etc. These compounds can be utilized as next generation radio-pharmaceuticals.