Band 42, Heft 3

Polyvinylidene fluoride (PVDF)/polyethylene glycol (PEG) form-stabilized composite phase change nanofibers with various mass percentage of PEG1000 (with average molecular weight of 1000) loadings were fabricated by electrospinning technique, in which PEG was served as phase change material (PCM) and PVDF as the supporting matrix to afford a mechanically strong structure. Effect of PEG1000 content on nanofiber morphology, phase transition properties, thermal stability, thermal energy storage and release performance, and mechanical properties were studied experimentally. The results showed that the incorporation of PEG1000 improved the spinning solution viscosity and high mass fraction of PEG1000 in the nanofibers led to decreased fiber diameter and melting temperature, and higher latent heat of fusion. In addition, mechanical test revealed that the fracture elongation of the electrospun PVDF/PEG composite nanofibrous membranes were initially increased with unobvious tensile strength changes, while the value of the elongation would decrease, and the tensile strength increase as the mass ratio of PVDF/PEG lower to 1:1. Furthermore, the melting temperature and maximum latent heat for PVDF/PEG were determined from DSC measurement as 51.8 °C, and 73.3 J/g, when the mass radio of PVDF/PEG was 1:1 (w/w), which was suitable utilized for thermo-regulating textiles or in heat storage devices.

Novel bio-composite films based on Algerian earth chestnut i.e. Bunium incrassatum roots (Talghouda, TG) and cellulose derivatives (ethylcellulose; EC and cellulose acetate; AC) are prepared and tested for methylene blue (MB) adsorption from aqueous solutions. The biomaterial films are elaborated by dissolution solvent evaporation technique and are characterized by infrared spectroscopy, X-ray diffraction, SEM and optical microscopy. The pH pzc is also determined. For the adsorption tests, design of experiments based on 2 3 factorial design is built and followed. So, the effects of TG:EC:AC ratio, pH and MB initial concentration are discussed on the basis of mathematical modelling using Minitab software. Mathematical relations between equilibrium adsorption percentages and capacities versus selected variables were obtained and illustrated by surface plots. The interactive effects between variables have been also identified. The results showed that the MB adsorption percentage exceeded 83% and is mostly affected by pH value. Nevertheless the adsorption capacity is affected by MB initial concentration.

In this paper, we discussed the characteristics and properties of polypropylene (PP)/magnesium oxide (MgO) composites prepared by melt compounding. In addition, we also discussed the effect of adding vapor-grown carbon fiber (VGCF) to PP/MgO composite on the properties of the composites. The thermal conductivity of PP/MgO increased with MgO content. In the region of MgO content of more than 30 vol%, the thermal conductivity of PP/MgO with MgO-10 (particle size of 10 μm) is the largest by comparison of other PP/MgO with different MgO sizes. The thermal conductivity of PP/MgO became increased by adding VGCF in PP/MgO. According to the estimation of thermal conductivity using Bruggeman’s equation, no synergistic effect was observed by adding VGCF into the PP/MgO composite. The surface resistance of PP/MgO significantly decreased by adding VGCF at a content of more than 3 vol%. At VGCF content of 1 vol%, the surface resistance of the composite became large, and the value was more than 10 9  Ω/sq. In addition, the Non-Newtonian property of PP/MgO composite melt was enhanced by the addition of VGCF into the composite.

Poly(lactic acid), PLA, is a biodegradable polymer obtained from renewable sources with similar properties when compared with petroleum-based thermoplastics but with inherent brittleness. In this work, the use of thermoplastic polyurethane (TPU) as toughening agent was evaluated. PLA/TPU blends with 25 and 50 wt% of TPU were produced in an internal mixer without the use of compatibilizers. Their thermal, rheological, and mechanical properties were analyzed and correlated with the developed morphology. Immiscible blends with dispersed droplets morphology were obtained, and it was observed an inversion between the matrix and dispersed phases with the increase of the TPU content. The presence of TPU altered the elasticity and viscosity of the blends when compared to PLA, besides acting as a nucleating agent. Huge increments in impact resistance (up to 365%) were achieved, indicating a great potential of TPU to be used as a PLA toughening agent.

Membrane separation technology is widely used in wastewater purification, but the issue of membrane fouling could not be ignored. Hydrophilic modification is an effective method to reduce membrane fouling. Therefore, in this work, a hydrophilic modified polyvinylidene fluoride (PVDF) ultrafiltration membrane was prepared by polymer/non-solvent co-induced phase separation, and the effect of coagulation bath temperature on the membrane structure and performance was systematically investigated based on the previous study. With the increased of the coagulation bath temperature, the phase separation process changed from delayed to instantaneous, and the membrane surface changed from porous to dense, while the macropore structures and sponge-like pores appeared on the cross-section. Meanwhile, the pure water flux decreased from 229.3 L/(m 2 ·h) to 2.08 L/(m 2 ·h), the protein rejection rate increased from 83.87% to 100%, and the surface water contact angle increased from 63° to 90°. Thus, excessively high coagulation bath temperature adversely affected the permeate and separation performance, as well as antifouling performance of the membrane. This study enriched the research for preparing separation membranes by polymer/non-solvent co-induced phase separation and provided a practical and theoretical reference for controlling the membrane structure and properties by changing the coagulation bath temperature.

Polymer based organic solar cells (OSCs) are of tremendous interest as suitable candidates for producing clean and renewable energy in recent years. In this study, inverted OSCs on stainless steel (SS) substrate with zinc oxide (ZnO) as the electron selective transport layer (ESTL), are investigated, occupying bulk heterojunction blend of regioregular poly(3-hexylthiophene) (P3HT) and phenyl-C61-butyric acid methyl ester (PCBM) as the active material and poly-(4,3-ethylene dioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as the hole transport layer (HTL). The device structure is SS/ZnO/P3HT:PCBM/PEDOT:PSS/Au. ZnO films are prepared by spin coating and electrodeposition techniques, followed by annealing under ambient conditions. The insertion of ZnO layer between the SS substrate and active layer has improved short-circuit current ( J sc ), open-circuit voltage ( V oc ), fill factor (FF), and power conversion efficiency (PCE) compared to those of the reference cell without ZnO layer, achieving the highest efficiency of 0.66% for the device with spin coated ZnO from sol–gel technique. This enhancement can be attributed to the effective electron extraction and the increased crystallinity of ZnO after annealing treatments at higher temperatures as further confirmed by X-ray diffraction (XRD) and scanning electron microscope (SEM) analyses.

In tissue engineering, 3D printing is an important tool that uses biocompatible materials, cells, and supporting components to fabricate complex 3D printed constructs. This review focuses on the cytocompatibility characteristics of 3D printed constructs, made from different synthetic and natural materials. From the overview of this article, inkjet and extrusion-based 3D printing are widely used methods for fabricating 3D printed scaffolds for tissue engineering. This review highlights that scaffold prepared by both inkjet and extrusion-based 3D printing techniques showed significant impact on cell adherence, proliferation, and differentiation as evidenced by in vitro and in vivo studies. 3D printed constructs with growth factors (FGF-2, TGF- β 1, or FGF-2/TGF- β 1) enhance extracellular matrix (ECM), collagen I content, and high glycosaminoglycan (GAG) content for cell growth and bone formation. Similarly, the utilization of 3D printing in other tissue engineering applications cannot be belittled. In conclusion, it would be interesting to combine different 3D printing techniques to fabricate future 3D printed constructs for several tissue engineering applications.

This study focuses on the adsorption of hazardous Cr (III) and Cu (II) ions from aqueous solution by applying modified waste polypropylene (PP) fabric as an adsorbent. Pre-irradiation technique was performed for grafting of sodium styrene sulfonate (SSS) and acrylic acid (AAc) onto the PP fabric. The monomer containing 8% SSS and 16% AAc in water was used. Graft yield at 30 kGy radiation dose was 390% when 4% NaCl was added as additive. The prepared adsorbent was characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), thermo-gravimetric analysis (TGA) and dynamic mechanical analyzer (DMA). The influences of different parameters including pH, contact time, temperature and initial metal ion concentration were also investigated. The equilibrium adsorption data were better fitted to the Langmuir isotherm model with maximum monolayer adsorption capacity 384.62 mg/g for Cr (III) and 188.68 mg/g for Cu (II) ions. The kinetic data were better explained by pseudo first-order kinetic model having good matching between the experimental and theoretical adsorption capacity. The adsorption process was spontaneous, endothermic and thermodynamically feasible. Furthermore, investigation of desorption of metal ions and reuse of the adsorbent suggesting that the adsorbent is an efficient and alternative material in the removal of Cr (III) and Cu (II) from aqueous media.