Band 37, Heft 3 -

Basicity of titanium bearing blast furnace (BF) slag is critical for its crystallization behavior. Thermodynamics calculation indicates that rutile is the main phase after crystallization (or at room temperature). It precipitates during the cooling when the basicity of the slag is lower than 0.7. With increasing basicity, perovskite appears and becomes the main phase instead which contains titanium. Crystallization temperature of perovskite is higher than that of rutile and the other phases. Namely, perovskite crystallizes firstly from the molten slag during decreasing temperature. XRD analysis shows that CaTi 21 O 38 is the main phase with a basicity of 0.6. CaMg 0.39 Al 0.87 Ti 0.48 Si 1.26 O 6 , CaTiSiO 5 and CaMgSi 2 O 6 are the main crystallization phases with a basicity of 0.8. The difference between experimental and thermodynamics calculation is due to the complicate crystallization behavior of the multiple slag under super cooling rate. When the slag basicity increases to 1.1, the main precipitatied phase is perovskite, which agrees well with theory calculation. In addition, the crystal structure of the synthesized titanium bearing slag is basically similar regardless of the basicity.

Distribution behavior of B and P during directional solidification of Al-20Si, Al-30Si and Al-40Si alloys has been investigated. Macrostructure of the Al-Si alloy ingots and concentration profile of elements B and P reveal that the elements segregate to eutectic Al-Si melt during growth of primary Si flakes, and P gradually segregates to the top of the ingots during directional solidification. An apparent segregation coefficient, k a , is introduced to describe the segregation behavior of B and P between the primary Si and the Al-Si melt and compared with thermodynamic theoretical equilibrium coefficients. The apparent segregation coefficients of B and P decrease with increase of solidification temperature.

The TiC/Ni composite coating with different content of CeO 2 was fabricated on the Cr12MoV steel by laser cladding. The microstructure of cladding layers with the different content of CeO 2 from the bottom to the surface is columnar crystal, cellular crystal, and equiaxed crystal. When the content of CeO 2 is 0 %, the cladding layer has a coarse and nonuniform microstructure and TiC particles gathering in the cladding layer, and then the wear resistance was reduced. Appropriate rare-earth elements refined and homogenised the microstructure and enhanced the content of carbides, precipitated TiC particles and original TiC particles were spheroidised and refined, the wear resistance of the cladding layer was improved significantly. Excessive rare-earth elements polluted the grain boundaries and made the excessive burning loss of TiC particles that reduced the wear resistance of the cladding layer.

This research study attempts to create an optimized parametric window by employing Taguchi algorithm for Plasma Arc Welding (PAW) of 2 mm thick 2205 duplex stainless steel. The parameters considered for experimentation and optimization are the welding current, welding speed and pilot arc length respectively. The experimentation involves the parameters variation and subsequently recording the depth of penetration and bead width. Welding current of 60–70 A, welding speed of 250–300 mm/min and pilot arc length of 1–2 mm are the range between which the parameters are varied. Design of experiments is used for the experimental trials. Back propagation neural network, Genetic algorithm and Taguchi techniques are used for predicting the bead width, depth of penetration and validated with experimentally achieved results which were in good agreement. Additionally, micro-structural characterizations are carried out to examine the weld quality. The extrapolation of these optimized parametric values yield enhanced weld strength with cost and time reduction.

A component distribution model is proposed for three-component functionally gradient cemented carbide (FGCC) based on electron probe microanalysis results obtained for gradient layer thickness, microstructure, and elemental distribution. The residual surface stress of FGCC-T5 tools occurring during the fabrication process is analyzed using an ANSYS-implemented finite element method (FEM) and X-ray diffraction. A comparison of the experimental and calculated values verifies the feasibility of using FEM to analyze the residual surface stress in FGCC-T5 tools. The effects of the distribution index, geometrical shape, substrate thickness, gradient layer thickness, and position of the cobalt-rich layer on residual surface stress are studied in detail.

Fireside corrosion behavior of Inconel 740H superalloy was studied at 750 °C in simulated coal ash/flue gas environments by means of XRD, SEM and EDS. The results indicated that the corrosion behavior was strongly related to the SO 2 levels and was significantly affected by NaCl additions. In presence of the atmospheres with 0.1 % SO 2 , the alloy exhibited the highest corrosion resistance due to formation of a stable and dense Cr 2 O 3 film. In presence of the atmosphere with 1.5 % SO 2 , however, a non-coherent and porous Cr 2 O 3 film was formed. The thickness of film and internal sulfides were substantially increased. The NaCl additions significantly accelerated the corrosion process. A non-protective outer oxide film was formed, composed by multiple layers with serious inner sulfide and spallation. The depths of internal oxidizing and sulfuration zones were significantly increased. The mechanism of ash corrosion formation was also discussed.

Mechanical and creep properties of Q345c continuous casting slab subjected to uniaxial tensile tests at high temperature were considered in this paper. The minimum creep strain rate and creep rupture life equations whose parameters are calculated by inverse-estimation using the regression analysis were derived based on experimental data. The minimum creep strain rate under constant stress increases with the increase of the temperature from 1000 °C to 1200 °C. A new casting machine curve with the aim of fully using high-temperature creep behaviour is proposed in this paper. The basic arc segment is cancelled in the new curve so that length of the straightening area can be extended and time of creep behaviour can be increased significantly. For the new casting machine curve, the maximum straightening strain rate at the slab surface is less than the minimum creep strain rate. So slab straightening deformation based on the steel creep behaviour at high temperature can be carried out in the process of Q345c steel continuous casting. The effect of creep property at high temperature on slab straightening deformation is positive. It is helpful for the design of new casting machine and improvement of old casting machine.

Effects of lanthanum content on the solidification structure and the hot ductility of Fe-43Ni expansion alloy were investigated, the corresponding mechanisms were also discussed. The results showed that the macrostructures of the alloys were first significantly refined with increasing lanthanum content in the range of 0~0.025 % and then became coarse again with lanthanum content up to 0.04 %. La 2 O 2 S inclusions can serve as the effective inclusions sites promoting the refinement of the macrostructures. The changes of the macrostructures were influenced by the quantity density and the size distribution of La 2 O 2 S inclusions. The addition of 0.01–0.025 % lanthanum can improve the hot ductility over the whole testing temperature range, especially at 1000–1050 °C. The improvement of the hot ductility was mainly associated with the grain boundary strengthening and the acceleration of dynamic recrystallization by adding lanthanum. With addition of 0.04 % lanthanum, the hot ductility of the alloy became deteriorated, which was owed to the presence of brittle Fe-Ni-La intermetallic compounds.

The effects of heat treatment process on microstructure and properties of a nickel base superalloy are investigated. The size of γ´ phase decreases and the stress rupture life of alloy at 1100 °C/60 MPa drops with the rise of cooling rate. The hardness at room temperature also increases. The size of cuboidal γ´ precipitate and the volume of spherical γ´ precipitate increase with the rise of aging temperature. With higher aging temperature, the alloy exhibits bimodal γ´ phase. A reasonable combination of the size and volume fraction of cuboidal and spherical γ´ phase can obtain better stress rupture property at 1100 °C/60 MPa.

The paper investigated the creep-fatigue behavior for directionally solidified nickel-based superalloy DZ445 at 900 °C. It is found that the fatigue life shows an abnormal increase when the dwell time exceeds a critical value during creep-fatigue deformation. The area of hysteresis loop and fractograph explain the phenomenon quite well. The shortest life corresponds to the maximal area of hysteresis loop, i. e. the maximum energy to be consumed during the creep-fatigue cycle. The fractographic observation of failed samples further supports the abnormal behavior of fatigue life.

We present the first experimental results of the growth of Cu 6 Sn 5 and Cu 3 Sn under an external force field – during the sedimentation process. The results are compared with the proposed model under the combined influence of the Kirkendall effect, backstress and sedimentation. It is shown that Cu 3 Sn consumes the preformed Cu 6 Sn 5 phase during sedimentation under a strong gravitational field of 779,000 G at 200 °C.