Abstract
The phase equilibria of the Co–Cu –Ti system at 850 °C are investigated using a high-efficiency diffusion couple and six key ternary alloys. The samples are examined by means of optical microscopy, scanning electron microscopy, and electron probe microanalysis. At 850 °C, no ternary compound is found. The Ti3Cu phase is a metastable phase. The solubilities of Cu in Ti2Co, TiCo, TiCo2(c) and TiCo3 were determined to be 8.7, 35.8, 2.1, and 5.4 at.%, respectively. And the solubilities of Co in Ti2Cu, TiCu, Ti3Cu4, and TiCu2 were measured to be 6.6, 0.7, 2.4, and 10.2 at.%, respectively. The following 9 three-phase equilibria are observed: (Ti) + Ti2Co + Ti2Cu, Ti2Co + Ti2Cu + TiCo, Ti2Cu + TiCu + TiCo, TiCu + Ti3Cu4 + TiCo, Ti3Cu4 + TiCu2 + TiCo, TiCu2 + TiCo + (Cu), TiCo + TiCo2(c) + (Cu), TiCo2(h) + TiCo3 + (Cu), and TiCo3 + (Co) + (Cu).
References
[1] K.P. Gupta: J. Phase Equilib. 24 (2003) 272.10.1361/105497103770330640Search in Google Scholar
[2] H.U. Pfeifer, S. Bhan, K. Schubert: J. Less-Common Met. 14 (1968) 291.10.1016/0022-5088(68)90034-9Search in Google Scholar
[3] A.V. Davydov, U.R. Kattner, D. Josell, J.E. Blendell, R.M.Waterstrat, A.J. Shapiro, W.J. Boettinger: Metall. Mater. Trans. A 32 (2001) 2175.10.1007/s11661-001-0193-8Search in Google Scholar
[4] K.C.H. Kumar, I. Ansara, P. Wollants, L. Delaey: Z. Metallkd. 87 (1996) 666.Search in Google Scholar
[5] P. Canale, C. Servant: Z. Metallkd. 93 (2002) 273.10.3139/146.020273Search in Google Scholar
[6] J.L. Murray, in: P.R. Subramanian, D.J. Chakrabarti, D.E. Laughlin (Eds.), Phase Diagrams of Binary Copper Alloy, ASM International, Materials Park, OH (1990) 447.Search in Google Scholar
[7] T. Yamane, S. Nakajima, H. Araki, Y. Minamino, S. Saji, J. Takahashi, Y. Mijamoto: J. Mater. Sci. Lett. 13 (1994) 162.10.1007/BF00278149Search in Google Scholar
[8] V.N. Eremenko, Y.I. Buyanov, S.B. Prima: Poroshk. Metall. 20 (1966) 77.Search in Google Scholar
[9] J. Kubista, J. Vrest’al: J. Phase Equilib. 21 (2000) 125.10.1361/105497100770340165Search in Google Scholar
[10] H.H. Xu, Y. Du, B.Y. Huang, S.H. Liu: J. Alloys & Comp. 399 (2005) 92.10.1016/j.jallcom.2005.02.039Search in Google Scholar
© 2006 Carl Hanser Verlag, München
Articles in the same Issue
- Contents
- Phase separation in Si–(B)–C–N polymer-derived ceramics
- Solidification curves for commercial Mg alloys obtained from heat-transfer modeled DTA experiments
- Thermodynamic assessment of the Mg–Nd system
- Solid-state reaction in Ni/Si multilayered films, characterized by magneto-optical and optical spectroscopies
- Phase diagram of the Co–Cu–Ti system at 850 °C
- Effects of an electric field applied during the solution heat treatment of the Al–Mg –Si–Cu alloy AA6111 on the subsequent natural aging kinetics and tensile properties
- Fabrication and electrical sliding wear of graphitic Cu–Cr–Zr matrix composites
- Further results on creep behaviour of sand-cast Mg–2.8Nd–0.8Zn–0.5Zr–0.3Gd alloy at 0.56 to 0.61Tm under stresses 40 to 90 MPa
- On the creep resistance in cast Ni-base superalloys
- Formation, stability, and presence of magnesium nitride in magnesium recycling processes
- From waste to high strength alloy – recycling of magnesium chips
- Sigma phase formation and its effect on mechanical properties in the corrosion-resistant superalloy K44
- Personal/Personelles
- Press / Presse
- Contents
- Articles Basic
- Phase separation in Si–(B)–C–N polymer-derived ceramics
- Solidification curves for commercial Mg alloys obtained from heat-transfer modeled DTA experiments
- Thermodynamic assessment of the Mg–Nd system
- Solid-state reaction in Ni/Si multilayered films, characterized by magneto-optical and optical spectroscopies
- Phase diagram of the Co–Cu–Ti system at 850 °C
- Effects of an electric field applied during the solution heat treatment of the Al–Mg –Si–Cu alloy AA6111 on the subsequent natural aging kinetics and tensile properties
- Articles Applied
- Fabrication and electrical sliding wear of graphitic Cu–Cr–Zr matrix composites
- Further results on creep behaviour of sand-cast Mg–2.8Nd–0.8Zn–0.5Zr–0.3Gd alloy at 0.56 to 0.61Tm under stresses 40 to 90 MPa
- On the creep resistance in cast Ni-base superalloys
- Formation, stability, and presence of magnesium nitride in magnesium recycling processes
- From waste to high strength alloy – recycling of magnesium chips
- Sigma phase formation and its effect on mechanical properties in the corrosion-resistant superalloy K44
- Notifications/Mitteilungen
- Personal/Personelles
- Press / Presse
Articles in the same Issue
- Contents
- Phase separation in Si–(B)–C–N polymer-derived ceramics
- Solidification curves for commercial Mg alloys obtained from heat-transfer modeled DTA experiments
- Thermodynamic assessment of the Mg–Nd system
- Solid-state reaction in Ni/Si multilayered films, characterized by magneto-optical and optical spectroscopies
- Phase diagram of the Co–Cu–Ti system at 850 °C
- Effects of an electric field applied during the solution heat treatment of the Al–Mg –Si–Cu alloy AA6111 on the subsequent natural aging kinetics and tensile properties
- Fabrication and electrical sliding wear of graphitic Cu–Cr–Zr matrix composites
- Further results on creep behaviour of sand-cast Mg–2.8Nd–0.8Zn–0.5Zr–0.3Gd alloy at 0.56 to 0.61Tm under stresses 40 to 90 MPa
- On the creep resistance in cast Ni-base superalloys
- Formation, stability, and presence of magnesium nitride in magnesium recycling processes
- From waste to high strength alloy – recycling of magnesium chips
- Sigma phase formation and its effect on mechanical properties in the corrosion-resistant superalloy K44
- Personal/Personelles
- Press / Presse
- Contents
- Articles Basic
- Phase separation in Si–(B)–C–N polymer-derived ceramics
- Solidification curves for commercial Mg alloys obtained from heat-transfer modeled DTA experiments
- Thermodynamic assessment of the Mg–Nd system
- Solid-state reaction in Ni/Si multilayered films, characterized by magneto-optical and optical spectroscopies
- Phase diagram of the Co–Cu–Ti system at 850 °C
- Effects of an electric field applied during the solution heat treatment of the Al–Mg –Si–Cu alloy AA6111 on the subsequent natural aging kinetics and tensile properties
- Articles Applied
- Fabrication and electrical sliding wear of graphitic Cu–Cr–Zr matrix composites
- Further results on creep behaviour of sand-cast Mg–2.8Nd–0.8Zn–0.5Zr–0.3Gd alloy at 0.56 to 0.61Tm under stresses 40 to 90 MPa
- On the creep resistance in cast Ni-base superalloys
- Formation, stability, and presence of magnesium nitride in magnesium recycling processes
- From waste to high strength alloy – recycling of magnesium chips
- Sigma phase formation and its effect on mechanical properties in the corrosion-resistant superalloy K44
- Notifications/Mitteilungen
- Personal/Personelles
- Press / Presse