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Thermodynamic assessment of the ternary Cu–Pb–O system

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Published/Copyright: February 1, 2022
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 96 Issue 8

Abstract

The thermodynamic assessment of the ternary Cu– Pb– O system was carried out by the CALPHAD method. The thermodynamic properties of the phases are described using a compound energy formalism (CEF) for the various solid phases and an ionic two-sublattice model for the liquid. The thermodynamic parameters of the sub-systems Cu–O, Pb–O and Cu– Pb are adopted from recent assessments. Ternary interaction parameters of the liquid phase have been optimized on the base of the selected literature data (phase diagram and activity of oxygen). The ternary system shows a large liquid miscibility gap of peculiar shape, which connects to the miscibility gaps in each of the binary sub-systems. Calculated phase diagrams are compared with the experimental data.

Keywords: Cu –Pb–O; Phase diagram; Thermodynamics; CALPHAD
Marija Cancarevic Max-Planck-Institut für Metallforschung Pulvermetallurgisches Laboratorium Heisenbergstraße 3, D-70569 Stuttgart, Germany Tel.: +49 711 68 93 107 Fax: +49 711 68 93 131

  1. Financial support of this work by Robert Bosch GmbH is gratefully acknowledged.

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Received: 2004-11-02
Accepted: 2005-02-16
Published Online: 2022-02-01

© 2005 Carl Hanser Verlag, München

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https://doi.org/10.3139/ijmr-2005-1153
Keywords for this article
Cu –Pb–O; Phase diagram; Thermodynamics; CALPHAD

Articles in the same Issue

  1. Frontmatter
  2. Articles Basic
  3. Diffusion in molybdenum disilicide
  4. Martensitic transformation, ductility, and shape-memory effect of polycrystalline Ni56Mn25 – xFexGa19 alloys
  5. Mechanical and electrical properties of Ti2SnC dispersion-strengthened copper
  6. Thermodynamic and phase relation study of the Ni–Ge –O system in the solid state
  7. Thermodynamic assessment of Mg–Al–Mn phase equilibria, focusing on Mg-rich alloys
  8. DSC study on the phase decomposition of an Al–Cu alloy occurring during annealing at 403 K
  9. Structure and thermal stability of a melt-quenched single-phase nanocrystalline Hf61Fe39 alloy
  10. Thermodynamic assessment of the ternary Cu–Pb–O system
  11. Combined EELS, EDX, and STEM investigations of Cu-induced nanostrucutures and thin surface layer phases
  12. Articles Applied
  13. Fatigue failure of titanium implants for mandibular reconstruction
  14. Solid state reaction mechanism for the synthesis of La1 – xSrxCoO3–δ (0.1 ≤ x ≤ 0.7)
  15. Dislocation structures in 16MND5 pressure vessel steel strained in uniaxial tension at –196 °C
  16. Microstructure of AZ91 alloy deformed by equal channel angular pressing
  17. The effect of copper on secondary phase precipitation in duplex stainless steel – a thermodynamic calculations approach
  18. Stretch-zone analysis by image processing for the evaluation of initiation fracture toughness of a HSLA steel
  19. Copper-lithium alloy produced by powder metallurgy procedures and its age-hardening response
  20. Effects of the local microstructures on the mechanical properties in FSWed joints of a 7075-T6 Al alloy
  21. Estimating ternary surface tension for systems with limited solubility
  22. Notifications/Mitteilungen
  23. Personal/Personelles
  24. News/Aktuelles
  25. Conferences/Konferenzen
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