Abstract
A new model is introduced to calculate the physicochemical properties of systems with limited solubility. It has been applied to compute the surface tension of MnO– CaO– SiO2 liquid phase at 1500 °C based on the boundary data. The good agreement between referenced data and theoretical calculations shows that this method is feasible and will play a useful role for metallurgical slag since most of metallurgical systems are with a limited homogeneous field.
-
The authors like to express their thanks to Ministry of Education and to the Chinese National Science Foundation for their kind financial supports under contracts of No: 2002-0210-550(EDU), 50274008(NSFC), 2002-0212-860(NSFC).
References
[1] T. Tanaka, K. Hack, T. Iida, S. Hara: Z. Metallkd. 87 (1996) 380.Search in Google Scholar
[2] T. Tanaka, S. Hara, M. Ogawa, T. Ueda: Z. Metallkd. 89 (1998) 368.Search in Google Scholar
[3] T. Tanaka, K. Hack, S. Hara: MRS Bull. 24 (1999) 45.10.1557/S0883769400052180Search in Google Scholar
[4] T. Tanaka, S. Hara: Z. Metallkd. 90 (1999) 348.Search in Google Scholar
[5] T. Ueda, T. Tanaka, S. Hara: Z. Metallkd. 90 (1999) 342.Search in Google Scholar
[6] T. Tanaka, S. Hara: Electrochemistry 67 (1999) 573.10.5796/electrochemistry.67.573Search in Google Scholar
[7] Xian-mei Zhong, K.-C. Chou, Yunmin Gao, Xingmin Guo, Xinzhe Lan: CALPHAD 25 (2001) 455.10.1016/S0364-5916(01)00064-5Search in Google Scholar
[8] X.M. Zhong, Y.H. Liu, K.-C. Chou, X.G. Lu, D. Zivkovic, Z. Zivkovic: J. Phase Equilibria 24 (2003) 7.10.1007/s11669-003-0002-8Search in Google Scholar
[9] M. Hillert: CALPHAD 14 (1980) 1.10.1016/0364-5916(80)90016-4Search in Google Scholar
[10] I. Ansara: International Metals Reviews 24 (1979) 20.10.1179/imtr.1979.24.1.20Search in Google Scholar
[11] K.-C. Chou, Y.A. Chang: Ber. Bunsenges. Phys. Chem. 93 (1989) 741.10.1002/bbpc.19890930616Search in Google Scholar
[12] K.-C. Chou, S.-K. Wei: Metall. Mater. Trans. B 28 (1997) 439.10.1007/s11663-997-0110-7Search in Google Scholar
[13] F. Kohler: Monatsh. Chem. 91 (1960) 738.10.1007/BF00899814Search in Google Scholar
[14] Y.M. Muggianu, M. Gambino, J.P. Bros: J. Chem. Phys. 72 (1965) 83.Search in Google Scholar
[15] K.T. Jacobs, K. Fitzner: Thermochimica Acta 18 (1977) 197.10.1016/0040-6031(77)80019-1Search in Google Scholar
[16] G.W. Toop: Trans. AIME 233 (1965) 850.Search in Google Scholar
[17] R. Lück, U. Gerling, B. Predel: Z. Metalkd. 77 (1986) 442.Search in Google Scholar
[18] K.-C. Chou: CALPHAD 11 (1987) 293.10.1016/0364-5916(87)90048-4Search in Google Scholar
[19] R.-Q. Li: MS. Thesis, University of Science & Technology Beijing, China (1988).Search in Google Scholar
[20] S.-L. Chen, K.-C. Chou: Rare Metals 18 (1989) 22.Search in Google Scholar
[21] K.-C. Chou, R.-Q. Li: Rare Metals 18 (1989) 12.Search in Google Scholar
[22] S.-L. Chen, K.-C. Chou: CALPHAD 13 (1989) 79.10.1016/0364-5916(89)90042-4Search in Google Scholar
[23] S.-L. Chen, J.-Q. Cui, T.-K. Chen, K.-C. Chou: CALPHAD 13 (1989) 225.10.1016/0364-5916(89)90002-3Search in Google Scholar
[24] Kuo-Chih Chou: CALPHAD 19 (1995) 315.10.1016/0364-5916(95)00029-ESearch in Google Scholar
[25] Kuo-Chih Chou, Xianmei Zhong, Kuangdi Xu: Metall. Mater. Trans. B 35 (2004) 715.10.1007/s11663-004-0011-ySearch in Google Scholar
[26] T.A. Kekelidze, Sh. M.Mikiashvili, T.I. Dzhintsaradze, R.V. Khomeriki: Izv. An. Gruz. SSR: Ser. Khim 4 (1978) 240.Search in Google Scholar
[27] B.J. Keene: Slag Atlas, 2nd ed., Verlag Stahleisen GmbH, Düsseldorf (1995) 403, 440Search in Google Scholar
© 2005 Carl Hanser Verlag, München
Articles in the same Issue
- Frontmatter
- Articles Basic
- Diffusion in molybdenum disilicide
- Martensitic transformation, ductility, and shape-memory effect of polycrystalline Ni56Mn25 – xFexGa19 alloys
- Mechanical and electrical properties of Ti2SnC dispersion-strengthened copper
- Thermodynamic and phase relation study of the Ni–Ge –O system in the solid state
- Thermodynamic assessment of Mg–Al–Mn phase equilibria, focusing on Mg-rich alloys
- DSC study on the phase decomposition of an Al–Cu alloy occurring during annealing at 403 K
- Structure and thermal stability of a melt-quenched single-phase nanocrystalline Hf61Fe39 alloy
- Thermodynamic assessment of the ternary Cu–Pb–O system
- Combined EELS, EDX, and STEM investigations of Cu-induced nanostrucutures and thin surface layer phases
- Articles Applied
- Fatigue failure of titanium implants for mandibular reconstruction
- Solid state reaction mechanism for the synthesis of La1 – xSrxCoO3–δ (0.1 ≤ x ≤ 0.7)
- Dislocation structures in 16MND5 pressure vessel steel strained in uniaxial tension at –196 °C
- Microstructure of AZ91 alloy deformed by equal channel angular pressing
- The effect of copper on secondary phase precipitation in duplex stainless steel – a thermodynamic calculations approach
- Stretch-zone analysis by image processing for the evaluation of initiation fracture toughness of a HSLA steel
- Copper-lithium alloy produced by powder metallurgy procedures and its age-hardening response
- Effects of the local microstructures on the mechanical properties in FSWed joints of a 7075-T6 Al alloy
- Estimating ternary surface tension for systems with limited solubility
- Notifications/Mitteilungen
- Personal/Personelles
- News/Aktuelles
- Conferences/Konferenzen
Articles in the same Issue
- Frontmatter
- Articles Basic
- Diffusion in molybdenum disilicide
- Martensitic transformation, ductility, and shape-memory effect of polycrystalline Ni56Mn25 – xFexGa19 alloys
- Mechanical and electrical properties of Ti2SnC dispersion-strengthened copper
- Thermodynamic and phase relation study of the Ni–Ge –O system in the solid state
- Thermodynamic assessment of Mg–Al–Mn phase equilibria, focusing on Mg-rich alloys
- DSC study on the phase decomposition of an Al–Cu alloy occurring during annealing at 403 K
- Structure and thermal stability of a melt-quenched single-phase nanocrystalline Hf61Fe39 alloy
- Thermodynamic assessment of the ternary Cu–Pb–O system
- Combined EELS, EDX, and STEM investigations of Cu-induced nanostrucutures and thin surface layer phases
- Articles Applied
- Fatigue failure of titanium implants for mandibular reconstruction
- Solid state reaction mechanism for the synthesis of La1 – xSrxCoO3–δ (0.1 ≤ x ≤ 0.7)
- Dislocation structures in 16MND5 pressure vessel steel strained in uniaxial tension at –196 °C
- Microstructure of AZ91 alloy deformed by equal channel angular pressing
- The effect of copper on secondary phase precipitation in duplex stainless steel – a thermodynamic calculations approach
- Stretch-zone analysis by image processing for the evaluation of initiation fracture toughness of a HSLA steel
- Copper-lithium alloy produced by powder metallurgy procedures and its age-hardening response
- Effects of the local microstructures on the mechanical properties in FSWed joints of a 7075-T6 Al alloy
- Estimating ternary surface tension for systems with limited solubility
- Notifications/Mitteilungen
- Personal/Personelles
- News/Aktuelles
- Conferences/Konferenzen