Bio-Based Hybrid Polymers from Vinyl Ester Resin and Modified Palm Oil: Synthesis and Characterization
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A. Fakhari
Abstract
A series of bio-based hybrid thermosets composed of maleinated acrylated epoxidized palm oil (MAEPO) and vinyl ester resin (VE) were produced using free radical-induced crosslinking. The amount of petroleum-based resin which was replaced by bio-resin (MAEPO) was varied from 5 to 20 wt%. The structure of the polymer systems was investigated by scanning electron microscopy and dynamic mechanical analysis. The mechanical properties of the VE/MAEPO resins were studied using tensile, flexural and impact tests. The result obtained from structural analysis revealed that for the polymer hybrids with up to 20 wt% bio-resin content, there is good compatibility between MAEPO and VE as no phase separation was observed for these systems. The prepared eco-friendly bio-based thermosetting resins exhibit remarkable improvement in toughness parameters, such as ductility and impact strength, thereby showing potential for use in composites and nanocomposites applications.
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© 2017, Carl Hanser Verlag, Munich
Artikel in diesem Heft
- Contents
- Contents
- Editorial
- New Associate Editor for the Americas
- Regular Contributed Articles
- Effect of Flow Induced Orientation of Carbon Nanotubes on the Capillary Extrusion Behavior of Low-Density Polyethylene
- Mullins Effect under Compression Mode and its Reversibility of Thermoplastic Vulcanizate Based on Ethylene-Vinyl Acetate Copolymer/Styrene-Butadiene Rubber Blend
- Bio-Based Hybrid Polymers from Vinyl Ester Resin and Modified Palm Oil: Synthesis and Characterization
- Study on Crystal Form Transition and Non-Isothermal Crystallization of Glycidyl Methacrylate Grafted Isotactic Polybutene-1
- Flashing Method for Fabricating Micro Scale Fibers, Spheres, Porous and Condensed Polymer Structures
- Preparation and Performance Evaluation of SPEEK/Polyaniline Composite Membrane for Direct Methanol Fuel Cell
- Rotational Molding of Linear Low Density Polyethylene (LLDPE) Fumed Silica Nanocomposites
- Design Guidelines to Balance the Flow Distribution in Complex Profile Extrusion Dies
- Microstructure and Mechanical Properties of Nanocomposite Based on Polypropylene/Ethylene Propylene Diene Monomer/Graphene
- An Engineering Model that Simulates Pantographing Occurring in the Shaping Process of Reinforced Uncured Rubber Parts
- The Influence of Different Melt Temperatures on the Mechanical Properties of Injection Molded PA-12 and the Post Process Detection by Thermal Analysis
- Morphology and Thermal Behavior of TPU/PP Blends Modified with Maleic Anhydride Grafted SEBS-g-MA Block Copolymer
- Extrusion Blow Molding of Polymeric Blends Based on Thermotropic Liquid Crystalline Polymer and High Density Polyethylene
- Characterization of Stereocomplex Polylactide/Nanoclay Nanocomposites
- Attempts to Optimize the Dispersion State during Twin-Screw Extrusion of Polypropylene/Clay Nanocomposites
- Rapid Communications
- Improved Layer Mechanical Properties of Micro Injection Molded PP
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei-Kakou Abstracts
Artikel in diesem Heft
- Contents
- Contents
- Editorial
- New Associate Editor for the Americas
- Regular Contributed Articles
- Effect of Flow Induced Orientation of Carbon Nanotubes on the Capillary Extrusion Behavior of Low-Density Polyethylene
- Mullins Effect under Compression Mode and its Reversibility of Thermoplastic Vulcanizate Based on Ethylene-Vinyl Acetate Copolymer/Styrene-Butadiene Rubber Blend
- Bio-Based Hybrid Polymers from Vinyl Ester Resin and Modified Palm Oil: Synthesis and Characterization
- Study on Crystal Form Transition and Non-Isothermal Crystallization of Glycidyl Methacrylate Grafted Isotactic Polybutene-1
- Flashing Method for Fabricating Micro Scale Fibers, Spheres, Porous and Condensed Polymer Structures
- Preparation and Performance Evaluation of SPEEK/Polyaniline Composite Membrane for Direct Methanol Fuel Cell
- Rotational Molding of Linear Low Density Polyethylene (LLDPE) Fumed Silica Nanocomposites
- Design Guidelines to Balance the Flow Distribution in Complex Profile Extrusion Dies
- Microstructure and Mechanical Properties of Nanocomposite Based on Polypropylene/Ethylene Propylene Diene Monomer/Graphene
- An Engineering Model that Simulates Pantographing Occurring in the Shaping Process of Reinforced Uncured Rubber Parts
- The Influence of Different Melt Temperatures on the Mechanical Properties of Injection Molded PA-12 and the Post Process Detection by Thermal Analysis
- Morphology and Thermal Behavior of TPU/PP Blends Modified with Maleic Anhydride Grafted SEBS-g-MA Block Copolymer
- Extrusion Blow Molding of Polymeric Blends Based on Thermotropic Liquid Crystalline Polymer and High Density Polyethylene
- Characterization of Stereocomplex Polylactide/Nanoclay Nanocomposites
- Attempts to Optimize the Dispersion State during Twin-Screw Extrusion of Polypropylene/Clay Nanocomposites
- Rapid Communications
- Improved Layer Mechanical Properties of Micro Injection Molded PP
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei-Kakou Abstracts