A critical analysis of the X-ray diffraction intensities in concentrated multicomponent alloys
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Rameshwari Naorem
Abstract
The decrease in the X-ray diffraction Bragg peak intensity from concentrated multicomponent alloys (CMA), has been modeled in literature akin to the effect of temperature. In the current work, experiments and computations are used to comprehend the effect of atomic disorder in CMA on the Bragg peaks of powder diffraction patterns. Ni–Co–Fe–Cr–Mn and Cu–Ni–Co–Fe–V have been used as model systems for the study. It is proved that the intensity decrease is not insignificant, but is not anomalous either. A recipe is evolved to compare the Bragg peak intensities across the alloys of a CMA. It is demonstrated that it is incorrect to model the effect of an increase in atomic disorder in a CMA, as a temperature effect. A ‘good measure’ of lattice distortion is identified and further it is established that full width half maximum is a good measure of the bond length distortion. It is demonstrated that the true strain due to bond length distortion is of significantly lower magnitude than that given by a priori measures of lattice strain. In the scheme of categorization of defects in crystals, it is argued that CMA is a separate class (as distinct from type-I and type-II defects); which should be construed as a defected solid, rather than a defect in a solid.
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© 2019, Carl Hanser Verlag, München
Artikel in diesem Heft
- Contents
- Contents
- Original Contributions
- Relationship between the variation in transformation temperatures, resistivity and dislocation density during thermal cycling of Ni50Ti50 shape memory alloy
- A critical analysis of the X-ray diffraction intensities in concentrated multicomponent alloys
- Thermodynamic investigations in the Al–Fe system: Thermodynamic modeling using CALPHAD
- Investigation of semi-solid microstructures of an A356 alloy containing rare-earth Gd during isothermal heat treatment
- Effects of double-ageing on the mechanical properties and microstructural evolution in the 1460 alloy
- Mechanical properties characterisation of AlSi10Mg parts produced by laser powder bed fusion additive manufacturing
- Tribological performance and corrosion behavior of aluminum alloy protected by Cr-doped diamond-like carbon thin film
- Effect of sintering temperature on the densification and optical properties of spark plasma sintered ZnSe ceramics
- Mono-crystalline SnTe with micro-octahedroncharacteristic: One-pot facile synthesis and comprehensive crystallographic evidence
- Finite element simulation of the residual stress in Ti6Al4V titanium alloy laser welded joint
- Short Communications
- Mechanism of the effect of electron beam melting on the distribution of oxygen, nitrogen and carbon in silicon
- Synthesis and study of structural, morphological, optical and toxicological properties of ferromagnetic cobalt oxide nanoparticles in liver carcinoma cell line
- DGM News
- DGM News
Artikel in diesem Heft
- Contents
- Contents
- Original Contributions
- Relationship between the variation in transformation temperatures, resistivity and dislocation density during thermal cycling of Ni50Ti50 shape memory alloy
- A critical analysis of the X-ray diffraction intensities in concentrated multicomponent alloys
- Thermodynamic investigations in the Al–Fe system: Thermodynamic modeling using CALPHAD
- Investigation of semi-solid microstructures of an A356 alloy containing rare-earth Gd during isothermal heat treatment
- Effects of double-ageing on the mechanical properties and microstructural evolution in the 1460 alloy
- Mechanical properties characterisation of AlSi10Mg parts produced by laser powder bed fusion additive manufacturing
- Tribological performance and corrosion behavior of aluminum alloy protected by Cr-doped diamond-like carbon thin film
- Effect of sintering temperature on the densification and optical properties of spark plasma sintered ZnSe ceramics
- Mono-crystalline SnTe with micro-octahedroncharacteristic: One-pot facile synthesis and comprehensive crystallographic evidence
- Finite element simulation of the residual stress in Ti6Al4V titanium alloy laser welded joint
- Short Communications
- Mechanism of the effect of electron beam melting on the distribution of oxygen, nitrogen and carbon in silicon
- Synthesis and study of structural, morphological, optical and toxicological properties of ferromagnetic cobalt oxide nanoparticles in liver carcinoma cell line
- DGM News
- DGM News
