Article
Licensed
Unlicensed Requires Authentication

Enthalpies of mixing in binary Mn–In and ternary Mn–In–Gd liquid alloys

  • , and
Published/Copyright: March 26, 2018
Become an author with De Gruyter Brill
Submit Manuscript Author Information
International Journal of Materials Research
From the journal International Journal of Materials Research Volume 109 Issue 4

Abstract

The enthalpies of mixing in liquid alloys of the binary Mn–In and ternary Mn–In–Gd systems were determined over a wide range of compositions by means of isoperibolic calorimetry in the temperature range 1 500 – 1 650 K. The enthalpies of mixing in the Mn–In system demonstrate endothermic effects (ΔHmax = 4.66 ± 0.38 kJ · mol−1 at xIn = 0.40). The enthalpies of mixing in the liquid ternary Mn–In–Gd alloys were determined along six sections (xMn/xIn = 0.22/0.78; 0.44/0.56; 0.65/0.35 and 0.83/0.17 for xGd changed from 0 up to 0.5 and xMn/xGd = 0.30/0.70; 0.60/0.40 for xIn changed from 0 up to 0.3). Enthalpies of mixing in the ternary system were found to be predominantly exothermic and steadily increasing in absolute values towards the Gd–In boundary binary system, reaching the maximum value in the vicinity of the phase GdIn.

Keywords: Manganese; Indium; Gadolinium; Calorimetry; Enthalpy of mixing
*Correspondence address, Dr. Natalia Usenko, Taras Shevchenko National University, Department of Chemistry, 64, Volodymirska St. 01601 Kyiv Ukraine, Tel.: +380442393370, E-mail:

References

[1] L.Y.Wang, J.Wang, C.F.Zhu, G.Cheng, C.Y.Tang, G.H.Rao, H.Y.Zhou: Thermochim. Acta607 (2015) 74–81. 10.1016/j.tca.2015.03.022Search in Google Scholar

[2] S.V.Meschel, O.J.Kleppa: J. Alloys Compd.333 (2002) 91–98. 10.1016/S0925-8388(01)01727-3Search in Google Scholar

[3] T.B.Massalski (Ed.): Binary Alloy Phase Diagrams, 1st ed., ASM International, Metals Park, OH (1986). 10.1007/BF02867807Search in Google Scholar

[4] M.Ivanov, V.Berezutski, N.Usenko: Int. J. Mater. Res. (Z. Metallkd.)102 (2011) 277–281. 10.3139/146.110474Search in Google Scholar

[5] M.O.Shevchenko, M.I.Ivanov, V.V.Berezutski, V.S.Sudavtsova: Russ. J. Phys. Chem.90 (2016) 3–12. 10.1134/S0036024415120274Search in Google Scholar

[6] S.Delfino, A.Saccone, R.Ferro: Z. Metallkd.74 (1983) 674–679.Search in Google Scholar

[7] A.Palenzona, C.Ciraficci: Thermochim. Acta.9 (1974) 419–425. 10.1016/0040-6031(74)80039-0Search in Google Scholar

[8] S.V.Meschel, O.J.Kleppa: J. Alloys Compd.337 (2002) 115–119. 10.1016/S0925–8388(01)01920-XSearch in Google Scholar

[9] C.B.Alcock, V.P.Itkin, M.K.Horrigan: Canad. Metall. Quart.23 (1984) 309–315. 10.1179/cmq.1984.23.3.309Search in Google Scholar

[10] N.I.Usenko, M.I.Ivanov, V.M.Petiuh, V.T.Witusiewicz: J. Alloys Compd.190 (1993) 149–155. 10.1016/0925-8388(93)90391-YSearch in Google Scholar

[11] A.T.Dinsdale: Calphad15 (1991) 317–425. 10.1016/0364-5916(91)90030-NSearch in Google Scholar

[12] M.I.Ivanov, V.T.Witusiewicz: J. Alloys Compd.186 (1992) 255–266. 10.1016/0925-8388(92)90012-XSearch in Google Scholar

[13] C.W.Bale, A.D.Pelton: Metall. Trans.5 (1974) 2323–2337. 10.1007/BF02644013Search in Google Scholar

[14] L.S.Darken: J. Am. Chem. Soc.72 (1950) 2909–2914. 10.1021/ja01163a030Search in Google Scholar

[15] R.Lück, U.Gerling, B.Predel: Z. Metallkd.77 (1976) 442–448.Search in Google Scholar

[16] M.Hillert: CALPHAD4 (1980) 1–12. 10.1016/0364-5916(80)90016-4Search in Google Scholar

[17] A.K.Niessen, F.R.de Boer, R.Boom, W.C.M.Mattens, A.R.Miedema: CALPHAD7 (1983) 51–70. 10.1016/0364-5916(83)90030-5Search in Google Scholar

[18] www.webelements.com/periodicity/electroneg_allred_rochow.Search in Google Scholar

[19] http://www.webelements.com/periodicity/molar_volume.Search in Google Scholar

[20] R.N.Singh, F.Sommer: Z. Metallkd.83 (1992) 533–540.Search in Google Scholar

[21] http://www.webelements.com/manganese/thermochemistry.html.Search in Google Scholar

Received: 2017-09-08
Accepted: 2017-11-21
Published Online: 2018-03-26
Published in Print: 2018-04-13

© 2018, Carl Hanser Verlag, München

Articles in the same Issue

  1. Contents
  2. Contents
  3. Original Contributions
  4. Deposition of CVD-TiCN and TiAlN coatings guided with thermodynamic calculations
  5. Microstructure and mechanical properties of ultra-fine WC-10Co cemented carbides with Cr3C2 and NbC: Experimental investigation supported by thermodynamic calculation
  6. Enthalpies of mixing in binary Mn–In and ternary Mn–In–Gd liquid alloys
  7. Thermal stability of Nb–Cr–Mo alloy
  8. Effect of processing parameters on the grain refinement of vanadium nitrogen microalloyed steel
  9. Effects of heat treatment and testing temperature on the tensile properties of Al–Cu and Al–Cu–Si based alloys
  10. Fabrication of Al–Si Gasar by mold casting technique
  11. Tribological performance of glass/epoxy composites filled with MWCNTs
  12. Reaction fabrication and wear performance of TiCx/(Cu–A1) bonded diamond composites
  13. DC-EPD of nanoceramic particles accelerated via anodic dissolution in organic media
  14. Short Communications
  15. Formation of zirconia precursor nanoplates mediated by ionic liquid and transformation to monoclinic ZrO2 nanostructures
  16. Characterization of interfaces in tri-layered brass/steel/brass composites fabricated by casting and hot dipping
  17. DGM News
  18. DGM News
https://doi.org/10.3139/146.111611
Keywords for this article
Manganese; Indium; Gadolinium; Calorimetry; Enthalpy of mixing

Articles in the same Issue

  1. Contents
  2. Contents
  3. Original Contributions
  4. Deposition of CVD-TiCN and TiAlN coatings guided with thermodynamic calculations
  5. Microstructure and mechanical properties of ultra-fine WC-10Co cemented carbides with Cr3C2 and NbC: Experimental investigation supported by thermodynamic calculation
  6. Enthalpies of mixing in binary Mn–In and ternary Mn–In–Gd liquid alloys
  7. Thermal stability of Nb–Cr–Mo alloy
  8. Effect of processing parameters on the grain refinement of vanadium nitrogen microalloyed steel
  9. Effects of heat treatment and testing temperature on the tensile properties of Al–Cu and Al–Cu–Si based alloys
  10. Fabrication of Al–Si Gasar by mold casting technique
  11. Tribological performance of glass/epoxy composites filled with MWCNTs
  12. Reaction fabrication and wear performance of TiCx/(Cu–A1) bonded diamond composites
  13. DC-EPD of nanoceramic particles accelerated via anodic dissolution in organic media
  14. Short Communications
  15. Formation of zirconia precursor nanoplates mediated by ionic liquid and transformation to monoclinic ZrO2 nanostructures
  16. Characterization of interfaces in tri-layered brass/steel/brass composites fabricated by casting and hot dipping
  17. DGM News
  18. DGM News
Downloaded on 10.4.2026 from https://www.degruyterbrill.com/document/doi/10.3139/146.111611/html
Scroll to top button