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Effect of acetic acid on corrosion behavior of AISI 201, 304 and 430 stainless steels

  • Himanshu Vashishtha , Ravindra V. Taiwade and Sumitra Sharma
Published/Copyright: May 4, 2017
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Abstract

Austenitic stainless steels are often used to handle organic acids such as acetic acid (CH3COOH), which are extensively used in food contact applications and chemical industries for manufacturing medicines, nutrition and various chemical amalgams. In the present investigation an attempt has been made to compare the corrosion behavior of Cr–Ni (AISI type 304), Cr–Mn–Ni (type 201) and Cr (type 430) stainless steel for economical replacement of higher cost Cr–Ni grade. Immersion testing was performed at room temperature and boiling temperature in acetic acid. Atomic absorption spectroscopy was carried out to evaluate metal ion concentration in the immersion solution. The surface morphology of pit formation was characterized using scanning electron microscopy coupled with energy dispersive X-ray spectroscopy. The effect of elemental leaching on electrical conductivity of the immersion solution was evaluated and correlated with pH measurements. A new mechanism has been proposed for the pit formation due to manganese sulfide inclusions. The replacement compatibility was further confirmed with anodic polarization testing and a successful replacement was established for room temperature applications.


*Correspondence address, Dr. Ravindra V. Taiwade, Metallurgical and Materials Engineering, Visvesvaraya National Institute of Technology (VNIT), South Ambazari Road, Nagpur 440010, India, Tel.: +919881712985, Fax: +91-712-2223230, E-mail:

References

[1] T.Oshima, Y.Habara, K.Kuroda: ISIJ Int.47 (2007) 359. 10.2355/isijinternational.47.359Search in Google Scholar

[2] R.Dalipi, L.Borgese, A.Casaroli, M.Boniardi, U.Fittschen, K.Tsuji, L.E.Depero: J. Food Eng.173 (2016) 85. 10.1016/j.jfoodeng.2015.10.045Search in Google Scholar

[3] D.G.Barceloux: Clin. Toxicol.37 (1999) 239. 10.1081/CLT-100102423Search in Google Scholar

[4] G.Herting, D.Lindstrom, I.O.Wallinder, C.Leygraf: J. Food Eng.93 (2009) 23. 10.1016/j.jfoodeng.2008.12.019Search in Google Scholar

[5] K.S.George, S.Nesic: Corrosion63 (2007) 178. 10.5006/1.3278342Search in Google Scholar

[6] S.K.Singh, A.K.Mukherjee: J. Mater. Sci. Technol.26 (2010) 264. 10.1016/S1005-0302(10)60044-8Search in Google Scholar

[7] J.Amri, E.Gulbrandsen, R.P.Nogueira: Corros. Sci.52 (2010) 1728. 10.1016/j.corsci.2010.01.010Search in Google Scholar

[8] I.Sekine, A.Masuko, K.Senoo: Corrosion43 (1987) 553. 10.5006/1.3583900Search in Google Scholar

[9] E.Otero, A.Pardo, M.V.Utrilla, F.J.Perez, C.Merino: Corros. Sci.39 (1997) 453. 10.1016/S0010-938X(97)86097-0Search in Google Scholar

[10] A.Turnbull, M.Ryan, A.Willetts, S.Zhou: Corros. Sci.45 (2003) 1051. 10.1016/S0010-938x(02)00149-xSearch in Google Scholar

[11] G.Herting, I.O.Wallinder, C.Leygraf: J. Food Eng.87 (2008) 291. 10.1016/j.jfoodeng.2007.12.006Search in Google Scholar

[12] I.Sekine, S.Hatakeyama, Y.Nakajawa: Corros. Sci.27 (1987) 275. 10.1016/0010-938X(87)90023-0Search in Google Scholar

[13] I.Sekine, S.Hatakeyama, Y.Nakajawa: Electrochim. Acta32 (1987) 915. 10.1016/0013-4686(87)87083-4Search in Google Scholar

[14] N.Mazinanian, I.O.Wallinder, Y.Hedberg: J. Food Eng.145 (2015) 51. 10.1016/j.jfoodeng.2014.08.006Search in Google Scholar

[15] V.B.Singh, A.K.Gupta: Corrosion57 (2001) 43. 10.5006/1.3290329Search in Google Scholar

[16] V.S.Rao, L.K.Singhal: Corrosion66 (2010) 085004-1. 10.5006/1.3479954Search in Google Scholar

[17] A.Fattah-alhosseini, S.Vafaeian: Egypt. J. Pet.24 (2015) 333. 10.1016/j.ejpe.2015.07.016Search in Google Scholar

[18] R.Dalipi, L.Borgese, A.Casaroli, M.Boniardi, U.Fittschen, K.Tsuji, L.E.Depero: J. Food Eng.173 (2016) 85. 10.1016/j.jfoodeng.2015.10.045Search in Google Scholar

[19] R.V.Taiwade, A.P.Patil, S.J.Patre, R.K.Dayal: ISIJ Int.52 (2012) 1879. 10.2355/isijinternational.52.1879Search in Google Scholar

[20] ASTM A262: Standard Practices for detecting susceptibility to intergranular attack in austenitic stainless steels (2016).Search in Google Scholar

[21] ASTM G31–72: Standard practice for laboratory immersion corrosion testing of metals (2004).Search in Google Scholar

[22] ASTM G1–03: Standard practice for preparing, cleaning, and evaluating corrosion test specimens (2011).Search in Google Scholar

[23] V.Singh, A.Gupta: Corrosion57 (2001) 43. 10.5006/1.3290329Search in Google Scholar

[24] S.Mishra, T.J.Lienert, M.Q.Johnson, T.Debroy: Acta Mater.56 (2008) 2133. 10.1016/j.actamat.2008.01.028Search in Google Scholar

[25] M.P.Ryan, D.E.Williams, R.J.Chater, B.M.Hutton, D.S.McPhail: Nature415 (2002) 770. PMid:11845203; 10.1038/415770aSearch in Google Scholar

[26] I.Sekine, T.Kawase, M.Kobayashi, M.Yuasa: Corros. Sci.32 (1991) 815. 10.1016/0010-938X(91)90026-LSearch in Google Scholar

[27] D.E.Williams, Y.Y.Jhu: J. Electrochem. Soc.147 (2000) 1763. 10.1149/1.1393431Search in Google Scholar

[28] L.Freire, M.J.Carmezim, M.G.S.Ferreira, M.F.Montemor: Electrochim. Acta.56 (2011) 5280. 10.1016/j.electacta.2011.02.094Search in Google Scholar

[29] V.Hays, R.L.Gall, G.Saindrenan, D.Roptin: Scr. Mater.38 (1998) 391. 10.1016/S1359-6462(97)00470-3Search in Google Scholar

[30] T.L.Sudesh, L.Wijesinghe, D.J.Blackwood: Corros. Sci.49 (2007) 1755. 10.1016/j.corsci.2006.10.025Search in Google Scholar

[31] A.Chiba, I.Muto, Y.Sugawara, N.Hara: J. Electrochem. Soc.159 (2012) C341. 10.1149/2.054208jesSearch in Google Scholar

[32] P.Schmuki, H.Hildebrand, A.Friedrich, S.Virtanen: Corros. Sci.47 (2005) 1239. 10.1016/j.corsci.2004.05.023Search in Google Scholar

[33] V.Vignal, N.Mary, R.Oltra, J.Peultier: J. Electrochem. Soc.153 (2006) B352. 10.1149/1.2218762Search in Google Scholar

[34] J.Stewart, D.E.Williams: Corros. Sci.33 (1992) 457. 10.1016/0010-938X(92)90074-DSearch in Google Scholar

[35] M.J.Carmezim, A.M.Simoes, M.F.Montemor, M.D.Belo: Corros. Sci.47 (2005) 581. 10.1016/j.corsci.2004.07.002Search in Google Scholar

[36] M.Nagayama, M.Cohen: J. Electrochem. Soc.109 (1962) 781. 10.1149/1.2425555Search in Google Scholar

Received: 2016-12-13
Accepted: 2017-02-15
Published Online: 2017-05-04
Published in Print: 2017-05-15

© 2017, Carl Hanser Verlag, München

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