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Optical properties and weakening of elastic moduli with increasing glass transition temperature (Tg) in (80–x)TeO2-xBaO-20ZnO glasses

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Published/Copyright: August 7, 2015
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 106 Issue 8

Abstract

BaO addition to ternary (80–x)TeO2-20ZnO-xBaO (x = 0–20 mol.%) glasses resulted in a decrease in ultrasonic velocities and independent elastic moduli; this result indicated that the rigidity of the glass network weakened possibly because non-bridging oxygen increased. Thermal analysis results showed that glass transition temperature increased as BaO content increased because of the stabilizing effect of Ba2+ on the glass network. Additional analyses using bulk compression and ring deformation models revealed that the ratio between theoretical bulk modulus and experimental bulk modulus increased; this result indicated that the compression mechanism mainly involved isotropic ring compression. Furthermore, the increase in non-bridging oxygen formation with BaO addition caused a decrease in optical energy gap and an increase in refractive index. An increase in Urbach energy indicated that the degree of disorder in the glass system also increased.

Keywords: Elastic moduli; Tellurite glass; Ultrasonic velocity; Optical energy gap; Glass transition temperature
* Correspondence address, Dr. A. K. Yahya, Faculty of Applied Sciences, Universiti Teknologi Mara, 40450 Shah Alam, Selangor, Malaysia, Tel.: +60 3-55444613, Fax: +60 3-5544 4562, E-mail:

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Received: 2014-12-16
Accepted: 2015-03-16
Published Online: 2015-08-07
Published in Print: 2015-08-11

© 2015, Carl Hanser Verlag, München

Articles in the same Issue

  1. Contents
  2. Contents
  3. Original Contributions
  4. Effect of carbon on the solubility of nitrogen in slag
  5. Phase equilibria investigations and thermodynamic modeling of the PbO–Al2O3 system
  6. Experimental investigation of the phase equilibria in the Co–Fe–Ti ternary system
  7. Microstructural investigation on marforming and conventional cold deformation in Ni–Ti–Fe-based shape memory alloys
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  10. Effect of annealing and surfactant on photoluminescence of ZnS:O2− nanoparticles
  11. An experimental investigation into the effects of Cr2O3 and ZnO2 nanoparticles on the mechanical properties and durability of self-compacting mortar
  12. Optical properties and weakening of elastic moduli with increasing glass transition temperature (Tg) in (80–x)TeO2-xBaO-20ZnO glasses
  13. Simple fabrication of highly ordered anodic aluminum oxide (AAO) films
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  16. Manganese ferrite–graphene nanocomposite as a high-performance anode material for lithium-ion batteries
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https://doi.org/10.3139/146.111250
Keywords for this article
Elastic moduli; Tellurite glass; Ultrasonic velocity; Optical energy gap; Glass transition temperature

Articles in the same Issue

  1. Contents
  2. Contents
  3. Original Contributions
  4. Effect of carbon on the solubility of nitrogen in slag
  5. Phase equilibria investigations and thermodynamic modeling of the PbO–Al2O3 system
  6. Experimental investigation of the phase equilibria in the Co–Fe–Ti ternary system
  7. Microstructural investigation on marforming and conventional cold deformation in Ni–Ti–Fe-based shape memory alloys
  8. Modeling of hot deformation behavior with dynamic recrystallization in TC4 titanium alloy
  9. Powder metallurgy of high speed-steel produced by solid state sintering and heat treatment
  10. Effect of annealing and surfactant on photoluminescence of ZnS:O2− nanoparticles
  11. An experimental investigation into the effects of Cr2O3 and ZnO2 nanoparticles on the mechanical properties and durability of self-compacting mortar
  12. Optical properties and weakening of elastic moduli with increasing glass transition temperature (Tg) in (80–x)TeO2-xBaO-20ZnO glasses
  13. Simple fabrication of highly ordered anodic aluminum oxide (AAO) films
  14. Short Communications
  15. Launching particle to constant reinforcement ratio as a parameter for improving the nanoreinforcement distribution and tensile strength of aluminum nanometal matrix composites
  16. Manganese ferrite–graphene nanocomposite as a high-performance anode material for lithium-ion batteries
  17. Facile synthesis of TiO2 nanoplates decorated with Ag nanoparticles for electro-oxidation of hydrazine
  18. People
  19. People
  20. DGM News
  21. DGM News
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