Startseite Rapid synthesis of Mn3O4 powder from pyro-synthesis of ethylene glycol–metal nitrate precursor assisted by nitric acid
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Rapid synthesis of Mn3O4 powder from pyro-synthesis of ethylene glycol–metal nitrate precursor assisted by nitric acid

  • Cristiane de Abreu Dias , Marcos A. L. Nobre und Mauro C. Lopes
Veröffentlicht/Copyright: 12. März 2015
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International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 106 Heft 3

Abstract

The rapid synthesis of Mn3O4 powders by a two-step process of pyro-synthesis of ethylene glycol–metal nitrate precursor assisted by nitric acid is reported. A new strategy that accelerates the synthesis and allows obtaining highly pure crystalline Mn3O4 is discussed. The structural and morphological characteristics of the Mn3O4 powders are presented and discussed. The mechanism of formation of the Mn3O4 is also discussed. In comparison with other synthesis methods, the present method shows that the proposed route of synthesis has the main advantage of high production of the powder material in a very short time.

Keywords: Polyol; Nitric acid; Hausmannite
* Correspondence address, Dr. Cristiane de Abreu Dias, Technological Federal University of Paraná (UTFPR), Campus Dois Vizinhos Paraná, 85660-000, Brazil, Tel.: +554635368417, Fax: +554635368900, E-mail:

References

[1] S.Cimino, S.Colonna, S.De Rossi, M.Faticanti, L.Lisi, I.Pettiti, P.Porta: J. Catal.205 (2002) 309. 10.1006/jcat.2001.3441Suche in Google Scholar

[2] H.Dhaouadi, O.Ghodbane, F.Hosni, F.Touati: ISRN Spectroscopy2012 (2012) 1. 10.5402/2012/174952Suche in Google Scholar

[3] F.Nâamoune, B.Messaoudi, A.Kahoul, N.Cherchour, A.Pailleret, H.Takenouti: Ionics18 (2012) 365. 10.1007/s11581-011-0621-8Suche in Google Scholar

[4] D.P.Dubal, R.Holze: J. Power Sources238 (2013) 274. 10.1016/j.jpowsour.2013.01.198Suche in Google Scholar

[5] R.Song, S.Feng, H.Wang, C.Hou: J. Solid State Chem.202 (2013) 57. 10.1016/j.jssc.2013.03.015Suche in Google Scholar

[6] Z.Y.Tian, P.M.Kouotou, N.Bahlawane, P.H.T.Ngamou: J. Phys. Chem. C117 (2013) 6218. 10.1021/jp309224mSuche in Google Scholar

[7] Y.Li, H.Tan, X.Y.Yang, B.Goris, J.Verbeeck, S.Bals, P.Colson, R.Cloots, G.V.Tendeloo, B.L.Su: Small7 (2011) 475. 10.1002/smll.201001403Suche in Google Scholar

[8] A.Baykal, H.Kavas, Z.Durmus, M.Demir, S.Kazan, R.Topkaya, M.S.Toprak: Cent. Eur. J. Chem.8 (2010) 633. 10.2478/s11532-010-0037-8Suche in Google Scholar

[9] E.Finocchio, G.Busca: Catal. Today70 (2001) 213. 10.1016/S0920-5861(01)00419-9Suche in Google Scholar

[10] M.Anilkumar, V.Ravi: Mater. Res. Bull.40 (2005) 605. 10.1016/j.materresbull.2005.01.009Suche in Google Scholar

[11] S.K.Apte, S.D.Naik, R.S.Sonawane, B.B.Kale, N.Pavaskar, A.B.Mandale, B.K.Das: Mater. Res. Bull.41 (2006) 647. 10.1016/j.materresbull.2005.08.028Suche in Google Scholar

[12] D.P.Dubal, D.S.Dhawale, R.R.Salunkhea, S.M.Pawar, V.J.Fulari, C.D.Lokhande: J. Alloys Compd.484 (2009) 218. 10.1016/j.jallcom.2009.03.135Suche in Google Scholar

[13] M.Salavati-Niasari, F.Davar, M.Mazaheri: Polyhedron27 (2008) 3467. 10.1016/j.poly.2008.04.015Suche in Google Scholar

[14] F.Fievet, J.P.Largier, M.Figlarz: Mater. Res. Bull.32 (1989) 29. 10.1557/S0883769400060930Suche in Google Scholar

[15] C.Feldmann: Adv. Funct. Mater.13 (2003) 101. 10.1002/adfm.200301005Suche in Google Scholar

[16] J.Gim, V.Mathew, J.Lim, J.Song, S.Baek, J.Kang, D.Ahn, S.-J.Song, H.Yoon, J.Kim: Sci. Rep.2 (2012) 946. 10.1038/srep00946Suche in Google Scholar PubMed PubMed Central

[17] J.Kang, V.Mathew, J.Gim, S.Kim, J.Song, W.B.In, J.Han, J.H.Lee, J.Kim: Sci. Rep.4 (2014) 4047. 10.1038/srep04047Suche in Google Scholar PubMed PubMed Central

[18] J.Kang, S.Baek, V.Mathew, J.Gim, J.Song, H.Park, E.Chae, A.K.Rai, J.Kim: J. Mater. Chem.22 (2012) 20857. 10.1039/c2jm13689aSuche in Google Scholar

[19] J.Kang, J.Song, S.Kim, J.Gim, J.Jo, V.Mathew, J.Han, J.Kim: RSC Adv.3 (2013) 25640. 10.1039/c2ra21945jSuche in Google Scholar

[20] E.J.Mittemeijer, U.Welzel: Z. Kristallogr.223 (2008) 552. 10.1524/zkri.2008.1213Suche in Google Scholar

[21] T.Rhadfi, L.Sicard, F.Testard, O.Taché, A.Atlamsani, E.Anxolabéhère: J. Phys. Chem. C116 (2012) 5515. 10.1021/jp212454mSuche in Google Scholar

[22] M.Wekesa, M.D.J.Uddin, H.F.Sobhi: Int. J. Chem. Res.2 (2011) 34.Suche in Google Scholar

[23] F.Fiévet, R.Brayner, in: R.Brayner, F.Fiévet, T.Coradin (Eds.), Nanomaterials: A Danger or a Promise? Chap. 1, Springer, London (2013) 1. 10.1007/978.1-4471.4213.3_1Suche in Google Scholar

[24] L.Poul, S.Amar, N.Jouini, F.Fievet: J. Sol-Gel Sci. Technol.26 (2003) 261. 10.1023/A:1020763402390Suche in Google Scholar

[25] H.B.Park, Y.S.Hong, J.E.Yi, H.J.Kweon, S.J.Kim: Bull. Korean Chem. Soc.18 (1997) 612.Suche in Google Scholar

[26] V.Prevot, C.Forano, J.P.Besse: Chem. Mater.17 (2005) 6695. 10.1021/cm050581xSuche in Google Scholar

[27] H.M.Ali, A.Briggs: Appl. Therm. Eng.49 (2012) 9. 10.1016/j.applthermaleng.2011.08.017Suche in Google Scholar

[28] T.Rhadfi, L.Sicard, F.Testard, O.Taché, A.Atlamsani, E.Anxolabéhère: J. Phys. Chem. C116 (2012) 5515. 10.1021/jp212454mSuche in Google Scholar

[29] D.Larcher, G.Sudant, R.Patrice, J.-M.Tarascon: Chem. Mater.15 (2003) 3543. 10.1021/cm030048mSuche in Google Scholar

[30] M.Gunay, H.Sozeri, A.Baykal: J. Supercond. Novel Magn.25 (2012) 1929. 10.1007/s10948-012-1451-2Suche in Google Scholar

[31] Z.-H.Wang, L.-X.Yuan, Q.-G.Shao, F.Huang, Y.-H.Huang: Mater. Lett.80 (2012) 110. 10.1016/j.matlet.2011.09.046Suche in Google Scholar

[32] K.V.Sankar, D.Kalpana, R.K.Selvan: J. Appl. Electrochem.42 (2012) 463. 10.1007/s10800-012-0424-2Suche in Google Scholar

[33] F.Davar, M.Salavati-Niasari, N.Mir, K.Saberyan, M.Monemzadeh, E.Ahmadi: Polyhedron29 (2010) 1747. 10.1016/j.poly.2010.02.026Suche in Google Scholar

[34] Y.-F.Han, F.Chen, Z.-Y.Zhong, K.Ramesh, E.Widjaja, L.-W.Chen: Catal. Commun.7 (2006) 739. 10.1016/j.catcom.2006.08.006Suche in Google Scholar

[35] J.Gao, M.A.Lowe, H.D.Abruna: Chem. Mater.23 (2011) 3223. 10.1021/cm200975xSuche in Google Scholar

[36] R.Mehdizadeh, L.A.Saghatforoush, S.Sanati: Superlattices Microstruct.52 (2012) 92. 10.1016/j.spmi.2012.03.017Suche in Google Scholar

[37] S.Xing, Z.Zhou, Z.Ma, Y.Wu: Mater. Lett.65 (2011) 517. 10.1016/j.matlet.2010.10.082Suche in Google Scholar

[38] H.Dhaouadi, A.Madani, F.Touati: Mater. Lett.64 (2010) 2395. 10.1016/j.matlet.2010.07.036Suche in Google Scholar

[39] K.A.M.Ahmed, Q.Zeng, K.Wu, K.Huang: J. Solid State Chem.183 (2010) 744. 10.1016/j.jssc.2010.01.015Suche in Google Scholar

[40] J.Du, Y.Gao, L.Chai, G.Zou, Y.Li, Y.Qian: Nanotechnology17 (2006) 4923. 10.1088/0957-4484/17/12/004Suche in Google Scholar

[41] M.Ishii, M.Nakahira, T.Yamanaka: Solid State Commun.11 (1972) 209. 10.1016/0038-1098(72)91162-3Suche in Google Scholar

[42] Z.Durmus, M.Tomas, A.Baykal, H.Kavas, T. GürkaynakAltnçekiçc, M.S.Toprak: Russ. J. Inorg. Chem.55 (2010) 1947. 10.1134/S0036023610120211Suche in Google Scholar

[43] Y.C.Zhang, T.Qiao, X.Y.Hu, W.D.Zhou: J. Cryst. Growth280 (2005) 652. 10.1016/j.jcrysgro.2005.02.060Suche in Google Scholar

[44] C.Matranga, L.Chen, M.Smith, E.Bittner, J.K.Johnson, B.Bockrath: J. Phys. Chem. B107 (2003) 12930. 10.1021/jp0364654Suche in Google Scholar

[45] S.Ashoka, P.Chithaiah, C.N.Tharamani, G.T.Chandrappa: J. Exp. Nanosci.5 (2010) 285. 10.1080/17458080903495003Suche in Google Scholar

[46] L.B.McCusker, F.Liebau, G.Engelhardt: Pure Appl. Chem.73 (2001) 381. 10.1351/pac200173020381Suche in Google Scholar

[47] Y.Ren, Z.Ma, P.G.Bruce: Chem. Soc. Rev.41 (2012) 4909. 10.1039/c2cs35086fSuche in Google Scholar PubMed

[48] J.Trambukis, Z.A.Munir: J. Am. Ceram. Soc.73 (1990) 1240. 10.1111/j.1151-2916.1990.tb05186.xSuche in Google Scholar

[49] L.Sicard, J.M.Meins, C.Méthivier, F.Herbst, S.Ammar: J. Magn. Magn. Mater.322 (2010) 2634. 10.1016/j.jmmm.2010.03.016Suche in Google Scholar

[50] Y.Zhao, C.Li, F.Li, Z.Shi, S.Feng: Dalton Trans.40 (2011) 583. 10.1039/c0dt01198cSuche in Google Scholar PubMed

Received: 2014-05-01
Accepted: 2014-11-04
Published Online: 2015-03-12
Published in Print: 2015-03-11

© 2015, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Phase equilibria studies of the “MnO”–Al2O3–SiO2 system in equilibrium with metallic alloy. Part 2: phase equilibria
  5. X-ray stress measurement from an imperfect Debye–Scherrer ring
  6. Effect of heat treatment on the microstructure and tensile properties of Ti-5Al-3Zr-4Mo-3V alloy
  7. Quantification of roping in aluminium sheet alloys for car body applications by combining 3D surface measurements with Fourier analysis
  8. Dissimilar friction stir welding between polycarbonate and AA 7075 aluminum alloy
  9. Evaluation of the corrosion resistance of plasma nitrided austenitic stainless steel
  10. Corrosion performance and microstructural response of A380 matrix alloy reinforced with sol–gel TiO2-coated SiC particles: a perspective on previous studies
  11. Role of chloride in the electrochemical behaviour of AZ31B Mg alloy
  12. Implications of solute super-saturation in growth of vaporisation-induced recrystallised grains during heat treatment in Ni-base superalloys
  13. Rapid synthesis of Mn3O4 powder from pyro-synthesis of ethylene glycol–metal nitrate precursor assisted by nitric acid
  14. Production of bioactive glass-derived scaffolds using citric acid porogen
  15. Short Communications
  16. Microstructure and mechanical properties of deformed Mg–Mn–Sn alloys
  17. Fast microwave synthesis and characterization of MgTi2O5
  18. Time dependent synthesis of crystalline Bi2S3 and its application as a sensitizer in SnO2 based solar cells
  19. Synthesis of cobalt-doped CdS (CdS:Co) by a simple and rapid microwave activated method and investigating optical properties
  20. People
  21. In Memoriam Volker Schumacher
  22. DGM News
  23. DGM News
https://doi.org/10.3139/146.111176
Schlagwörter für diesen Artikel
Polyol; Nitric acid; Hausmannite

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Phase equilibria studies of the “MnO”–Al2O3–SiO2 system in equilibrium with metallic alloy. Part 2: phase equilibria
  5. X-ray stress measurement from an imperfect Debye–Scherrer ring
  6. Effect of heat treatment on the microstructure and tensile properties of Ti-5Al-3Zr-4Mo-3V alloy
  7. Quantification of roping in aluminium sheet alloys for car body applications by combining 3D surface measurements with Fourier analysis
  8. Dissimilar friction stir welding between polycarbonate and AA 7075 aluminum alloy
  9. Evaluation of the corrosion resistance of plasma nitrided austenitic stainless steel
  10. Corrosion performance and microstructural response of A380 matrix alloy reinforced with sol–gel TiO2-coated SiC particles: a perspective on previous studies
  11. Role of chloride in the electrochemical behaviour of AZ31B Mg alloy
  12. Implications of solute super-saturation in growth of vaporisation-induced recrystallised grains during heat treatment in Ni-base superalloys
  13. Rapid synthesis of Mn3O4 powder from pyro-synthesis of ethylene glycol–metal nitrate precursor assisted by nitric acid
  14. Production of bioactive glass-derived scaffolds using citric acid porogen
  15. Short Communications
  16. Microstructure and mechanical properties of deformed Mg–Mn–Sn alloys
  17. Fast microwave synthesis and characterization of MgTi2O5
  18. Time dependent synthesis of crystalline Bi2S3 and its application as a sensitizer in SnO2 based solar cells
  19. Synthesis of cobalt-doped CdS (CdS:Co) by a simple and rapid microwave activated method and investigating optical properties
  20. People
  21. In Memoriam Volker Schumacher
  22. DGM News
  23. DGM News
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