Startseite Technik Effects of molecular polarity on nanofluidic behavior in a silicalite
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Effects of molecular polarity on nanofluidic behavior in a silicalite

  • Weiyi Lu , Taewan Kim , Cang Zhao und Yu Qiao
Veröffentlicht/Copyright: 16. August 2013
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International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 104 Heft 6

Abstract

While “like attracts like” is common sense for large surfaces, here we show that in a nanopore the effective solid–liquid interfacial tension can be quite independent of the liquid polartiy. Moreover, as the liquid molecules and ions are confined, their behavior can be either reversible or irreversible, depending on the liquid composition. These unique phenomena can be attributed to the confinement effects and the absence of bulk liquid phase in the nanoenvironment.

Keywords: Polarity; Nanopore; Interfacial tension
* Correspondence address, Professor Yu Qiao, 9500 Gilman Drive, La Jolla, CA 92093-0085, USA, Tel.: +1-858-534-3388, Fax: +1-858-534-1310, E-mail:

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Received: 2012-6-4
Accepted: 2012-9-19
Published Online: 2013-08-16
Published in Print: 2013-06-13

© 2013, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Analysis of V(C, N) nanoparticles in a medium carbon bainitic microalloyed steel and their influence on strengthening
  5. Experimental and numerical investigation of the microstructural influence on the deformation behavior of notched cp-titanium specimens
  6. Interfacial study of Si–Ge multilayers grown using ultrahigh-vacuum chemical vapor deposition
  7. Age-hardenability related to precipitation and lamellar-forming grain boundary reaction in dental low-carat gold alloy
  8. Calorimetric study and phase diagram investigation of the Au–Ga system
  9. Roles of iron and copper salts for controlling morphology of silver nanostructures
  10. Hydrothermal synthesis of nanowires, nanobelts, and nanotubes of vanadium oxides from one reaction system
  11. Facile synthesis of ultrafine TiO2 nanowires with large aspect ratio and its photoactivity
  12. Kinetics of thermal dehydration of sol-gel derived MgO–ZrO2 composite hydrogel
  13. Synthesis and reaction process of β-Si3N4 by means of carbothermal nitridation of serpentine
  14. Analysis of size effect and anisotropy of 6H – SiC thermal conductivity
  15. Effects of molecular polarity on nanofluidic behavior in a silicalite
  16. Vertical static compression performance of honeycomb paperboard
  17. Short Communications
  18. Synthesis of phase purity V2AlC via self-propagation high temperature sintering
  19. Densification and microwave properties of low-temperature co-fired CaO–B2O3–SiO2 glass-ceramic with La–B–Si additions
  20. DGM News
  21. DGM News
https://doi.org/10.3139/146.110900
Schlagwörter für diesen Artikel
Polarity; Nanopore; Interfacial tension

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Analysis of V(C, N) nanoparticles in a medium carbon bainitic microalloyed steel and their influence on strengthening
  5. Experimental and numerical investigation of the microstructural influence on the deformation behavior of notched cp-titanium specimens
  6. Interfacial study of Si–Ge multilayers grown using ultrahigh-vacuum chemical vapor deposition
  7. Age-hardenability related to precipitation and lamellar-forming grain boundary reaction in dental low-carat gold alloy
  8. Calorimetric study and phase diagram investigation of the Au–Ga system
  9. Roles of iron and copper salts for controlling morphology of silver nanostructures
  10. Hydrothermal synthesis of nanowires, nanobelts, and nanotubes of vanadium oxides from one reaction system
  11. Facile synthesis of ultrafine TiO2 nanowires with large aspect ratio and its photoactivity
  12. Kinetics of thermal dehydration of sol-gel derived MgO–ZrO2 composite hydrogel
  13. Synthesis and reaction process of β-Si3N4 by means of carbothermal nitridation of serpentine
  14. Analysis of size effect and anisotropy of 6H – SiC thermal conductivity
  15. Effects of molecular polarity on nanofluidic behavior in a silicalite
  16. Vertical static compression performance of honeycomb paperboard
  17. Short Communications
  18. Synthesis of phase purity V2AlC via self-propagation high temperature sintering
  19. Densification and microwave properties of low-temperature co-fired CaO–B2O3–SiO2 glass-ceramic with La–B–Si additions
  20. DGM News
  21. DGM News
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