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Experimental investigation of the Zn–Fe–V system at 450°C

  • Changjun Wu , Xuping Su , Daniel Liu , Xinming Wang , Fucheng Yin , Zhongxi Zhu und Zhi Li
Veröffentlicht/Copyright: 11. Juni 2013
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International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 101 Heft 12

Abstract

The 450°C isothermal section of the ZnüFeüV ternary phase diagram has been determined experimentally using X-ray diffraction and scanning electron microscopy coupled with energy/wave dispersive spectroscopy. A new ternary compound T, containing 1.4 to 4.5 at.% V, 5.6 to 15.5 at.% Fe and 82.3 to 92.2 at.% Zn, was positively identified for the first time in this study. The existence of the rphase, together with two ZnüV compounds, VZn3 and V4Zn5, at 450°C has been confirmed. Fe has no detectable solubility in ZnüV compounds. But it was proved that about 3.0 at.% Zn can dissolve into α-V at 450°C. Experimental results indicated that the maximum solubility of V in d, γ1, and γ was 0.5 at.%, 1.3 at.% and 1.8 at.% respectively, whereas that in ζ was less than 0.2 at.%.

Keywords: Zn-Fe-V; Phase diagram; Intermetallic compound; Thermodynamic equilibrium
* Correspondence address, Prof. Xuping Su, School of Materials Science and Engineering, Changzhou University, Changzhou 213164, Jiangsu, P. R. China. Tel.: +86 519 8633 0982, Fax: +86 519 8633 0095. E-mail:

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Received: 2009-10-26
Accepted: 2010-10-4
Published Online: 2013-06-11
Published in Print: 2010-12-01

© 2010, Carl Hanser Verlag, München

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https://doi.org/10.3139/146.110433
Schlagwörter für diesen Artikel
Zn-Fe-V; Phase diagram; Intermetallic compound; Thermodynamic equilibrium

Artikel in diesem Heft

  1. Basic
  2. High-temperature in-situ microscopy during stress-induced phase transformations in Co49Ni21Ga30 shape memory alloy single crystals
  3. Contents
  4. contents
  5. Editorial
  6. Editorial December 2010
  7. Basic
  8. Atomic mobilities and diffusivities in the fcc, L12 and B2 phases of the Ni-Al system
  9. Experimental investigation of the Zn–Fe–V system at 450°C
  10. Time resolved X-ray imaging of eutectic cellular patterns evolving during solidification of ternary Al–Cu–Ag alloys
  11. Reassessment of the Mg–Ge binary system using CALPHAD supported by first-principles calculation
  12. A quantitative modeling of the unloading behavior of metals during a tensile test
  13. A technique for diameter enlargement in SiC crystal growth
  14. Applied
  15. Thermal and chemical stability of Cr2AlC in contact with α-Al2O3 and NiAl
  16. Microstructure and mechanical properties of Zn25Al3Cu based composites with large Al2O3 particles at room and elevated temperatures
  17. An investigation on Incoloy800-SS304 clad plate by explosive welding
  18. Effect of grain boundary precipitates on vibration damping of FeüCrüMgüAl/Si alloy
  19. Adsorption of metal ions on magnetic carbon nanomaterials bearing chitosan-functionalized silica
  20. Tensile and in-vitro degradation study of electro spun fibrous mat produced from eri silk fibroin
  21. Study of the influence of UV-irradiation on the photodegradation of plasticized poly(para-tert-butylstyrene) films
  22. Enhanced photocatalytic activity of beryllium doped titania in visible light on the degradation of methyl orange dye
  23. Progress in chemistry modelling for vapour and aerosol transport analyses
  24. DGM News
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