Synthesis and characterization of nanostructured Cu/ZnO/Al2O3 from lyotropic liquid crystalline templates
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Xiaodong Wang
Abstract
The hexagonal lyotropic liquid crystalline phases of nonionic surfactants AEO-9 were used to template directly the fabrication of nanostructured Cu/ZnO/Al2O3 oxides. The reaction between metal precursors and alkaline reacting substance dissolved within the aqueous domains of the liquid crystalline templates generated nanostructured oxides. Low-angle X-ray diffraction and transmission election microscopy characterization reveals the product as a hexagonal array of cylindrical pores with pore-to-pore separation of ca. 6.3 nm. Possessing ordered nanochannels, Cu/ZnO/Al2O3 oxides could find more potential application in catalysis.
References
[1] R.Q.Yang, X.C.Yu, Y.Zhang, W.Z.Li, N.Tsubaki: Fuel87 (2008) 443. 10.1016/j.fuel.2007.06.020Suche in Google Scholar
[2] T.Shishido, M.Yamamoto, D.L.Li, Y.Tian, H.Morioka, M.Honda: Appl. Catal. A-Gen303 (2006) 62. 10.1016/j.apcata.2006.01.031Suche in Google Scholar
[3] L.C.Wang, Y.M.Liu, M.Chen, Y.Cao, H.Y.He, G.S.Wu, W.L.Dai, K.N.Fan: J. Catal.246 (2007) 193. 10.1016/j.jcat.2006.12.006Suche in Google Scholar
[4] J.Bao, Z.L.Liu, Y.Zhang, N.Tsubaki: Catal. Commun.9 (2008) 913. 10.1016/j.catcom.2007.09.034Suche in Google Scholar
[5] S.Michael, K.Karel, L.Juergen: US Patent 4535071.Suche in Google Scholar
[6] R.J.Guo, B.Q.Zhang, Y.Sun, X.F.Liu: Progress in Chemistry19 (2007) 1695.Suche in Google Scholar
[7] C.T.Kresge, M.E.Leonowicz, W.J.Roth, J.C.Vartuli, J.S.Beck: Nature359 (1992) 710.Suche in Google Scholar
[8] P.V.Braun, P.Osenar, S.I.Stupp: Nature380 (1996) 325.Suche in Google Scholar
[9] G.S.Attard, C.G.Göltner, J.M.Corker, S.Henke, R.H.Templer: Angew. Chem. Int. Ed. Engl.36 (1997) 1315.Suche in Google Scholar
[10] G.S.Attard, S.A.A.Leclerc, S.Maniguet, A.E.Russell, I.Nandhakumar, P.N.Bartlettet: Chem. Mater.13 (2001) 1444. 10.1021/cm000850dSuche in Google Scholar
[11] G.S.Attard, S.A.A.Leclerc, S.Maniguet, A.E.Russell, I.Nandhakumar, B.R.Gollas, P.N.Bartlett: Microporous Mesoporous Mat.44–45 (2001) 159.Suche in Google Scholar
[12] R.J.Guo, B.Q.Zhang, X.F.Liu: Mater. Reser. Bull.43 (2008) 191. 10.1016/j.materresbull.2007.02.029Suche in Google Scholar
[13] R.J.Guo, B.Q.Zhang, X.F.Liu: Appl. Surf. Sci.254 (2007) 538. 10.1016/j.apsusc.2007.06.054Suche in Google Scholar
[14] B.Q.Zhang, R.J.Guo, X.F.Liu: Appl. Surf. Sci.254 (2008) 5394. 10.1016/j.apsusc.2008.02.071Suche in Google Scholar
[15] H.M.Luo, J.F.Zhang, Y.S.Yan: Chem. Mater.15 (2003) 3769. 10.1021/cm0345218Suche in Google Scholar
© 2010, Carl Hanser Verlag, München
Artikel in diesem Heft
- Contents
- Contents
- Editorial
- Hans-Peter Degischer – 65th birthday
- Basic
- X-ray and neutron imaging – Complementary techniques for materials science and engineering
- Fast in-situ X-ray micro tomography characterisation of microstructural evolution and strain-induced damage in alloys at various temperatures
- Thermo-kinetic computer simulation of differential scanning calorimetry curves of AlMgSi alloys
- Influence of stacking fault energy and alloying on stage V hardening of HPT-deformed materials
- Thermo-physical properties of silver/carbon fibre composites
- Influence of reinforcement contiguity on the thermal expansion of alumina particle reinforced aluminium composites
- A continuum based microstructure model of inhomogeneous hardening and recovery as a pre-stage of recrystallization nucleation
- Applied
- Metal foams – towards microcellular materials
- Gigacycle fatigue response of tool steels produced by powder metallurgy compared to ingot metallurgy tool steels
- Characterization of the microstructure and damage mechanisms in a Ti6Al4V alloy modified with 1 wt.% B
- Structural and age hardening characteristics of near eutectic Al–Si alloys
- Stress-corrosion cracking susceptibility of AZ31 alloy after varied heat-treatment in 3.5 wt.% NaCl solution
- Tensile deformation behavior of AA5083-H111 at cold and warm temperatures
- Experimental investigation of thermal fatigue behaviour of header tube to stub welded joint in power plants
- Synthesis and characterization of nanostructured Cu/ZnO/Al2O3 from lyotropic liquid crystalline templates
- DGM News
- Personal
Artikel in diesem Heft
- Contents
- Contents
- Editorial
- Hans-Peter Degischer – 65th birthday
- Basic
- X-ray and neutron imaging – Complementary techniques for materials science and engineering
- Fast in-situ X-ray micro tomography characterisation of microstructural evolution and strain-induced damage in alloys at various temperatures
- Thermo-kinetic computer simulation of differential scanning calorimetry curves of AlMgSi alloys
- Influence of stacking fault energy and alloying on stage V hardening of HPT-deformed materials
- Thermo-physical properties of silver/carbon fibre composites
- Influence of reinforcement contiguity on the thermal expansion of alumina particle reinforced aluminium composites
- A continuum based microstructure model of inhomogeneous hardening and recovery as a pre-stage of recrystallization nucleation
- Applied
- Metal foams – towards microcellular materials
- Gigacycle fatigue response of tool steels produced by powder metallurgy compared to ingot metallurgy tool steels
- Characterization of the microstructure and damage mechanisms in a Ti6Al4V alloy modified with 1 wt.% B
- Structural and age hardening characteristics of near eutectic Al–Si alloys
- Stress-corrosion cracking susceptibility of AZ31 alloy after varied heat-treatment in 3.5 wt.% NaCl solution
- Tensile deformation behavior of AA5083-H111 at cold and warm temperatures
- Experimental investigation of thermal fatigue behaviour of header tube to stub welded joint in power plants
- Synthesis and characterization of nanostructured Cu/ZnO/Al2O3 from lyotropic liquid crystalline templates
- DGM News
- Personal
