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Phase equilibria and thermal analysis in the Fe–Mn–Ni system

  • Lijun Zhang , Yong Du , Honghui Xu , Shuhong Liu , Yajun Liu , Feng Zheng , Nathalie Dupin , Huaiying Zhou and Chengying Tang
Published/Copyright: June 11, 2013
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 100 Issue 2

Abstract

Based on the critical review of the experimental data available in the literature, 7 decisive ternary alloys were prepared. New phase transition temperatures and phase equilibria at 800°C in the Fe – Mn – Ni system were measured. An effective method to accurately determine phase transition temperatures from differential thermal analysis curves with overlapped peaks and nonlevel baselines within a narrow temperature range was developed. A massive transformation was observed in one quenched Fe-rich alloy. In order to make the fcc_A1 phase always in the fully disordered state in the ternary system, the effect of the binary reciprocal parameter on the Gibbs energy of ternary ordered L12 phase was considered. It was found that the introduction of only one parameter could describe all reliable experimental data in the Fe – Mn – Ni system satisfactorily. The presently obtained parameters were successfully applied in two practical cases.

Keywords: Fe – Mn – Ni phase diagram; Massive transformation; Differential thermal analysis; Thermodynamic calculation; Order/disorder transformations
* Correspondence address, Professor Dr. Yong Du, State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083, P.R. China, Tel.: +86 731 8836 213, Fax: +86 731 8710 855, E-mail:

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Received: 2008-9-17
Accepted: 2008-11-13
Published Online: 2013-06-11
Published in Print: 2009-02-01

© 2009, Carl Hanser Verlag, München

Articles in the same Issue

  1. Contents
  2. Contents
  3. Feature
  4. Materials constitution and computational thermodynamics in the context of 100 years of IJMR – Zeitschrift für Metallkunde
  5. Upgrading CALPHAD to microstructure simulation: the phase-field method
  6. Prediction, determination and validation of phase diagrams via the global study of energy landscapes
  7. Alloy development using modern tools
  8. Phase equilibria and thermal analysis in the Fe–Mn–Ni system
  9. Integrated approach to thermodynamics, phase relations, liquid densities and solidification microstructures in the Al–Bi–Cu system
  10. Formation of clathrates Ba–M–Ge(M = Mn, Fe, Co)
  11. New paradigm of a metastable phase diagram presenting structural transformations induced by annealing of Si–C–N amorphous ceramics derived from polymer precursors
  12. Basic
  13. Thermodynamic assessment of the Ce–Si, Y–Si, Mg–Ce–Si and Mg–Y–Si systems
  14. Thermodynamic re-assessment of the Ti–Al–Nb system
  15. Effect of varying oxygen partial pressure on the properties of reactively evaporated zinc aluminate thin films
  16. Applied
  17. Matrix induced synthesis of Y3Al5O12: Ce phosphor through the Pechini method
  18. Microstructure and room temperature compressive properties of holmium doped DS NiAl-Cr(Mo)-Hf eutectic alloy
  19. Evaporation mechanism of aluminum during electron beam cold hearth melting of Ti64 alloy
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  21. DGM News
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https://doi.org/10.3139/146.110002
Keywords for this article
Fe – Mn – Ni phase diagram; Massive transformation; Differential thermal analysis; Thermodynamic calculation; Order/disorder transformations

Articles in the same Issue

  1. Contents
  2. Contents
  3. Feature
  4. Materials constitution and computational thermodynamics in the context of 100 years of IJMR – Zeitschrift für Metallkunde
  5. Upgrading CALPHAD to microstructure simulation: the phase-field method
  6. Prediction, determination and validation of phase diagrams via the global study of energy landscapes
  7. Alloy development using modern tools
  8. Phase equilibria and thermal analysis in the Fe–Mn–Ni system
  9. Integrated approach to thermodynamics, phase relations, liquid densities and solidification microstructures in the Al–Bi–Cu system
  10. Formation of clathrates Ba–M–Ge(M = Mn, Fe, Co)
  11. New paradigm of a metastable phase diagram presenting structural transformations induced by annealing of Si–C–N amorphous ceramics derived from polymer precursors
  12. Basic
  13. Thermodynamic assessment of the Ce–Si, Y–Si, Mg–Ce–Si and Mg–Y–Si systems
  14. Thermodynamic re-assessment of the Ti–Al–Nb system
  15. Effect of varying oxygen partial pressure on the properties of reactively evaporated zinc aluminate thin films
  16. Applied
  17. Matrix induced synthesis of Y3Al5O12: Ce phosphor through the Pechini method
  18. Microstructure and room temperature compressive properties of holmium doped DS NiAl-Cr(Mo)-Hf eutectic alloy
  19. Evaporation mechanism of aluminum during electron beam cold hearth melting of Ti64 alloy
  20. 560°C isothermal section of the Zn–Fe–Ni–Si quaternary system at the zinc-rich corner
  21. DGM News
  22. Personal
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