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Surface Characterization of Textiles for Optimization of Functional Polymeric Nano-Capsule Attachment

  • Wazir Akbar und G. Bahar Basim
Veröffentlicht/Copyright: 1. Oktober 2019
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Tenside Surfactants Detergents
Aus der Zeitschrift Tenside Surfactants Detergents Band 56 Heft 5

Abstract

Surface properties of textiles play an essential role in their functionalization with micro/nanometer-sized polymeric capsules containing active agents that can provide controlled release. The attached capsules provide additional functionalities such as deodorizing, anti-microbial, or insect repellant properties. The efficiency of capsule attachment depends on the interaction between the selected textile material and the type of capsules. In this study, surface characteristics of the textiles were modified systematically to enhance the attachment of polyethyleneglycol based polymeric capsules. In the first phase of textile selection, four different textile materials, composed of 100% single fiber, were analyzed. Among the analyzed textile samples, cotton and polyester blends were investigated in detail due to their higher hydrophobicity, less negative zeta potential after treatment with finishing solution and broad applicability in sports outfits. In the second phase, statistical design of experiment (DoE) approach was used to have a deeper understanding of the processing factors such as the silicon (hydrophobic component) concentration in the finishing solution and the cotton/polyester blend ratio. An optimal textile was designed based on maximizing the capsule attachment on the cotton fibers woven on top and polyester at the bottom for providing strength and ease of ironing. The selected blend, treated with the required silicon concentration in the finishing solution, retained the highest amount of polymeric capsules containing eucalyptus oil for tick/insect repellency.

Kurzfassung

Die Oberflächeneigenschaften von Textilien spielen eine wesentliche Rolle bei ihrer Funktionalisierung mit mikro- und nanometergroßen Polymerkapseln, die eine kontrollierte Freiset-zung von Wirkstoffen ermöglichen. Die auf die Textiloberfläche aufgebrachten Kapseln bieten zusätzliche Funktionen wie desodorierende, antimikrobielle oder insektenabweisende Eigenschaften. Die Effizienz der Kapselbindung hängt von der Wechselwirkung zwischen dem ausgewählten Textilmaterial und der Art der Kapseln ab. In dieser Untersuchung wurden die Oberflächeneigenschaften der Textilien systematisch modifiziert, um die Bindung von Kapseln aus Polyethylenglykol zu verbessern. In der ersten Phase der Textilauswahl wurden vier verschiedene Textilmaterialien aus 100% Einzelfaser analysiert. Unter den untersuchten Textilproben wurden Baumwoll- und Polyestermischungen aufgrund ihrer höheren Hydrophobizität, ihres geringeren negativen Zeta-Potentials nach der Behandlung mit einer Ausrüstungslösung und ihrer breiten Anwendbarkeit in Sportbekleidung eingehend untersucht. In der zweiten Phase wurde ein statistischer Versuchsplan (design of experiment = DoE) verwendet, um Verfahrensfaktoren wie die Siliziumkonzentration (hydrophobe Komponente) in der Ausrüstungslösung und das Mischungsverhältnis von Baumwolle zu Polyester besser zu verstehen. Ein optimales Textil wurde entworfen, in dem die Kapselbindung auf den Baumwollfasern, die oben gewebt sind, und Polyesterfasern, die unten gewebt sind, maximiert wurde, um so Festigkeit und Leichtigkeit beim Bügeln zu gewährleisten. Auf der Oberfläche der ausgewählten Mischung, die mit der erforderlichen Siliziumkonzentration in der Ausrüstungslösung behandelt wurde, wurde die größte Menge an Polymerkapseln mit Eukalyptusöl zur Zecken- und Insektenabwehr bestimmt.

Key words: Textile surface modification; micro/nano-capsules; design of experiment; polymeric capsule attachment on textiles
Stichwörter: Textiloberflächenmodifizierung; Mikro- und Nanokapseln; statistische Versuchsplanung; Polymerkapselbindung auf Textilien
∗Mr. Wazir Akbar, Department of Mechanical Engineering, Ozyegin University, Istanbul, Turkey 34794, E-Mail:

Wazir Akbar received his BSc. degree from mechanical engineering department of UET Peshawar, Pakistan in 2013 and MSc. degree from Ozyegin University, Istanbul in 2016. His MSc thesis focused on developing functional particles and systems for textile applications. His research interests include materials and surface characterization and computational fluid mechanics. He is currently a PhD student at the department of mechanical engineering at the Ozyegin University and working on micro-modelling of nanoparticle slurry systems for chemical mechanical planarization applications.

Dr. Bahar Basim's research experience and interests extend within the applications nanotechnology in manufacturing. She received her PhD from the University of Florida Materials Science and Engineering Department in 2002 with specializations in particle science and technology and electronic materials. Her doctorate dissertation was supported by the National Science Foundation Engineering Research Center for Particle Science and Technology and focused on slurry design for chemical mechanical planarization (CMP) process. After graduation, she worked as a senior process engineer for Intel Corporation on 90 nm node flash development in Santa Clara CA and joined Texas Instruments Incorporated in Dallas TX, where she contributed to CMP process development, non-volatile memory product development, yield enhancement and process integration of 90/65-nm CMOS, flash and ferroelectric memory device manufacturing as a Process Integration Engineer with the Analog Technology Development Group. She is a Member of Technical Staff at TI since 2007. Dr. In September 2009 Dr. Basim joined academia as a founder faculty of a Private University in Europe. She has numerous granted US patents and international patent applications on nanotechnology applications in microelectronics, coatings and surface science in addition to many technical papers, books and presentations. She is the organizing member of the Electrochemical Society CMP symposia since 2010 and a referee for many technical journals on microelectronics manufacturing. She has founded the BioCapSOL Start-up Company in Europe in 2016. Dr. Basim is affiliated with the University of Texas at Dallas Natural Science and Research Laboratory and continuing her research on CMP, thin films, interfaces and implementation of CMP process on 3-D objects as an alternative nano-structuring technique.

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Received: 2019-07-07
Accepted: 2019-07-21
Published Online: 2019-10-01
Published in Print: 2019-09-16

© 2019, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Microbial Synthesis
  4. Production of Non-Toxic Biosurfactant – Surfactin – Through Microbial Fermentation of Biomass Hydrolysates for Industrial and Environmental Applications
  5. Characterisation Novel Biosurfactants
  6. Structures and Properties of Sophorolipids in Dependence of Microbial Strain, Lipid Substrate and Post-Modification
  7. Personal Care/Cleansing
  8. Amino-Acid Surfactants in Personal Cleansing (Review)
  9. Toward Milder Personal Care Cleansing Products: Fast ex vivo Screening of Irritating Effects of Surfactants on Skin Using Raman Microscopy
  10. Textile Surface Modification
  11. Surface Characterization of Textiles for Optimization of Functional Polymeric Nano-Capsule Attachment
  12. Enhanced Oil Recovery and Oil-Spill Dispersants
  13. Pseudo-Gemini Biosurfactants with CO2 Switchability for Enhanced Oil Recovery (EOR)
  14. Hydrophilic-Lipophilic-Difference (HLD) Guided Formulation of Oil Spill Dispersants with Biobased Surfactants
  15. Mineral Processing
  16. Floatability of Chalcopyrite by Glycolipid Biosurfactants as Compared to Traditional Thiol Surfactants
  17. Antimicrobial Properties
  18. Stability of Emulsions and Nanoemulsions Stabilized with Biosurfactants, and their Antimicrobial Performance against Escherichia coli O157:H7 and Listeria monocytogenes
https://doi.org/10.3139/113.110645
Schlagwörter für diesen Artikel
Textile surface modification; micro/nano-capsules; design of experiment; polymeric capsule attachment on textiles

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Microbial Synthesis
  4. Production of Non-Toxic Biosurfactant – Surfactin – Through Microbial Fermentation of Biomass Hydrolysates for Industrial and Environmental Applications
  5. Characterisation Novel Biosurfactants
  6. Structures and Properties of Sophorolipids in Dependence of Microbial Strain, Lipid Substrate and Post-Modification
  7. Personal Care/Cleansing
  8. Amino-Acid Surfactants in Personal Cleansing (Review)
  9. Toward Milder Personal Care Cleansing Products: Fast ex vivo Screening of Irritating Effects of Surfactants on Skin Using Raman Microscopy
  10. Textile Surface Modification
  11. Surface Characterization of Textiles for Optimization of Functional Polymeric Nano-Capsule Attachment
  12. Enhanced Oil Recovery and Oil-Spill Dispersants
  13. Pseudo-Gemini Biosurfactants with CO2 Switchability for Enhanced Oil Recovery (EOR)
  14. Hydrophilic-Lipophilic-Difference (HLD) Guided Formulation of Oil Spill Dispersants with Biobased Surfactants
  15. Mineral Processing
  16. Floatability of Chalcopyrite by Glycolipid Biosurfactants as Compared to Traditional Thiol Surfactants
  17. Antimicrobial Properties
  18. Stability of Emulsions and Nanoemulsions Stabilized with Biosurfactants, and their Antimicrobial Performance against Escherichia coli O157:H7 and Listeria monocytogenes
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