Startseite Effects of hydrostaticity and Mn-substitution on dolomite stability at high pressure
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Effects of hydrostaticity and Mn-substitution on dolomite stability at high pressure

  • Faxiang Wang , Chaoshuai Zhao , Liangxu Xu und Jin Liu ORCID logo
Veröffentlicht/Copyright: 1. Dezember 2022
Veröffentlichen auch Sie bei De Gruyter Brill
Informationen für Autor*innen
American Mineralogist
Aus der Zeitschrift American Mineralogist Band 107 Heft 12

Abstract

Studying the structural evolution of the dolomite group at high pressure is crucial for constraining the deep carbon cycle and mantle dynamics. Here we collected high-pressure laser Raman spectra of natural Mg-dolomite CaMg(CO3)2 and Mn-dolomite kutnohorite Ca1.11Mn0.89(CO3)2 samples up to 56 GPa at room temperature in a diamond-anvil cell (DAC) using helium and neon as a pressure-transmitting medium (PTM), respectively. Using helium or neon can ensure samples stay under relatively hydrostatic conditions over the investigated pressure range, resembling the hydrostatic conditions of the deep mantle. Phase transitions in CaMg(CO3)2 were observed at 36.1(25) GPa in helium and 35.2(10) GPa in neon PTM from dolomite-II to -III, respectively. Moreover, the onset pressure of Mn-dolomite Ca1.11Mn0.89(CO3)2-III occurs at 23−25 GPa, about 10 GPa lower than that of Mg-dolomite-III, suggesting that cation substitution could significantly change the onset pressure of the phase transitions in the dolomite group. These results provide new insights into deep carbon carriers within the Earth’s mantle.

Keywords: Deep carbon cycle; Raman spectroscopy; high pressure; dolomite; phase transition

Funding statement: This study was funded by the National Key Research and Development Program of China (2019YFA0708502). C. Zhao acknowledges support from the National Natural Science Foundation of China (NSFC grant no. 42104101) and the open fund from the Key Laboratory of Deep-Earth Dynamics of the Ministry of Natural Resource, Institute of Geology, Chinese Academy of Geological Sciences (J1901-16). Some experiments were supported by the Synergic Extreme Condition User Facility (SECUF). The Department of Mineral Sciences, Smithsonian Institution is acknowledged for the Mn-dolomite sample (Kutnohorite, no. NMNH148722).

References cited

Binck, J., Bayarjargal, L., Lobanov, S.S., Morgenroth, W., Luchitskaia, R., Pickard, C.J., Milman, V., Refson, K., Jochym, D.B., Byrne, P., and Winkler, B. (2020a) Phase stabilities of MgCO3 and MgCO3-II studied by Raman spectroscopy, X-ray diffraction, and density functional theory calculations. Physical Review Materials, 4, 0055001.10.1103/PhysRevMaterials.4.055001Suche in Google Scholar

Binck, J., Chariton, S., Stekiel, M., Bayarjargal, L., Morgenroth, W., Milman, V., Dubrovinsky, L., and Winkler, B. (2020b) High-pressure, high-temperature phase stability of iron-poor dolomite and the structures of dolomite-IIIc and dolomite-V. Physics of the Earth and Planetary Interiors, 299, 106403.10.1016/j.pepi.2019.106403Suche in Google Scholar

Boulard, E., Gloter, A., Corgne, A., Antonangeli, D., Auzende, A.L., Perrillat, J.P., Guyot, F., and Fiquet, G. (2011) New host for carbon in the deep Earth. Proceedings of the National Academy of Sciences, 108, 5184–5187.10.1073/pnas.1016934108Suche in Google Scholar PubMed PubMed Central

Boulard, E., Goncharov, A.F., Blanchard, M., and Mao, W.L. (2015) Pressure-induced phase transition in MnCO3 and its implications on the deep carbon cycle. Journal of Geophysical Research: Solid Earth, 120, 4069–4079.10.1002/2015JB011901Suche in Google Scholar

Boulard, E., Guyot, F., and Fiquet, G. (2020) High-pressure transformations and stability of ferromagnesite in the Earth’s mantle. Carbon in Earth’s Interior, 105–113.10.1002/9781119508229.ch11Suche in Google Scholar

Brenker, F.E., Vollmer, C., Vincze, L., Vekemans, B., Szymanski, A., Janssens, K., Szaloki, I., Nasdala, L., Joswig, W., and Kaminsky, F. (2007) Carbonates from the lower part of transition zone or even the lower mantle. Earth and Planetary Science Letters, 260, 1–9.10.1016/j.epsl.2007.02.038Suche in Google Scholar

Cerantola, V., Bykova, E., Kupenko, I., Merlini, M., Ismailova, L., McCammon, C., Bykov, M., Chumakov, A.I., Petitgirard, S., Kantor, I., and others. (2017) Stability of iron-bearing carbonates in the deep Earth’s interior. Nature Communications, 8, 15960.10.1038/ncomms15960Suche in Google Scholar PubMed PubMed Central

Dasgupta, R., and Hirschmann, M.M. (2010) The deep carbon cycle and melting in Earth’s interior. Earth and Planetary Science Letters, 298, 1–13.10.1016/j.epsl.2010.06.039Suche in Google Scholar

Efthimiopoulos, I., Jahn, S., Kuras, A., Schade, U., and Koch-Müller, M. (2017) Combined high-pressure and high-temperature vibrational studies of dolomite: phase diagram and evidence of a new distorted modification. Physics and Chemistry of Minerals, 44, 465–476.10.1007/s00269-017-0874-5Suche in Google Scholar

Efthimiopoulos, I., Germer, M., Jahn, S., Harms, M., Reichmann, H.J., Speziale, S., Schade, U., Sieber, M., and Koch-Müller, M. (2018) Effects of hydrostaticity on the structural stability of carbonates at lower mantle pressures: the case study of dolomite. High Pressure Research, 1–14.10.1080/08957959.2018.1558223Suche in Google Scholar

Farsang, S., Facq, S., and Redfern, S. (2018) Raman modes of carbonate minerals as pressure and temperature gauges up to 6 GPa and 500 °C. American Mineralogist, 103, 1988–1998.Suche in Google Scholar

Farsang, S., Louvel, M., Zhao, C., Mezouar, M., Rosa, A.D., Widmer, R.N., Feng, X., Liu, J., and Redfern, S.A.T. (2021a) Deep carbon cycle constrained by carbonate solubility. Nature Communications, 12, 4311.10.1038/s41467-021-24533-7Suche in Google Scholar PubMed PubMed Central

Farsang, S., Louvel, M., Rosa, A.D., Amboage, M., Anzellini, S., Widmer, R.N., and Redfern, S.A.T. (2021b) Effect of salinity, pressure and temperature on the solubility of smithsonite (ZnCO3) and Zn complexation in crustal and upper mantle hydrothermal fluids. Chemical Geology, 578, 120320.10.1016/j.chemgeo.2021.120320Suche in Google Scholar

Farsang, S., Widmer, R.N., and Redfern, S.A.T. (2021c) High-pressure and high-temperature vibrational properties and anharmonicity of carbonate minerals up to 6 GPa and 500 °C by Raman spectroscopy. American Mineralogist, 106, 581–598.10.2138/am-2020-7404Suche in Google Scholar

Fiquet, G., Guyot, F., Kunz, M., Matas, J., Andrault, D., and Hanfland, M. (2002) Structural refinements of magnesite at very high pressure. American Mineralogist, 87, 1261–1265.10.2138/am-2002-8-927Suche in Google Scholar

Frezzotti, M.L., Selverstone, J., Sharp, Z.D., and Compagnoni, R. (2011) Carbonate dissolution during subduction revealed by diamond-bearing rocks from the Alps. Nature Geoscience, 4(10), 703–706.10.1038/ngeo1246Suche in Google Scholar

Fu, S., Yang, J., and Lin, J.F. (2017) Abnormal elasticity of single-crystal magnesiosiderite across the spin transition in Earth’s lower mantle. Physical Review Letters, 118, 036402.10.1103/PhysRevLett.118.036402Suche in Google Scholar PubMed

Gaillard, F., Malki, M., Iacono-Marziano, G., Pichavant, M., and Scaillet, B. (2008) Carbonatite melts and electrical conductivity in the asthenosphere. Science, 322, 1363–1365.10.1126/science.1164446Suche in Google Scholar PubMed

Gui, W.B., Zhao, C.S., and Liu, J. (2021) Phase stability and hydroxyl vibration of brucite Mg(OH)2 at high pressure and high temperature. Chinese Physics Letters, 38, 038101.10.1088/0256-307X/38/3/038101Suche in Google Scholar

Hazen, R.M., Downs, R.T., Jones, A.P., and Kah, L. (2013) Carbon mineralogy and crystal chemistry. Reviews in Mineralogy and Geochemistry, 75, 7–46.10.1515/9781501508318-004Suche in Google Scholar

Isshiki, M., Irifune, T., Hirose, K., Ono, S., Ohishi, Y., Watanuki, T., Nishibori, E., Takata, M., and Sakata, M. (2004) Stability of magnesite and its high-pressure form in the lowermost mantle. Nature, 427, 60–63.10.1038/nature02181Suche in Google Scholar PubMed

Klotz, S., Chervin, J.C., Munsch, P., and Le Marchand, G. (2009) Hydrostatic limits of 11 pressure transmitting media. Journal of Physics D: Applied Physics, 42, 075413.10.1088/0022-3727/42/7/075413Suche in Google Scholar

Liang, W., Li, L., Yin, Y., Li, R., Li, Z., Liu, X., Zhao, C., Yang, S., Meng, Y., Li, Z., He, Y., and Li, H. (2019) Crystal structure of norsethite-type BaMn(CO3)2 and its pressure-induced transition investigated by Raman spectroscopy. Physics and Chemistry of Minerals, 46, 771–781.10.1007/s00269-019-01038-wSuche in Google Scholar

Lin, J.F., Liu, J., Jacobs, C., and Prakapenka, V.B. (2012) Vibrational and elastic properties of ferromagnesite across the electronic spin-pairing transition of iron. American Mineralogist, 97, 583–591.10.2138/am.2012.3961Suche in Google Scholar

Liu, J., Lin, J.F., and Prakapenka, V.B. (2015) High-pressure orthorhombic ferro-magnesite as a potential deep-mantle carbon carrier. Scientific Reports, 5, 7640.10.1038/srep07640Suche in Google Scholar PubMed PubMed Central

Liu, J., Caracas, R., Fan, D., Bobocioiu, E., Zhang, D., and Mao, W.L. (2016) High-pressure compressibility and vibrational properties of (Ca,Mn)CO3. American Mineralogist, 101, 2723–2730.10.2138/am-2016-5742Suche in Google Scholar

Lobanov, S.S., and Goncharov, A.F. (2020) Pressure-induced sp2-sp3 transitions in carbon-bearing phases. Carbon in Earth’s Interior, 1–9.Suche in Google Scholar

Logvinova, A.M., Wirth, R., Fedorova, E.N., and Sobolev, N.V. (2008) Nanometresized mineral and fluid inclusions in cloudy Siberian diamonds: new insights on diamond formation. European Journal of Mineralogy, 20, 317–331.10.1127/0935-1221/2008/0020-1815Suche in Google Scholar

Logvinova, A.M., Wirth, R., Tomilenko, A.A., Afanas’ev, V.P., and Sobolev, N.V. (2011) The phase composition of crystal-fluid nanoinclusions in alluvial diamonds in the northeastern Siberian Platform. Russian Geology and Geophysics, 52, 1286–1297.10.1016/j.rgg.2011.10.002Suche in Google Scholar

Logvinova, A.M., Shatskiy, A., Wirth, R., Tomilenko, A.A., Ugap’eva, S.S., and Sobolev, N.V. (2019) Carbonatite melt in type Ia gem diamond. Lithos, 342-343, 463–467.10.1016/j.lithos.2019.06.010Suche in Google Scholar

Mao, H.-K., and Mao, W.L. (2020) Key problems of the four-dimensional Earth system. Matter and Radiation at Extremes, 5, 038102.10.1063/1.5139023Suche in Google Scholar

Mao, H.K., Xu, J., and Bell, P.M. (1986) Calibration of the ruby pressure gauge to 800 kbar under quasi-hydrostatic conditions. Journal of Geophysical Research, 91, 4673.10.1029/JB091iB05p04673Suche in Google Scholar

Mao, Z., Armentrout, M., Rainey, E., Manning, C.E., Dera, P., Prakapenka, V.B., and Kavner, A. (2011) Dolomite III: A new candidate lower mantle carbonate. Geophysical Research Letters, 38, L22303.10.1029/2011GL049519Suche in Google Scholar

Martirosyan, N.S., Efthimiopoulos, I., Pennacchioni, L., Wirth, R., Jahn, S., and Koch-Müller, M. (2021) Effect of cationic substitution on the pressure-induced phase transitions in calcium carbonate. American Mineralogist, 106, 549–558.10.2138/am-2021-7547Suche in Google Scholar

Merlini, M., Crichton, W.A., Hanfland, M., Gemmi, M., Muller, H., Kupenko, I., and Dubrovinsky, L. (2012) Structures of dolomite at ultrahigh pressure and their influence on the deep carbon cycle. Proceedings of the National Academy of Sciences, 109, 13509–13514.10.1073/pnas.1201336109Suche in Google Scholar PubMed PubMed Central

Merlini, M., Hanfland, M., and Gemmi, M. (2015) The MnCO3-II high-pressure polymorph of rhodocrosite. American Mineralogist, 100, 2625–2629.10.2138/am-2015-5320Suche in Google Scholar

Merlini, M., Cerantola, V., Gatta, G.D., Gemmi, M., Hanfland, M., Kupenko, I., Lotti, P., Müller, H., and Zhang, L. (2017) Dolomite-IV: Candidate structure for a carbonate in the Earth’s lower mantle. American Mineralogist, 102, 1763–1766.10.2138/am-2017-6161Suche in Google Scholar

Oganov, A.R., Ono, S., Ma, Y., Glass, C.W., and Garcia, A. (2008) Novel high-pressure structures of MgCO3, CaCO3 and CO2 and their role in Earth’s lower mantle. Earth and Planetary Science Letters, 273, 38–47.10.1016/j.epsl.2008.06.005Suche in Google Scholar

Palaich, S.E.M., Heffern, R.A., Watenphul, A., Knight, J., and Kavner, A. (2015) High-pressure compressibility and phase stability of Mn-dolomite (kutnohorite). American Mineralogist, 100, 2242–2245.10.2138/am-2015-5095Suche in Google Scholar

Plank, T., and Manning, C.E. (2019) Subducting carbon. Nature, 574, 343–352.10.1038/s41586-019-1643-zSuche in Google Scholar PubMed

Richard, J.R., and Wayne, A.D. (1989) Structural variation in the dolomite-ankerite solid-solution series An X-ray, Miissbauer, and TEM study. American Mineralogist, 74, 1159–1167.Suche in Google Scholar

Rividi, N., van Zuilen, M., Philippot, P., Menez, B., Godard, G., and Poidatz, E. (2010) Calibration of carbonate composition using micro-Raman analysis: application to planetary surface exploration. Astrobiology, 10, 293–309.10.1089/ast.2009.0388Suche in Google Scholar PubMed

Sanchez-Valle, C., Ghosh, S., and Rosa, A.D. (2011) Sound velocities of ferromagnesian carbonates and the seismic detection of carbonates in eclogites and the mantle. Geophysical Research Letters, 38, L24315.10.1029/2011GL049981Suche in Google Scholar

Shannon, R.D. (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallographica, A32, 751–767.10.1107/S0567739476001551Suche in Google Scholar

Shcheka, S.S., Wiedenbeck, M., Frost, D.J., and Keppler, H. (2006) Carbon solubility in mantle minerals. Earth and Planetary Science Letters, 245, 730–742.10.1016/j.epsl.2006.03.036Suche in Google Scholar

Shen, G., Wang, Y., Dewaele, A., Wu, C., Fratanduono, D.E., Eggert, J., Klotz, S., Dziubek, K.F., Loubeyre, P., Fat’yanov, O.V., and other members of the IPPS task group. (2020) Toward an international practical pressure scale: A proposal for an IPPS ruby gauge (IPPS-Ruby2020). High Pressure Research, 40, 299–314.10.1080/08957959.2020.1791107Suche in Google Scholar

Sun, Y., Hier-Majumder, S., Xu, Y., and Walter, M. (2020) Stability and migration of slab-derived carbonate-rich melts above the transition zone. Earth and Planetary Science Letters, 531, 116000.10.1016/j.epsl.2019.116000Suche in Google Scholar

Vennari, C.E., and Williams, Q. (2018) A novel carbon bonding environment in deep mantle high-pressure dolomite. American Mineralogist, 103, 171–174.10.2138/am-2018-6270Suche in Google Scholar

Vennari, C.E., Beavers, C.M., and Williams, Q. (2018) High-pressure/temperature behavior of the alkali/calcium carbonate shortite (Na2Ca2(CO3)3): Implications for carbon sequestration in Earth’s transition zone. Journal of Geophysical Research: Solid Earth, 123, 6574–6591.10.1107/S0108767318097192Suche in Google Scholar

Williams, Q., Collerson, B., and Knittle, E. (1992) Vibrational spectra of magnesite (MgCO3) and calcite-III at high pressures. American Mineralogist, 77, 1158–1165.Suche in Google Scholar

Yao, C., Wu, Z., Zou, F., and Sun, W. (2018) Thermodynamic and elastic properties of magnesite at mantle conditions: First-principles calculations. Geochemistry, Geophysics, Geosystems, 19, 2719–2731.10.1029/2017GC007396Suche in Google Scholar

Zhao, C., Li, H., Jiang, J., He, Y., and Liang, W. (2018) Phase transition and vibration properties of MnCO3 at high pressure and high-temperature by Raman spectroscopy. High Pressure Research, 38, 212–223.10.1080/08957959.2018.1476505Suche in Google Scholar

Zhao, C., Li, H., Chen, P., and Jiang, J. (2019) Sound velocities across calcite phase transitions by Brillouin scattering spectroscopy. American Mineralogist, 104, 418–424.10.2138/am-2019-6682Suche in Google Scholar

Zhao, C., Xu, L., Gui, W., and Liu, J. (2020) Phase stability and vibrational properties of iron-bearing carbonates at high pressure. Minerals, 10, 1142.10.3390/min10121142Suche in Google Scholar

Zhao, C., Lv, C., Xu, L., Liang, L., and Liu, J. (2021) Raman signatures of the distortion and stability of MgCO3 to 75 GPa. American Mineralogist, 106, 367–373.10.2138/am-2020-7490Suche in Google Scholar

Zucchini, A., Comodi, P., Nazzareni, S., and Hanfland, M. (2014) The effect of cation ordering and temperature on the high-pressure behaviour of dolomite. Physics and Chemistry of Minerals, 41, 783–793.10.1007/s00269-014-0691-zSuche in Google Scholar
Received: 2021-08-12
Accepted: 2021-12-21
Published Online: 2022-12-01
Published in Print: 2022-12-16

© 2022 Mineralogical Society of America

Artikel in diesem Heft

  1. Oxidation of arcs and mantle wedges: It’s not all about iron and water
  2. Paragenesis of Li minerals in the Nanyangshan rare-metal pegmatite, Northern China: Toward a generalized sequence of Li crystallization in Li-Cs-Ta-type granitic pegmatites
  3. The new mineral tomiolloite, Al12(Te4+O3)5[(SO3)0.5(SO4)0.5](OH)24: A unique microporous tellurite structure
  4. Authigenic anatase nanoparticles as a proxy for sedimentary environment and porewater pH
  5. Color effects of Cu nanoparticles in Cu-bearing plagioclase feldspars
  6. Expanding the speciation of terrestrial molybdenum: Discovery of polekhovskyite, MoNiP2, and insights into the sources of Mo-phosphides in the Dead Sea Transform area
  7. Sound speed and refractive index of amorphous CaSiO3 upon pressure cycling to 40 GPa
  8. Calorimetric study of skutterudite (CoAs2.92) and heazlewoodite (Ni3S2)
  9. Melting phase equilibrium relations in the MgSiO3-SiO2 system under high pressures
  10. Effects of hydrostaticity and Mn-substitution on dolomite stability at high pressure
  11. Crystallization of bastnäsite and burbankite from carbonatite melt in the system La(CO3)F-CaCO3-Na2CO3 at 100 MPa
  12. Crystal shapes, triglyphs, and twins in minerals: The case of pyrite
  13. Nanostructure reveals REE mineral crystallization mechanisms in granites from a heavy REE deposit, South China
  14. Paratobermorite, Ca4(Al0.5Si0.5)2Si4O16(OH)·2H2O·(Ca·3H2O), a new tobermorite-supergroup mineral with a novel topological type of the microporous crystal structure
  15. Morphological and chemical characterization of secondary carbonates in the Toki granite, central Japan, and the evolution of fluid chemistry
  16. Characteristics and formation of corundum within syenite in the Yushishan rare metal deposits in the northeastern Tibetan Plateau
  17. Hydrogen solubility in FeSi alloy phases at high pressures and temperatures
  18. First evidence of dmisteinbergite (CaAl2Si2O8 polymorph) in high-grade metamorphic rocks
  19. New Mineral Names
https://doi.org/10.2138/am-2022-8248
Schlagwörter für diesen Artikel
Deep carbon cycle; Raman spectroscopy; high pressure; dolomite; phase transition

Artikel in diesem Heft

  1. Oxidation of arcs and mantle wedges: It’s not all about iron and water
  2. Paragenesis of Li minerals in the Nanyangshan rare-metal pegmatite, Northern China: Toward a generalized sequence of Li crystallization in Li-Cs-Ta-type granitic pegmatites
  3. The new mineral tomiolloite, Al12(Te4+O3)5[(SO3)0.5(SO4)0.5](OH)24: A unique microporous tellurite structure
  4. Authigenic anatase nanoparticles as a proxy for sedimentary environment and porewater pH
  5. Color effects of Cu nanoparticles in Cu-bearing plagioclase feldspars
  6. Expanding the speciation of terrestrial molybdenum: Discovery of polekhovskyite, MoNiP2, and insights into the sources of Mo-phosphides in the Dead Sea Transform area
  7. Sound speed and refractive index of amorphous CaSiO3 upon pressure cycling to 40 GPa
  8. Calorimetric study of skutterudite (CoAs2.92) and heazlewoodite (Ni3S2)
  9. Melting phase equilibrium relations in the MgSiO3-SiO2 system under high pressures
  10. Effects of hydrostaticity and Mn-substitution on dolomite stability at high pressure
  11. Crystallization of bastnäsite and burbankite from carbonatite melt in the system La(CO3)F-CaCO3-Na2CO3 at 100 MPa
  12. Crystal shapes, triglyphs, and twins in minerals: The case of pyrite
  13. Nanostructure reveals REE mineral crystallization mechanisms in granites from a heavy REE deposit, South China
  14. Paratobermorite, Ca4(Al0.5Si0.5)2Si4O16(OH)·2H2O·(Ca·3H2O), a new tobermorite-supergroup mineral with a novel topological type of the microporous crystal structure
  15. Morphological and chemical characterization of secondary carbonates in the Toki granite, central Japan, and the evolution of fluid chemistry
  16. Characteristics and formation of corundum within syenite in the Yushishan rare metal deposits in the northeastern Tibetan Plateau
  17. Hydrogen solubility in FeSi alloy phases at high pressures and temperatures
  18. First evidence of dmisteinbergite (CaAl2Si2O8 polymorph) in high-grade metamorphic rocks
  19. New Mineral Names
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 18.9.2025 von https://www.degruyterbrill.com/document/doi/10.2138/am-2022-8248/html
Button zum nach oben scrollen