Startseite Interpretation of the infrared spectra of the lizardite-nepouite series in the near- and mid-infrared range
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Interpretation of the infrared spectra of the lizardite-nepouite series in the near- and mid-infrared range

  • Fabien Baron EMAIL logo und Sabine Petit
Veröffentlicht/Copyright: 18. Februar 2016
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American Mineralogist
Aus der Zeitschrift American Mineralogist Band 101 Heft 2

Abstract

A series of 1:1 silicate clays of the lizardite-nepouite series [Si2Mg3–xNixO5(OH4) with x = 0, 0.5, 1, 1.5, 2, 2.5, and 3] was synthesized at 220 °C during 7 days from coprecipitated gels in hydrothermal conditions. A clear relationship was evidenced between the d(06–33) and the Ni/Mg ratio of the synthesized samples following a Vegard’s law and suggested a random distribution of octahedral cations. For the first time, infrared spectra of this series were given in both near and mid-infrared spectral regions (250–7500 cm–1). Notably, the bands due to the OH stretching vibrations and those of their first overtones in the lizardite-nepouite series were attributed. The combination bands observed in the near infrared region for both end-members could be attributed thanks to combinations of two or three middle-infrared features. Some of the observed combination bands are clearly linked to combination of different vibrational groups.

Infrared spectroscopy is simple to use and is a powerful tool to study the crystal chemistry of garnierites. More broadly, the improvement of band attributions especially in near infrared contributes to develop the infrared analyses in field geology and remote sensing.

Keywords: Lizardite; nepouite; infrared spectroscopy; near infrared; mid-infrared; synthesis; nickel; clay minerals; serpentine; phyllosilicates; garnierite

Acknowledgments

We gratefully acknowledge A. Decarreau for his helpful discussions on a preliminary version. We are grateful to J. Yvon and an anonymous reviewer for their constructive contributions.

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  1. Manuscript handled by Julien Mercadier

Received: 2015-3-11
Accepted: 2015-9-9
Published Online: 2016-2-18
Published in Print: 2016-2-1

© 2016 by Walter de Gruyter Berlin/Boston

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https://doi.org/10.2138/am-2016-5352
Schlagwörter für diesen Artikel
Lizardite; nepouite; infrared spectroscopy; near infrared; mid-infrared; synthesis; nickel; clay minerals; serpentine; phyllosilicates; garnierite

Artikel in diesem Heft

  1. Highlights and Breakthroughs
  2. The deep continental crust has a larger Mg isotopic variation than previously thought
  3. Article
  4. Magnesium isotopic composition of the deep continental crust
  5. Review
  6. Cancrinite-group minerals: Crystal-chemical description and properties under non-ambient conditions—A review
  7. Amorphous Materials: Properties, Structure, and Durability
  8. Nepheline structural and chemical dependence on melt composition
  9. Chemistry and Mineralogy of Earth's Mantle
  10. Some thermodynamic properties of larnite (β-Ca2SiO4) constrained by high T/P experiment and/or theoretical simulation
  11. Minerals in the Human Body
  12. Growth dynamics of vaterite in relation to the physico-chemical properties of its precursor, amorphous calcium carbonate, in the Ca-CO3-PO4 system
  13. Special Collection: Perspectives on Origins and Evolution of Crustal Magmas
  14. Mafic replenishments into floored silicic magma chambers
  15. Special Collection: Perspectives on Origins and Evolution of Crustal Magmas
  16. Hafnium, oxygen, neodymium, strontium, and lead isotopic constraints on magmatic evolution of the supereruptive southern Black Mountains volcanic center, Arizona, U.S.A.: A combined LASS zircon–whole-rock study
  17. Special Collection: Perspectives on Origins and Evolution of Crustal Magmas
  18. Deciphering magmatic processes in calc-alkaline plutons using trace element zoning in hornblende
  19. Special Collection: Geology and Geobiology of Lassen Volcanic National Park
  20. The Lassen hydrothermal system
  21. Article
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  25. Article
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  27. Article
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  37. Article
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  39. Article
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  47. Letter
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  49. New Mineral Names
  50. New Mineral Names*,†
  51. Review
  52. American Mineralogist thanks the year 2015 reviewers
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