Inquisition of micellar and surface active properties of gemini surfactants in the presence of a dipeptide
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Jasmeet Kaur
Abstract
The influence of dipeptide glycyl-l-valine (gly-l-val) on the micellization and surface active properties of two different gemini surfactants varying in their spacer group i.e. ethylene-1,2-bis (N,N-dimethyl-N-dodecylammonium bromide) (12–2–12) and hexamethylene-1,6-bis-(N,N-dimethyl-N-dodecylammonium bromide) (12–6–12) was explored using tensiometry as well as conductivity technique. Conductivity measurements at several temperatures (293.15, 298.15, 303.15 and 308.15) K and tensiometric measurements at 298.15 K at several concentrations of dipeptide (0.02, 0.04 and 0.06) mol/kg were conducted so as to deduce the interactions amid dipeptide and two surfactants. Several parameters viz. critical micelle concentration (CMC) as well as the degree of ionization (α) along with various parameters associated with thermodynamics; standard entropy of micellization (
Acknowledgment
Jasmeet Kaur, one of the authors, would like to express her gratitude to the Ministry of Education (MOE) and the Director and Head of the Chemistry Department at Dr. B.R. Ambedkar National Institute of Technology.
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Research funding: None declared.
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Conflict of interests: The authors declare no conflicts of interest regarding this article.
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Supplementary Material
This article contains supplementary material (https://doi.org/10.1515/znb-2023-0035).
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Artikel in diesem Heft
- Frontmatter
- Review Article
- GO-Ag-NPs as a promising agent for biomedical, catalytic, electrochemical detection and water treatment technologies; a comprehensive review
- Original Papers
- Role of the thermal regime in the defect formation of zinc oxide nanostructures prepared by the thermal decomposition process
- Facile synthesis of a ZnO/Fe2O3 heterostructure and its graphene-reinforced composite for boosting the photo-mineralization of crystal violet and phenol
- Desulfurization of coal using SnO2/TiO2 nanocomposite immobilized on glass beads under solar light irradiation
- Photocatalytic degradation of dyes in aqueous media by gum shellac stabilized selenium nanoparticles
- Eco-friendly extraction of cellulose from Ailanthus altissima for nanocellulose production: physico-chemical properties
- Inquisition of micellar and surface active properties of gemini surfactants in the presence of a dipeptide
- Investigating adsorptive potential of Raphanus caudatus leaves biomass for methyl orange dye: isotherm and kinetic study
- Thienylpicolinamidine derivatives as new dissolution inhibitors for carbon steels in HCl medium: experimental and theoretical studies
- Extraction and characterization of novel cellulose nanocrystals from Artemisia scoparia straw and their application in hydroxypropyl methyl cellulose (HPMC) films
- Synthesis of doped metal sulfide nanoparticles and their graphene reinforced nanohybrid for Pb(II) detection
