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Suppression of steel corrosion via some gemini cationic surfactant-based Schiff base: experimental and theoretical investigations

  • Samy M. Shaban EMAIL logo , Samir H. Shafek , Ahmed H. Elged , Mahmoud Bekhit , Ahmed I. Adawy and Emad A. Badr
Published/Copyright: November 2, 2022
Zeitschrift für Physikalische Chemie
From the journal Zeitschrift für Physikalische Chemie Volume 236 Issue 11-12

Abstract

Steel is involved extensively in engineering vast constructing units in many industries and can undergo to corrosion by some chemical and/or electrochemical reactions with the environment. Therefore, designating an organic inhibitor with a specific chemical structure will participate in steel protection via enhancing their adsorption on the steel surface. Three gemini cationic surfactants based on azomethine with different hydrophobic tails labeled GSBI8, GSBI12, and GSBI16 have been designated and evaluated as corrosion inhibitors utilizing electrochemical impedance spectroscopy (EIS), gravimetrical and potentiodynamic polarization techniques. Importantly, the surfactant tail regulated the corrosion inhibition performance; with increasing the surfactant tail length, their inhibition efficiency enhanced because of their higher adsorption affinity. The inhibition efficiency of GSBI8, GSBI12, and GSBI16 reached 95.52, 96.72, and 97.1% respectively (EIS measurements). The Tafel examination clarified that GSBI8, GSBI12, and GSBI16 inhibitors behave as mixed type inhibitors following the modified Langmuir isotherm. The inhibitors adsorption on C-steel was confirmed by SEM surface examination. Finally, the DFT and MCs point of views investigation supported the experimental performance of the tested GSBI8, GSBI12, and GSBI16 inhibitors and specially their dependence on surfactant tail length.

Keywords: azomethine gemini surfactants; EIS; Langmuir isotherm; steel corrosion; weight loss DFT
Corresponding author: Samy M. Shaban, Surfactant Laboratory, Petrochemical Department, Egyptian Petroleum Research Institute, Cairo, Egypt; and School of Chemical Engineering, Sungkyunkwan University (SKKU), Suwon 16419, Republic of Korea, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Zhang, Y., Pan, Y., Li, P., Zeng, X., Guo, B., Pan, J., Hou, L., Yin, X. Novel Schiff base-based cationic Gemini surfactants as corrosion inhibitors for Q235 carbon steel and printed circuit boards. Colloid. Surface. 2021, 623, 126717; https://doi.org/10.1016/j.colsurfa.2021.126717.Search in Google Scholar

2. Mao, T., Huang, H., Liu, D., Shang, X., Wang, W., Wang, L. Novel cationic Gemini ester surfactant as an efficient and eco-friendly corrosion inhibitor for carbon steel in HCl solution. J. Mol. Liq. 2021, 339, 117174; https://doi.org/10.1016/j.molliq.2021.117174.Search in Google Scholar

3. Zhang, F., Li, X., Deng, S., Tang, M., Du, G. Amphoteric surfactant of octadecyl dimethyl betaine as an efficient corrosion inhibitor for cold rolled steel in phosphoric acid solution. J. Mater. Res. Technol. 2021, 15, 7050–7069; https://doi.org/10.1016/j.jmrt.2021.11.107.Search in Google Scholar

4. Zhu, H., Li, X., Lu, X., Wang, J., Hu, Z., Ma, X. Efficiency of Gemini surfactant containing semi-rigid spacer as microbial corrosion inhibitor for carbon steel in simulated seawater. Bioelectrochemistry 2021, 140, 107809; https://doi.org/10.1016/j.bioelechem.2021.107809.Search in Google Scholar PubMed

5. Abd El-Lateef, H. M., Abbasov, V. M., Aliyeva, L. I., Khalaf, M. M. Novel naphthenate surfactants based on petroleum acids and nitrogenous bases as corrosion inhibitors for C1018-type mild steel in CO2-saturated brine. Egypt. J. Pet. 2015, 24, 175–182; https://doi.org/10.1016/j.ejpe.2015.05.010.Search in Google Scholar

6. Shaban, S. M., Elsharif, A. M., Elged, A. H., Eluskkary, M. M., Aiad, I., Soliman, E. A. Some new phospho-zwitterionic Gemini surfactants as corrosion inhibitors for carbon steel in 1.0 M HCl solution. Environ. Technol. Innovat. 2021, 24, 102051; https://doi.org/10.1016/j.eti.2021.102051.Search in Google Scholar

7. El-Tabei, A. S., El-Tabey, A. E., El Basiony, N. M. Newly imine-azo dicationic amphiphilic for corrosion and sulfate-reducing bacteria inhibition in petroleum processes: laboratory and theoretical studies. Appl. Surf. Sci. 2022, 573, 151531; https://doi.org/10.1016/j.apsusc.2021.151531.Search in Google Scholar

8. Fouda, A. S., Elmorsi, M. A., Fayed, T., Shaban, S. M., Azazy, O. Corrosion inhibition of novel prepared cationic surfactants for API N80 carbon steel pipelines in oil industries. Surf. Eng. Appl. Electrochem. 2018, 54, 180–193; https://doi.org/10.3103/s1068375518020060.Search in Google Scholar

9. Aiad, I., Shaban, S. M., El-Sukkary, M. M., El-Awady, M. Y., Soliman, E. Electrical and gravimetric estimation of the corrosion inhibition of three synthesized cationic surfactants N-(3-(butylidene amino) propyl)-N, N-dimethyl alkan-1-ammonium bromide derivatives in 1 M HCl. Mater. Perform. Charact. 2017, 6, 429–450; https://doi.org/10.1520/mpc20170001.Search in Google Scholar

10. Shaban, S. M., Fouda, A. S., Rashwan, S. M., Ibrahim, H. E., Elbhrawy, M. F. Inhibitive action of new synthesized cationic surfactant with free hydroxyl group on the C1018 steel corrosion: experimental and theoretical investigations. Protect. Met. Phys. Chem. Surface 2018, 54, 709–723; https://doi.org/10.1134/s2070205118040238.Search in Google Scholar

11. Ly, M., Mekonnen, T. H. Cationic surfactant modified cellulose nanocrystals for corrosion protective nanocomposite surface coatings. J. Ind. Eng. Chem. 2020, 83, 409–420; https://doi.org/10.1016/j.jiec.2019.12.014.Search in Google Scholar

12. Wang, Q., Liu, L., Zhang, Q., Wu, X., Zheng, H., Gao, P., Zeng, G., Yan, Z., Sun, Y., Li, Z., Li, X. Insight into the anti–corrosion performance of Artemisia argyi leaves extract as eco–friendly corrosion inhibitor for carbon steel in HCl medium. Sustain. Chem. Pharm. 2022, 27, 100710; https://doi.org/10.1016/j.scp.2022.100710.Search in Google Scholar

13. Sarkar, T. K., Saraswat, V., Mitra, R. K., Obot, I. B., Yadav, M. Mitigation of corrosion in petroleum oil well/tubing steel using pyrimidines as efficient corrosion inhibitor: experimental and theoretical investigation. Mater. Today Commun. 2021, 26, 101862; https://doi.org/10.1016/j.mtcomm.2020.101862.Search in Google Scholar

14. Shaban, S., Fouda, A., Elmorsi, M., Fayed, T., Azazy, O. A study on the effect of new prepared amide cationic amphipathic on the corrosion inhibition of API N80 steel pipelines in oil wells industries. Anti-corrosion Methods & Mater. 2018, 65, 197–209; https://doi.org/10.1108/acmm-08-2017-1824.Search in Google Scholar

15. Shaban, S. M., Elsamad, S. A., Tawfik, S. M., Abdel-Rahman, A. A. H., Aiad, I. Studying surface and thermodynamic behavior of a new multi-hydroxyl Gemini cationic surfactant and investigating their performance as corrosion inhibitor and biocide. J. Mol. Liq. 2020, 316, 113881; https://doi.org/10.1016/j.molliq.2020.113881.Search in Google Scholar

16. Zheng, T., Liu, J., Wang, M., Liu, Q., Wang, J., Chong, Y., Jia, G. Synergistic corrosion inhibition effects of quaternary ammonium salt cationic surfactants and thiourea on Q235 steel in sulfuric acid: experimental and theoretical research. Corrosion Sci. 2022, 199, 110199; https://doi.org/10.1016/j.corsci.2022.110199.Search in Google Scholar

17. Abd-Elaal, A. A., Shaban, S. M., Tawfik, S. M. Three Gemini cationic surfactants based on polyethylene glycol as effective corrosion inhibitor for mild steel in acidic environment. J. Assoc. Arab Univ. Basic Appl. Sci. 2017, 24, 54–65; https://doi.org/10.1016/j.jaubas.2017.03.004.Search in Google Scholar

18. El-Sukkary, M. M. A., Aiad, I., Deeb, A., El-Awady, M. Y., Ahmed, H. M., Shaban, S. M. The preparation and characterization of some novel quaternary iminium salts based on Schiff-base as a corrosion inhibitor. Petrol. Sci. Technol. 2010, 28, 1158–1169; https://doi.org/10.1080/10916460902967718.Search in Google Scholar

19. Wang, S., Sun, J., Shan, B., Fan, W., Ding, R., Yang, J., Zhao, X. Performance of dodecyl dimethyl benzyl ammonium chloride as bactericide and corrosion inhibitor for 7B04 aluminum alloy in an aircraft fuel system. Arab. J. Chem. 2022, 15, 103926; https://doi.org/10.1016/j.arabjc.2022.103926.Search in Google Scholar

20. Shaban, S. M., El-Sherif, R. M., Fahim, M. A. Studying the surface behavior of some prepared free hydroxyl cationic amphipathic compounds in aqueous solution and their biological activity. J. Mol. Liq. 2018, 252, 40–51; https://doi.org/10.1016/j.molliq.2017.12.105.Search in Google Scholar

21. Shaban, S. M., Kang, J., Kim, D.-H. Surfactants: recent advances and their applications. Compos. Commun. 2020, 22, 100537; https://doi.org/10.1016/j.coco.2020.100537.Search in Google Scholar

22. Aiad, I., EL-Sukkary, M. M., El-Deeb, A., El-Awady, M. Y., Shaban, S. M. Surface and biological activity of some prepared iminium surfactants based on Schiff bases. J. Surfactants Deterg. 2013, 16, 243–250; https://doi.org/10.1007/s11743-012-1402-8.Search in Google Scholar

23. Aiad, I., El-Sukkary, M. M., El-Deeb, A., El-Awady, M. Y., Shaban, S. M. Surface properties, thermodynamic aspects and antimicrobial activity of some novel iminium surfactants. J. Surfactants Deterg. 2012, 15, 359–366; https://doi.org/10.1007/s11743-011-1317-9.Search in Google Scholar

24. Taha, A. A., Shaban, S. M., Fetouh, H. A., Taha, S. T., Sabet, V. M., Kim, D.-H. Synthesis and evaluation of nonionic surfactants based on dimethylaminoethylamine: electrochemical investigation and theoretical modeling as inhibitors during electropolishing in-ortho-phosphoric acid. J. Mol. Liq. 2021, 328, 115421; https://doi.org/10.1016/j.molliq.2021.115421.Search in Google Scholar

25. Shaban, M. M., Eid, A. M., Farag, R. K., Negm, N. A., Fadda, A. A., Migahed, M. A. Novel trimeric cationic pyrdinium surfactants as bi-functional corrosion inhibitors and antiscalants for API 5L X70 carbon steel against oilfield formation water. J. Mol. Liq. 2020, 305, 112817; https://doi.org/10.1016/j.molliq.2020.112817.Search in Google Scholar

26. Ayukayeva, V. N., Boiko, G. I., Lyubchenko, N. P., Sarmurzina, R. G., Mukhamedova, R. F., Karabalin, U. S., Dergunov, S. A. Polyoxyethylene sorbitan trioleate surfactant as an effective corrosion inhibitor for carbon steel protection. Colloids Surf. A Physicochem. Eng. Asp. 2019, 579, 123636; https://doi.org/10.1016/j.colsurfa.2019.123636.Search in Google Scholar

27. Shaban, S. M., Kim, D.-H. The influence of the Gemini surfactants hydrocarbon tail on in-situ synthesis of silver nanoparticles: characterization, surface studies and biological performance. Kor. J. Chem. Eng. 2020, 37, 1008–1019; https://doi.org/10.1007/s11814-020-0542-1.Search in Google Scholar

28. Fernandes, C. M., Pina, V. G. S. S., Alfaro, C. G., de Sampaio, M. T. G., Massante, F. F., Alvarez, L. X., Barrios, A. M., Silva, J. C. M., Alves, O. C., Briganti, M., Totti, F., Ponzio, E. A. Innovative characterization of original green vanillin-derived Schiff bases as corrosion inhibitors by a synergic approach based on electrochemistry, microstructure, and computational analyses. Colloid. Surface. 2022, 641, 128540; https://doi.org/10.1016/j.colsurfa.2022.128540.Search in Google Scholar

29. Abd El-Lateef, H. M., Soliman, K. A., Tantawy, A. H. Novel synthesized Schiff Base-based cationic gemini surfactants: electrochemical investigation, theoretical modeling and applicability as biodegradable inhibitors for mild steel against acidic corrosion. J. Mol. Liq. 2017, 232, 478–498; https://doi.org/10.1016/j.molliq.2017.02.105.Search in Google Scholar

30. Labena, A., Hamed, A., Ismael, E. H. I., Shaban, S. M. Novel gemini cationic surfactants: thermodynamic, antimicrobial Susceptibility, and corrosion inhibition behavior against acidithiobacillus ferrooxidans. J. Surfactants Deterg. 2020, 23, 991–1004.10.1002/jsde.12437Search in Google Scholar

31. Badr, E. A., Shafek, S. H., Hefni, H. H. H., Elsharif, A. M., Alanezi, A. A., Shaban, S. M., Kim, D.-H. Synthesis of Schiff base-based cationic Gemini surfactants and evaluation of their effect on in-situ AgNPs preparation: structure, catalytic, and biological activity study. J. Mol. Liq. 2021, 326, 115342; https://doi.org/10.1016/j.molliq.2021.115342.Search in Google Scholar

32. Kamal, R. S., Migahed, M. A., Abd El-Sattar, N. E. A. Synthesis, characterization and performance of succinimide derivatives as anti-corrosion and anti-scalant in petroleum applications. J. Mol. Liq. 2022, 354, 118869; https://doi.org/10.1016/j.molliq.2022.118869.Search in Google Scholar

33. Badr, E. A., Bedair, M. A., Shaban, S. M. Adsorption and performance assessment of some imine derivatives as mild steel corrosion inhibitors in 1.0 M HCl solution by chemical, electrochemical and computational methods. Mater. Chem. Phys. 2018, 219, 444–460; https://doi.org/10.1016/j.matchemphys.2018.08.041.Search in Google Scholar

34. Daoudi, W., El Aatiaoui, A., Falil, N., Azzouzi, M., Berisha, A., Olasunkanmi, L. O., Dagdag, O., Ebenso, E. E., Koudad, M., Aouinti, A., Loutou, M., Oussaid, A. Essential oil of Dysphania ambrosioides as a green corrosion inhibitor for mild steel in HCl solution. J. Mol. Liq. 2022, 363, 119839; https://doi.org/10.1016/j.molliq.2022.119839.Search in Google Scholar

35. Shaban, S. M., Aiad, I., Moustafa, A. H., Aljoboury, O. H. Some alginates polymeric cationic surfactants; surface study and their evaluation as biocide and corrosion inhibitors. J. Mol. Liq. 2019, 273, 164–176; https://doi.org/10.1016/j.molliq.2018.10.017.Search in Google Scholar

36. Kousar, K., Walczak, M. S., Ljungdahl, T., Wetzel, A., Oskarsson, H., Restuccia, P., Ahmad, E. A., Harrison, N. M., Lindsay, R. Corrosion inhibition of carbon steel in hydrochloric acid: elucidating the performance of an imidazoline-based surfactant. Corrosion Sci. 2021, 180, 109195; https://doi.org/10.1016/j.corsci.2020.109195.Search in Google Scholar

37. Tawfik, S. M., Abd-Elaal, A. A., Shaban, S. M., Roshdy, A. A. Surface, thermodynamic and biological activities of some synthesized Gemini quaternary ammonium salts based on polyethylene glycol. J. Ind. Eng. Chem. 2015, 30, 112–119; https://doi.org/10.1016/j.jiec.2015.05.011.Search in Google Scholar

38. Toukal, L., Foudia, M., Haffar, D., Aliouane, N., Al-Noaimi, M., Bellal, Y., Elmsellem, H., Abdеl-Rahman, І. Monte Carlo simulation and electrochemical performance corrosion inhibition whid benzimidazole derivative for XC48 steel in 0.5 M H2SO4 and 1.0 M HCl solutions. J. Indian Chem. Soc. 2022, 99, 100634; https://doi.org/10.1016/j.jics.2022.100634.Search in Google Scholar

39. Lebrini, M., Lagrenée, M., Vezin, H., Gengembre, L., Bentiss, F. Electrochemical and quantum chemical studies of new thiadiazole derivatives adsorption on mild steel in normal hydrochloric acid medium. Corrosion Sci. 2005, 47, 485–505; https://doi.org/10.1016/j.corsci.2004.06.001.Search in Google Scholar

40. Ismail, M. A., Shaban, M. M., Abdel-Latif, E., Abdelhamed, F. H., Migahed, M. A., El-Haddad, M. N., Abousalem, A. S. Novel cationic aryl bithiophene/terthiophene derivatives as corrosion inhibitors by chemical, electrochemical and surface investigations. Sci. Rep. 2022, 12, 3192; https://doi.org/10.1038/s41598-022-06863-8.Search in Google Scholar PubMed PubMed Central

41. Azzam, E. M. S., El-Salam, H. M. A., Mohamed, R. A., Shaban, S. M., Shokry, A. Control the corrosion of mild steel using synthesized polymers based on polyacrylamide. Egypt. J. Pet. 2018, 27, 897–910; https://doi.org/10.1016/j.ejpe.2018.01.006.Search in Google Scholar

42. Villamil, R. F. V., Corio, P., Rubim, J. C., Agostinho, S. M. L. Effect of sodium dodecylsulfate on copper corrosion in sulfuric acid media in the absence and presence of benzotriazole. J. Electroanal. Chem. 1999, 472, 112–119; https://doi.org/10.1016/s0022-0728(99)00267-3.Search in Google Scholar

43. Fouda, A. S., Rashwan, S. M., Shaban, S. M., Ibrahim, H. E., Elbhrawy, M. F. Evaluation of a novel cationic surfactant based on 2-(2 (dimethylamino)ethoxy)ethanol as a corrosion inhibitor for carbon steel 1018 in 1.0MHCl solution. Egypt. J. Pet. 2018, 27, 295–306; https://doi.org/10.1016/j.ejpe.2017.05.001.Search in Google Scholar

44. Hegazy, M. A. A novel Schiff base-based cationic gemini surfactants: synthesis and effect on corrosion inhibition of carbon steel in hydrochloric acid solution. Corrosion Sci. 2009, 51, 2610–2618; https://doi.org/10.1016/j.corsci.2009.06.046.Search in Google Scholar

45. Ansari, K. R., Chauhan, D. S., Quraishi, M. A., Saleh, T. A. Surfactant modified graphene oxide as novel corrosion inhibitors for mild steels in acidic media. Inorg. Chem. Commun. 2020, 121, 108238; https://doi.org/10.1016/j.inoche.2020.108238.Search in Google Scholar

46. Shalabi, K., Helmy, A. M., El-Askalany, A. H., Shahba, M. M. New pyridinium bromide mono-cationic surfactant as corrosion inhibitor for carbon steel during chemical cleaning: experimental and theoretical studies. J. Mol. Liq. 2019, 293, 111480; https://doi.org/10.1016/j.molliq.2019.111480.Search in Google Scholar

47. Alnajjar, A. O., Abd El-Lateef, H. M. A novel approach to investigate the synergistic inhibition effect of nickel phosphate nanoparticles with quaternary ammonium surfactant on the Q235-mild steel corrosion: surface morphology, electrochemical-computational modeling outlines. J. Mol. Liq. 2021, 337, 116125; https://doi.org/10.1016/j.molliq.2021.116125.Search in Google Scholar

48. El-Tabei, A. S., El-Azabawy, O. E., El Basiony, N. M., Hegazy, M. A. Newly synthesized quaternary ammonium bis-cationic surfactant utilized for mitigation of carbon steel acidic corrosion; theoretical and experimental investigations. J. Mol. Struct. 2022, 1262, 133063; https://doi.org/10.1016/j.molstruc.2022.133063.Search in Google Scholar

49. Haladu, S. A., Dalhat Mu’azu, N., Ali, S. A., Elsharif, A. M., Odewunmi, N. A., Abd El-Lateef, H. M. Inhibition of mild steel corrosion in 1 M H2SO4 by a gemini surfactant 1,6-hexyldiyl-bis-(dimethyldodecylammonium bromide): ANN, RSM predictive modeling, quantum chemical and MD simulation studies. J. Mol. Liq. 2022, 350, 118533; https://doi.org/10.1016/j.molliq.2022.118533.Search in Google Scholar

50. Hegazy, M. A., Hegazy, M. M., Awad, M. K., Shawky, M. Chemical, electrochemical, theoretical (DFT & MEP), thermodynamics and surface morphology studies of carbon steel during gas and oil production using three novel di-cationic amphiphiles as corrosion inhibitors in acidic medium. J. Mol. Liq. 2021, 337, 116541; https://doi.org/10.1016/j.molliq.2021.116541.Search in Google Scholar

51. Han, T., Guo, J., Zhao, Q., Wu, Y., Zhang, Y. Enhanced corrosion inhibition of carbon steel by pyridyl gemini surfactants with different alkyl chains. Mater. Chem. Phys. 2020, 240, 122156; https://doi.org/10.1016/j.matchemphys.2019.122156.Search in Google Scholar

52. Verma, C., Quraishi, M. A., Rhee, K. Y. Hydrophilicity and hydrophobicity consideration of organic surfactant compounds: effect of alkyl chain length on corrosion protection. Adv. Colloid Interface Sci. 2022, 306, 102723; https://doi.org/10.1016/j.cis.2022.102723.Search in Google Scholar PubMed

53. Liu, Y., Zhang, H., Liu, Y., Li, J., Li, W. Inhibitive effect of quaternary ammonium-type surfactants on the self-corrosion of the anode in alkaline aluminium-air battery. J. Power Sources 2019, 434, 226723; https://doi.org/10.1016/j.jpowsour.2019.226723.Search in Google Scholar

54. Damej, M., Hsissou, R., Berisha, A., Azgaou, K., Sadiku, M., Benmessaoud, M., Labjar, N., El hajjaji, S. New epoxy resin as a corrosion inhibitor for the protection of carbon steel C38 in 1M HCl. experimental and theoretical studies (DFT, MC, and MD). J. Mol. Struct. 2022, 1254, 132425; https://doi.org/10.1016/j.molstruc.2022.132425.Search in Google Scholar

55. Li, X., Deng, S., Du, G. Nonionic surfactant of coconut diethanolamide as a novel corrosion inhibitor for cold rolled steel in both HCl and H2SO4 solutions. J. Taiwan Inst. Chem. Eng. 2022, 131, 104171; https://doi.org/10.1016/j.jtice.2021.104171.Search in Google Scholar

56. El Basiony, N. M., Elgendy, A., El-Tabey, A. E., Al-Sabagh, A. M., Abd El-Hafez, G. M., El-raouf, M. A., Migahed, M. A. Synthesis, characterization, experimental and theoretical calculations (DFT and MC) of ethoxylated aminothiazole as inhibitor for X65 steel corrosion in highly aggressive acidic media. J. Mol. Liq. 2020, 297, 111940; https://doi.org/10.1016/j.molliq.2019.111940.Search in Google Scholar

57. Abd El-Lateef, H. M., Shalabi, K., Tantawy, A. H. Corrosion inhibition and adsorption features of novel bioactive cationic surfactants bearing benzenesulphonamide on C1018-steel under sweet conditions: combined modeling and experimental approaches. J. Mol. Liq. 2020, 320, 114564; https://doi.org/10.1016/j.molliq.2020.114564.Search in Google Scholar

58. Abdelsalam, M. M., Bedair, M. A., Hassan, A. M., Heakal, B. H., Younis, A., Elbialy, Z. I., Badawy, M. A., Fawzy, H. E.-D., Fareed, S. A. Green synthesis, electrochemical, and DFT studies on the corrosion inhibition of steel by some novel triazole Schiff base derivatives in hydrochloric acid solution. Arab. J. Chem. 2022, 15, 103491; https://doi.org/10.1016/j.arabjc.2021.103491.Search in Google Scholar

Supplementary Material

The online version of this article offers supplementary material (https://doi.org/10.1515/zpch-2022-0116).

Received: 2022-08-20
Accepted: 2022-10-20
Published Online: 2022-11-02
Published in Print: 2022-12-16

© 2022 Walter de Gruyter GmbH, Berlin/Boston

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https://doi.org/10.1515/zpch-2022-0116
Keywords for this article
azomethine gemini surfactants; EIS; Langmuir isotherm; steel corrosion; weight loss DFT

Articles in the same Issue

  1. Frontmatter
  2. Original Papers
  3. Suppression of steel corrosion via some gemini cationic surfactant-based Schiff base: experimental and theoretical investigations
  4. Synthesis of poly (N-isopropyl acrylamide-co-2-acrylamido methylpropane sulfonic acid) hydrogel containing copper and nickel nanoparticles with easy recycling and efficient catalytic potential
  5. Eco-benign preparation of biosorbent using Momordica Charantia for the efficient removal of Cr(VI) ions from wastewater
  6. Oil mediated green synthesis of nano silver in the presence of surfactants for catalytic and food preservation application
  7. Adsorption properties of metal functionalized fullerene (C59Au, C59Hf, C59Ag, and C59Ir) nanoclusters for application as a biosensor for hydroxyurea (HXU): insight from theoretical computation
  8. Evaluation of diethylenetriaminepentaacetic acid modified chitosan immobilized in amino-carbmated alginate matrix as a low cost adsorbent for effective Cu(II) recovery
  9. Screening of four accelerated synthesized techniques in green fabrication of ZnO nanoparticles using Willow leaf extract
  10. Preparation and comparative evaluation of PVC/PbO and PVC/PbO/graphite based conductive nanocomposites
  11. Optical and topographic characteristics of silver films deposited from a colloidal solution on polyelectrolytes for IgG-FITC fluorescence analysis
  12. The three pyridazines, three naphthyridines and two azoles: effect of the position of the second heteroatom on pKaH of their eight conjugate acids
  13. Theoretical study on the origins of sildenafil tautomers’ relative stability
  14. Application of the Lennard-Jones potential for calculating the surface tension and the formation enthalpy of a binary solution
  15. Ultrasonic supported dye removal by a novel biomass
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  17. Review Article
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