Startseite Plasmonic Cu/CuCl/Cu2S/Ag and Cu/CuCl/Cu2S/Au Supports with Peroxidase-Like Activity: Insights from Surface Enhanced Raman Spectroscopy
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Plasmonic Cu/CuCl/Cu2S/Ag and Cu/CuCl/Cu2S/Au Supports with Peroxidase-Like Activity: Insights from Surface Enhanced Raman Spectroscopy

  • Wei Song , Peter Hildebrandt und Inez M. Weidinger EMAIL logo
Veröffentlicht/Copyright: 7. Mai 2018
Zeitschrift für Physikalische Chemie
Aus der Zeitschrift Zeitschrift für Physikalische Chemie Band 232 Heft 9-11

Abstract

In the present study, we present nanostructured bimetallic Cu/CuCl/Cu2S/Au(Ag) supports that exhibit plasmonic electromagnetic field enhancement and peroxidase-like catalytic activity. The Cu2S component acts as the peroxidase-like catalyst, while the Au or Ag component provides the necessary light enhancement for surface enhanced Raman spectroscopic (SERS) studies of surface bound molecular reactants. As a test reaction the catalytic oxidation of 3,3′,5,5′-tetramethylbenzidine (TMB) in presence of H2O2 was investigated. The comparison of product evolution in solution measured by UV-Vis spectroscopy and on the surface measured via SERS is able to give more insight into the different steps involved in the overall catalysis.

Keywords: Ag; Au; Cu2S; peroxidase-like catalytic oxidation; SERS

Acknowledgements

This work was supported by the DFG (Cluster of Excellence EXC314 UniCat) and the National Natural Science Foundation of China (21473068).

References

1. W. Liu, A. K. Herrmann, N. C. Bigall, P. Rodriguez, D. Wen, M. Oezaslan, T. J. Schmidt, N. Gaponik, A. Eychmüller, Acc. Chem. Res. 48 (2015) 154.10.1021/ar500237cSuche in Google Scholar PubMed PubMed Central

2. Q. Fu, F. Yang, X. Bao, Acc. Chem. Res. 46 (2013) 1692.10.1021/ar300249bSuche in Google Scholar PubMed

3. Z. Zhang, B. Xu, X. Wang, Chem. Soc. Rev. 43 (2014) 7870.10.1039/C3CS60389JSuche in Google Scholar

4. J. Y. Park, L. R. Baker, G. A. Somorjai, Chem. Rev. 115 (2015) 2781.10.1021/cr400311pSuche in Google Scholar PubMed

5. A. Sivanesan, H. K. Ly, J. Kozuch, M. Sezer, U. Kuhlmann, A. Fischer, I. M. Weidinger, Chem. Commun. 47 (2011) 3553.10.1039/c0cc05058jSuche in Google Scholar PubMed

6. A. Sivanesan, G. Kalaivani, A. Fischer, K. Stiba, S. Leimkühler, I. M. Weidinger, A. Chem, Anal. Chem. 84 (2012) 5759.10.1021/ac301001aSuche in Google Scholar PubMed

7. O. Diaz-Morales, F. Calle-Vallejo, C. D. Munck, M. T. M. Koper, Chem. Sci. 4 (2013) 2334.10.1039/c3sc50301aSuche in Google Scholar

8. F. J. Vidal-Iglesias, J. Solla-Gullon, J. M. Orts, A. Rodes, J. M. Perez, J. Phys. Chem. C 119 (2015) 12312.10.1021/acs.jpcc.5b01245Suche in Google Scholar

9. D.-Y. Wu, X.-M. Liu, Y.-F. Huang, B. Ren, X. Xu, Z.-Q. Tian, J. Phys. Chem. C 113 (2009) 18212.10.1021/jp9050929Suche in Google Scholar

10. B. Dong, Y. Fang, X. Chen, H. Xu, M. Sun, Langmuir 27 (2011) 10677.10.1021/la2018538Suche in Google Scholar PubMed

11. Q. Ding, H. Zhou, H. Zhang, Y. Zhang, G. Wang, H. Zhao, J. Mater. Chem. A 4 (2016) 8866.10.1039/C6TA02264BSuche in Google Scholar

12. W. Song, C. J. Querebillo, R. Gotz, S. Katz, U. Kuhlmann, U. Gernert, I. M. Weidinger, P. Hildebrandt, Nanoscale 9 (2017) 8380.10.1039/C7NR02760ESuche in Google Scholar PubMed

13. M. Muniz-Miranda, Appl. Catal. B 146 (2014) 147.10.1016/j.apcatb.2013.03.008Suche in Google Scholar

14. C. Wen, F. Liao, S. Liu, Y. Zhao, Z. Kang, X. Zhang, M. Shao, Chem. Commun. 49 (2013) 3049.10.1039/c3cc37877bSuche in Google Scholar PubMed

15. W. Song, W. Ji, S. Vantasin, I. Tanabe, B. Zhao, Y. Ozaki, J. Mater. Chem. A 3 (2015) 13556.10.1039/C5TA01974ESuche in Google Scholar

16. W. Song, G. D. Nie, W. Ji, Y. Z. Jiang, X. F. Lu, B. Zhao, Y. Ozaki, RSC Adv. 6 (2016) 54456.10.1039/C6RA09471FSuche in Google Scholar

17. Y. Guo, H. Wang, X. W. Ma, J. Jin, W. Ji, X. Wang, W. Song, B. Zhao, C. Y. He, ACS Appl. Mater. Interf. 9 (2017) 19074.10.1021/acsami.7b02149Suche in Google Scholar PubMed

18. M. Sezer, S. Frielingsdorf, D. Millo, N. Heidary, T. Utesch, M.-A. Mroginski, B. Friedrich, P. Hildebrandt, I. Zebger, I. M. Weidinger, J. Phys. Chem. B 115 (2011) 10368.10.1021/jp204665rSuche in Google Scholar PubMed

19. P. Kielb, M. Sezer, S. Katz, F. Lopez, C. Schulz, L. Gorton, R. Ludwig, U. Wollenberger, I. Zebger, I. M. Weidinger, Chemphyschem 16 (2015) 1960.10.1002/cphc.201500112Suche in Google Scholar PubMed

20. K. Sengupta, S. Chatterjee, S. Samanta, A. Dey, Proc. Natl. Acad. Sci. USA 110 (2013) 8431.10.1073/pnas.1300808110Suche in Google Scholar PubMed PubMed Central

21. H. Wei, E. Wang, Chem. Soc. Rev. 42 (2013) 6060.10.1039/c3cs35486eSuche in Google Scholar PubMed

22. Y. Lin, J. Ren, X. Qu, Acc. Chem. Res. 47 (2014) 1097.10.1021/ar400250zSuche in Google Scholar PubMed

23. L. Z. Gao, J. Zhuang, L. Nie, J. B. Zhang, Y. Zhang, N. Gu, T. H. Wang, J. Feng, D. L. Yang, S. Perrett, X. Yan, Nat. Nanotechnol. 2 (2007) 577.10.1038/nnano.2007.260Suche in Google Scholar PubMed

24. G. Nie, L. Zhang, X. Lu, X. Bian, W. Sun, C. Wang, Dalton Trans. 42 (2013) 14006.10.1039/c3dt51489gSuche in Google Scholar PubMed

25. Y. Jiang, N. Song, C. Wang, N. Pinna, X. Lu, J. Mater. Chem. B 5 (2017) 5499.10.1039/C7TB01058CSuche in Google Scholar PubMed

26. Z. Yang, F. Ma, Y. Zhu, S. Chen, C. Wang, X. Lu, Dalton Trans. 46 (2017) 11171.10.1039/C7DT01611ESuche in Google Scholar PubMed

27. R. André, F. Natálio, M. Humanes, J. Leppin, K. Heinze, R. Wever, H. C. Schröder, W. E. G. Müller, W. Tremel, Adv. Funct. Mater. 21 (2011) 501.10.1002/adfm.201001302Suche in Google Scholar

28. M. Chi, Y. Zhu, Z. Yang, M. Gao, S. Chen, N. Song, C. Wang, X. Lu, Nanotechnology 28 (2017) 295704.10.1088/1361-6528/aa76bcSuche in Google Scholar PubMed

29. Z. Jiang, P. Gao, Y. Lin, C. Huang, Y. Li, Anal. Chem. 87 (2015) 12177.10.1021/acs.analchem.5b03058Suche in Google Scholar PubMed

30. W. Song, M. Chi, M. Gao, B. Zhao, C. Wang, X. Lu, J. Mater. Chem. C 5 (2017) 7465.10.1039/C7TC01761HSuche in Google Scholar

31. Y. Xia, E. Kim, M. Mrksich, G. M. Whitesides, Chem. Mater. 8 (1996) 601.10.1021/cm950464+Suche in Google Scholar

32. B. Zhao, S. Li, Q. Zhang, Y. Wang, C. Song, Z. Zhang, K. Yu, Chem. Eng. J. 230 (2013) 236.10.1016/j.cej.2013.06.097Suche in Google Scholar

33. J. F. Li, Y. F. Huang, Y. Ding, Z. L. Yang, S. B. Li, X. S. Zhou, F. R. Fan, W. Zhang, Z. Y. Zhou, D. Y. Wu, B. Ren, Z. L. Wang, Z. Q. Tian, Nature 464 (2010) 392.10.1038/nature08907Suche in Google Scholar PubMed

34. J. A. Sánchezgil, J. V. Garcı́Aramos, J. Chem. Phys. 108 (1998) 317.10.1023/A:1005165615804Suche in Google Scholar

35. C. David, M. Richter, A. Knorr, I. M. Weidinger, P. Hildebrandt, J. Chem. Phys. 132 (2010) 24712.10.1063/1.3291438Suche in Google Scholar PubMed

36. E. Siebert, Y. Rippers, S. Frielingsdorf, J. Fritsch, A. Schmidt, J. Kalms, S. Katz, O. Lenz, P. Scheerer, L. Paasche, V. Pelmenschikov, U. Kuhlmann, M. A. Mroginski, I. Zebger, P. Hildebrandt, J. Phys. Chem. B 119 (2015) 13785.10.1021/acs.jpcb.5b04119Suche in Google Scholar PubMed

Received: 2018-01-29
Accepted: 2018-03-05
Published Online: 2018-05-07
Published in Print: 2018-08-28

©2018 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Preface
  3. Congratulations to Alexander Eychmüller
  4. Halogens in the Synthesis of Colloidal Semiconductor Nanocrystals
  5. Controlled Aqueous Synthesis of CdSe Quantum Dots using Double-Hydrophilic Block Copolymers as Stabilizers
  6. Fabrication of Ag2S/CdS Heterostructured Nanosheets via Self-Limited Cation Exchange
  7. Ion-Selective Ligands: How Colloidal Nano- and Micro-Particles Can Introduce New Functionalities
  8. TEM, FTIR and Electrochemistry Study: Desorption of PVP from Pt Nanocubes
  9. Incorporation of CdTe Nanocrystals into Metal Oxide Matrices Towards Inorganic Nanocomposite Materials
  10. Diatoms – A “Green” Way to Biosynthesize Gold-Silica Nanocomposites?
  11. Evidence for Photo-Switchable Carrier Mobilities in Blends of PbS Nanocrystals and Photochromic Dithienylcyclopentene Derivatives
  12. Gelation-Assisted Layer-by-Layer Deposition of High Performance Nanocomposites
  13. Enhancement of the Fluorescence Quantum Yield of Thiol-Stabilized CdTe Quantum Dots Through Surface Passivation with Sodium Chloride and Bicarbonate
  14. Fluorescence Quenching of CdTe Quantum Dots with Co (III) Complexes via Electrostatic Assembly Formation
  15. Colloidal Photoluminescent Refractive Index Nanosensor Using Plasmonic Effects
  16. Towards Low-Toxic Colloidal Quantum Dots
  17. Color-Enrichment Semiconductor Nanocrystals for Biorhythm-Friendly Backlighting
  18. Transient Absorption Studies on Nanostructured Materials and Composites: Towards the Development of New Photocatalytic Systems
  19. Transient Spectroscopy of Glass-Embedded Perovskite Quantum Dots: Novel Structures in an Old Wrapping
  20. Energy Transfer Between Single Semiconductor Quantum Dots and Organic Dye Molecules
  21. Chemical Routes to Surface Enhanced Infrared Absorption (SEIRA) Substrates
  22. Plasmonic Cu/CuCl/Cu2S/Ag and Cu/CuCl/Cu2S/Au Supports with Peroxidase-Like Activity: Insights from Surface Enhanced Raman Spectroscopy
  23. n-Type Cu2O/α-Fe2O3 Heterojunctions by Electrochemical Deposition: Tuning of Cu2O Thickness for Maximum Photoelectrochemical Performance
  24. The Photoelectrochemistry of Assemblies of Semiconductor Nanoparticles at Interfaces
  25. Surface-Charge Dependent Orientation of Water at the Interface of a Gold Electrode: A Cluster Study
  26. Single Particle Spectroscopy of Radiative Processes in Colloid-to-Film-Coupled Nanoantennas
  27. Coupled Plasmon Resonances and Gap Modes in Laterally Assembled Gold Nanorod Arrays
  28. Anisotropy of Structure and Optical Properties of Self-Assembled and Oriented Colloidal CdSe Nanoplatelets
  29. Simple Electroless Synthesis of Cobalt Nanoparticle Chains, Oriented by Externally Applied Magnetic Fields
  30. Functionalization of Graphene Aerogels and their Applications in Energy Storage and Conversion
  31. Macroscopic Aerogels with Retained Nanoscopic Plasmonic Properties
  32. Application of Aqueous-Based Covalent Crosslinking Strategies to the Formation of Metal Chalcogenide Gels and Aerogels
  33. Cellulose-Based Hydrogels with Controllable Electrical and Mechanical Properties
  34. Naphthalenetetracarboxylic Diimide Derivatives: Molecular Structure, Thin Film Properties and Solar Cell Applications
  35. Metal-Phenolic Encapsulated Mesoporous Silica Nanoparticles for pH-Responsive Drug Delivery and Magnetic Resonance Imaging
  36. Extraction of K2CO3 from Low Concentration [K+] Solutions with the Aid of CO2: A Study on the Metastable Phase Equilibrium of K2CO3-Na2CO3-H2O Ternary System
https://doi.org/10.1515/zpch-2018-1126
Schlagwörter für diesen Artikel
Ag; Au; Cu2S; peroxidase-like catalytic oxidation; SERS

Artikel in diesem Heft

  1. Frontmatter
  2. Preface
  3. Congratulations to Alexander Eychmüller
  4. Halogens in the Synthesis of Colloidal Semiconductor Nanocrystals
  5. Controlled Aqueous Synthesis of CdSe Quantum Dots using Double-Hydrophilic Block Copolymers as Stabilizers
  6. Fabrication of Ag2S/CdS Heterostructured Nanosheets via Self-Limited Cation Exchange
  7. Ion-Selective Ligands: How Colloidal Nano- and Micro-Particles Can Introduce New Functionalities
  8. TEM, FTIR and Electrochemistry Study: Desorption of PVP from Pt Nanocubes
  9. Incorporation of CdTe Nanocrystals into Metal Oxide Matrices Towards Inorganic Nanocomposite Materials
  10. Diatoms – A “Green” Way to Biosynthesize Gold-Silica Nanocomposites?
  11. Evidence for Photo-Switchable Carrier Mobilities in Blends of PbS Nanocrystals and Photochromic Dithienylcyclopentene Derivatives
  12. Gelation-Assisted Layer-by-Layer Deposition of High Performance Nanocomposites
  13. Enhancement of the Fluorescence Quantum Yield of Thiol-Stabilized CdTe Quantum Dots Through Surface Passivation with Sodium Chloride and Bicarbonate
  14. Fluorescence Quenching of CdTe Quantum Dots with Co (III) Complexes via Electrostatic Assembly Formation
  15. Colloidal Photoluminescent Refractive Index Nanosensor Using Plasmonic Effects
  16. Towards Low-Toxic Colloidal Quantum Dots
  17. Color-Enrichment Semiconductor Nanocrystals for Biorhythm-Friendly Backlighting
  18. Transient Absorption Studies on Nanostructured Materials and Composites: Towards the Development of New Photocatalytic Systems
  19. Transient Spectroscopy of Glass-Embedded Perovskite Quantum Dots: Novel Structures in an Old Wrapping
  20. Energy Transfer Between Single Semiconductor Quantum Dots and Organic Dye Molecules
  21. Chemical Routes to Surface Enhanced Infrared Absorption (SEIRA) Substrates
  22. Plasmonic Cu/CuCl/Cu2S/Ag and Cu/CuCl/Cu2S/Au Supports with Peroxidase-Like Activity: Insights from Surface Enhanced Raman Spectroscopy
  23. n-Type Cu2O/α-Fe2O3 Heterojunctions by Electrochemical Deposition: Tuning of Cu2O Thickness for Maximum Photoelectrochemical Performance
  24. The Photoelectrochemistry of Assemblies of Semiconductor Nanoparticles at Interfaces
  25. Surface-Charge Dependent Orientation of Water at the Interface of a Gold Electrode: A Cluster Study
  26. Single Particle Spectroscopy of Radiative Processes in Colloid-to-Film-Coupled Nanoantennas
  27. Coupled Plasmon Resonances and Gap Modes in Laterally Assembled Gold Nanorod Arrays
  28. Anisotropy of Structure and Optical Properties of Self-Assembled and Oriented Colloidal CdSe Nanoplatelets
  29. Simple Electroless Synthesis of Cobalt Nanoparticle Chains, Oriented by Externally Applied Magnetic Fields
  30. Functionalization of Graphene Aerogels and their Applications in Energy Storage and Conversion
  31. Macroscopic Aerogels with Retained Nanoscopic Plasmonic Properties
  32. Application of Aqueous-Based Covalent Crosslinking Strategies to the Formation of Metal Chalcogenide Gels and Aerogels
  33. Cellulose-Based Hydrogels with Controllable Electrical and Mechanical Properties
  34. Naphthalenetetracarboxylic Diimide Derivatives: Molecular Structure, Thin Film Properties and Solar Cell Applications
  35. Metal-Phenolic Encapsulated Mesoporous Silica Nanoparticles for pH-Responsive Drug Delivery and Magnetic Resonance Imaging
  36. Extraction of K2CO3 from Low Concentration [K+] Solutions with the Aid of CO2: A Study on the Metastable Phase Equilibrium of K2CO3-Na2CO3-H2O Ternary System
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 6.10.2025 von https://www.degruyterbrill.com/document/doi/10.1515/zpch-2018-1126/html
Button zum nach oben scrollen