Eu2Ru3Si5 and Eu2Ir3Ga5 – first europium compounds with U2Mn3Si5-type structure but different europium valence
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Stefan Seidel
Abstract
The silicide Eu2Ru3Si5 was synthesized from the elements in a sealed tantalum tube in a high-frequency furnace, while the gallide Eu2Ir3Ga5 was obtained by arc-melting. Both structures were refined from single-crystal X-ray diffractometer data: P4/mnc, a = 1072.69(8), c = 569.55(5) pm, wR = 0.0453, 617 F2 values, 31 variables for Eu2Ru3Si5 and a = 1122.18(7), c = 583.17(4) pm, wR = 0.0546, 729 F2 values, 31 variables for Eu2Ir3Ga4.95(1). The gallide shows small defects on one 8h site. The transition metal atoms in Eu2Ru3Si5 and Eu2Ir3Ga5 have octahedral p element coordination. These Ru@Si6 respectively Ir@Ga6 polyhedra are condensed to three-dimensional [Ru3Si5]6− respectively [Ir3Ga5]4− polyanionic networks. The ground states of Eu(III) in Eu2Ru3Si5 and Eu(II) in Eu2Ir3Ga5 were determined by 151Eu Mössbauer spectroscopy.
Acknowledgements
We thank Dipl.-Ing. U. Ch. Rodewald for the intensity data collections.
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: None declared.
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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Artikel in diesem Heft
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- Expanding transition metal borate chemistry to include main group elements: high-pressure synthesis and structural relation of β-MgB4O7
- Eu2Ru3Si5 and Eu2Ir3Ga5 – first europium compounds with U2Mn3Si5-type structure but different europium valence
- Mössbauer-spectroscopic characterization of the stannides Sr2Pd2Sn and Eu2Pd2Sn
- Orthoamide und Iminiumsalze, CVIII. Umsetzungen von Orthoamiden der Alkincarbonsäuren mit CH/NH-aciden, tautomeriefähigen Verbindungen
- Book Review
- Thomas J. Meade (Guest Editor), Astrid Sigel, Helmut Sigel, Eva Freisinger, Roland K. O. Sigel (Series Editors): Molecular Bio-Sensors and the Role of Metal Ions
Artikel in diesem Heft
- Frontmatter
- In this issue
- Research Articles
- Photoredox-catalyzed three-component difluorobenzylation of quinoxalin-2(1H)-ones with unactivated vinylarenes and BrCF2CO2Et/HCF2CO2H
- Catalyst-free direct synthesis of indeno[1,2-b]indol-5(4bH)-yl benzimidamides
- Crystal structure of three chloridocuprate(I, II) complexes with methylene blue (MB) counterions
- Crystal structure, photophysical properties, and DFT calculations of a boron difluoride curcumin complex
- The double cluster compound [Nb6Cl14(MeCN)4][Nb6Cl14(pyz)4]·6MeCN (Me: methyl, pyz: pyrazine) with a layered structure resulting from weak intermolecular interactions
- Expanding transition metal borate chemistry to include main group elements: high-pressure synthesis and structural relation of β-MgB4O7
- Eu2Ru3Si5 and Eu2Ir3Ga5 – first europium compounds with U2Mn3Si5-type structure but different europium valence
- Mössbauer-spectroscopic characterization of the stannides Sr2Pd2Sn and Eu2Pd2Sn
- Orthoamide und Iminiumsalze, CVIII. Umsetzungen von Orthoamiden der Alkincarbonsäuren mit CH/NH-aciden, tautomeriefähigen Verbindungen
- Book Review
- Thomas J. Meade (Guest Editor), Astrid Sigel, Helmut Sigel, Eva Freisinger, Roland K. O. Sigel (Series Editors): Molecular Bio-Sensors and the Role of Metal Ions
