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Crystal structure of three chloridocuprate(I, II) complexes with methylene blue (MB) counterions

  • Vahobjon Kh. Sabirov EMAIL logo and Mukarram X. Kadirova
Published/Copyright: March 14, 2023
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 78 Issue 5

Abstract

Three chloridocuprate complexes with methylene blue counterions of the chemical compositions [MB]+2[CuCl4]2− · H2O (1), [MB]+2[CuCl4]2− (2) and [(MB)+(CuCl2)−]3 (3) (where [MB]+ – methylthioninium cation; methylene blue cation) have been prepared by solvent-assisted mechanochemical synthesis. The reactions were carried out by mixing the copper(II) chloride dihydrate, CuCl2⋅2H2O, and methylene blue pentahydrate, [MB]+Cl− · 5H2O by grinding in an agate mortar with the addition of DMF as a solvent. The crystal structures of the compounds have been determined by single-crystal X-ray diffraction. The content of an asymmetric unit of the crystals consists of: (1) a tetrahedral [CuCl4]2− anion, two [MB]+ cations and one water molecule of crystallization; (2) a tetrahedral [CuCl4]2− anion and two [MB]+ cations; (3) trimeric [(MB)+(CuCl2)−]3 molecules with the Cu atoms coordinated by a nitrogen atom of the phenothiazine ring and two chlorine ions in a trigonal planar geometry with the copper atom in the oxidation state of +1.

Keywords: copper complex; methylene blue; X-ray diffraction
Corresponding author: Vahobjon Kh. Sabirov, Institute of Pharmaceutical Education and Research, 46 Building, 19 Quarter, Yunusabad District, 100114, Tashkent, Uzbekistan, E-mail:

Acknowledgments

The authors are grateful to the colleagues, especially to Odil Choriev, in the Institute of Bioorganic Chemistry of the Academy of Sciences of the Republic of Uzbekistan for assistance in the X-ray experiments.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Supplementary Material

This article contains supplementary material (https://doi.org/10.1515/znb-2022-0146).

Received: 2022-12-03
Accepted: 2023-02-06
Published Online: 2023-03-14
Published in Print: 2023-05-25

© 2023 Walter de Gruyter GmbH, Berlin/Boston

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https://doi.org/10.1515/znb-2022-0146
Keywords for this article
copper complex; methylene blue; X-ray diffraction

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. Photoredox-catalyzed three-component difluorobenzylation of quinoxalin-2(1H)-ones with unactivated vinylarenes and BrCF2CO2Et/HCF2CO2H
  5. Catalyst-free direct synthesis of indeno[1,2-b]indol-5(4bH)-yl benzimidamides
  6. Crystal structure of three chloridocuprate(I, II) complexes with methylene blue (MB) counterions
  7. Crystal structure, photophysical properties, and DFT calculations of a boron difluoride curcumin complex
  8. The double cluster compound [Nb6Cl14(MeCN)4][Nb6Cl14(pyz)4]·6MeCN (Me: methyl, pyz: pyrazine) with a layered structure resulting from weak intermolecular interactions
  9. Expanding transition metal borate chemistry to include main group elements: high-pressure synthesis and structural relation of β-MgB4O7
  10. Eu2Ru3Si5 and Eu2Ir3Ga5 – first europium compounds with U2Mn3Si5-type structure but different europium valence
  11. Mössbauer-spectroscopic characterization of the stannides Sr2Pd2Sn and Eu2Pd2Sn
  12. Orthoamide und Iminiumsalze, CVIII. Umsetzungen von Orthoamiden der Alkincarbonsäuren mit CH/NH-aciden, tautomeriefähigen Verbindungen
  13. Book Review
  14. Thomas J. Meade (Guest Editor), Astrid Sigel, Helmut Sigel, Eva Freisinger, Roland K. O. Sigel (Series Editors): Molecular Bio-Sensors and the Role of Metal Ions
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